Reaction of 3,5-diamino-4-nitropyrazole with electrophilic reagents

The interaction of 3,5-diamino-4-nitropyrazole with such electrophilic reagents as acetic anhydride, dimethylformamide acetal, orthoformic ester, and ketones has been studied. Derivatives of pyrazolol[1,5-a]pyrimidines were formed on reaction with 1,3-diketones and some of their properties have been studied.Center for Drug Chemistry, All-Russian Chemical and Pharmaceutical Research Institute (VNIKhFI), Moscow 119815. Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 3, pp. 329–335, March, 1997.     

Laser systems specialized for laser spectroscopy at storage rings

Laser spectroscopy at storage rings often suffers from a limited resolution due to Doppler-broadened resonances. Broadening is caused by the velocity spread of the ions stored in the beam. In the following, the present status of our work on laser systems specialized on the specific needs of laser spectroscopy at storage rings is reported. Two pulsed laser systems were developed. One is a dye laser whose spectral bandwidth can be switched by inserting different Littrow-prisms into the resonator. An increase in bandwidth up to a factor of 45 was achieved. This laser was used for fast qualitative scans and high resolution measurements. The other laser system is a Nd : YAG laser pumped optical parametric oscillator. It is a tunable laser system covering the spectral range from 410 to 4000 nm. Furthermore, a continuous wave laser with a frequency shifted feedback cavity is described. It shows broadband emission with an adjustable bandwidth of up to 4.5 GHz. This laser can be advantageous for laser cooling of ion beams. This revised version was published online in August 2006 with corrections to the Cover Date.     

Vibrational spectrum of uridine obtained by means of nonresonant-background-free CARS spectroscopy

Received: 18 June 1996/Revised version: 3 January 1997     

Critical fields and currents in a weakly nonlinear medium near the percolation threshold

For fields above a critical value the expansion of the conductivity in powers of the field ceases to be valid and the weak-nonlinearity approximation no longer works. The density behavior of the critical fields in strongly inhomogeneous media near the percolation threshold is found on the basis of two criteria—an average criterion and a local criterion. The parameter values of the medium for which crossover—a change of the critical behavior—occurs are determined. Similar calculations are performed for the critical currents. Zh. Tekh. Fiz. 68, 5–8 (June 1998)     

Solid phase synthesis of azapeptides using an automatic synthesizer

Peptides containing azaglycine located terminally or within the backbone have been prepared in the solid phase by means of an automatic synthesizer.     

Thermal diffusivity measurements in porous ceramics by photothermal methods

Received: 16 September 1996/Accepted: 6 January 1997     

Twistor Geometry for Hyperkähler Metrics on Complex Adjoint Orbits

We study the hyperkähler geometry of complex adjoint orbits from the point of view of twistor theory. We introduce, for complex semisimple adjoint orbits, the associated spectral curve and construct the twistor space as a union of certain regular adjoint orbits; we also exhibit the family of twistor lines. Furthermore, we show how our methods may be applied for describing hyperkähler metrics associated to more general spectral curves. In particular, we give an algebraic characterisation of the twistor lines.     

Forced-air precooling of spherical foods in bulk: A parametric study

In this paper, a mathematical model for forced-air precooling of spherical food products in bulk is developed. The foods are arranged in horizontal layers stacked one above the other to form a rectangular parallelepiped with a vertical gap in between the product layers. The foods are cooled by chilled air blown along the height of the package. The governing equations for the conduction heat transfer in the foods, simultaneous heat and mass transfer at the food-air interface and in the air stream are solved numerically using finite-difference methods. A comprehensive numerical study is performed by varying the process parameters over a wide range. Typical results showing the variation of moist air properties along the height of the package and the effect of each parameter on the process time are presented. The ranges of parameters for advantageous operation of the precooling system are identified. Correlations are obtained for the process time based on the product center and mass-averaged temperatures in terms of process parameters.