全文获取类型
收费全文 | 778篇 |
免费 | 28篇 |
国内免费 | 10篇 |
专业分类
化学 | 462篇 |
晶体学 | 6篇 |
力学 | 23篇 |
数学 | 163篇 |
物理学 | 162篇 |
出版年
2023年 | 5篇 |
2022年 | 20篇 |
2021年 | 28篇 |
2020年 | 23篇 |
2019年 | 10篇 |
2018年 | 17篇 |
2017年 | 16篇 |
2016年 | 45篇 |
2015年 | 28篇 |
2014年 | 33篇 |
2013年 | 56篇 |
2012年 | 63篇 |
2011年 | 51篇 |
2010年 | 38篇 |
2009年 | 25篇 |
2008年 | 52篇 |
2007年 | 35篇 |
2006年 | 40篇 |
2005年 | 25篇 |
2004年 | 24篇 |
2003年 | 20篇 |
2002年 | 20篇 |
2001年 | 7篇 |
2000年 | 10篇 |
1999年 | 5篇 |
1998年 | 7篇 |
1997年 | 4篇 |
1996年 | 5篇 |
1995年 | 5篇 |
1994年 | 5篇 |
1993年 | 14篇 |
1992年 | 5篇 |
1991年 | 3篇 |
1990年 | 6篇 |
1989年 | 3篇 |
1988年 | 3篇 |
1985年 | 4篇 |
1984年 | 3篇 |
1981年 | 4篇 |
1978年 | 3篇 |
1976年 | 3篇 |
1975年 | 3篇 |
1974年 | 2篇 |
1973年 | 6篇 |
1972年 | 3篇 |
1971年 | 4篇 |
1969年 | 4篇 |
1968年 | 2篇 |
1967年 | 2篇 |
1937年 | 2篇 |
排序方式: 共有816条查询结果,搜索用时 15 毫秒
101.
Lahcen Hssaini Francisca Hernandez Manuel Viuda-Martos Jamal Charafi Rachid Razouk Karim Houmanat Rachida Ouaabou Said Ennahli Driss Elothmani Ilham Hmid Marie Laure Fauconnier Hafida Hanine 《Molecules (Basel, Switzerland)》2021,26(9)
In the present study, chromatic coordinates, phenolic acids, flavonoids and antioxidant capacity assessed by 1,1-diphenyl-2-picrylhydrazyl (DPPH), 2,2′-azino-bis (3-ethylbenzothiazoline-6-sulfonate (ABTS) and lipid peroxidation inhibition capacity (LPIC) essays and their relative IC50 were investigated in 25 fig cultivars growing in Morocco. The aims of this study were to determine (i) the variation in these compounds among light and dark-colored cultivars, (ii) their partitioning between fruit peel and pulp and (iii) to display network connections among these variables. Twelve phenolic compounds (PCs) were isolated in peel extract versus eight in pulp samples. Anthocyanins, mainly cyanidin-3,5-diglucoside and cyanidin-3-O-rutinoside, were the predominant compounds in peels, where the mean concentrations were 75.90 ± 18.76 and 77.97 ± 18.95 µg/g dw, respectively. On the other hand, (−)-epicatechin and cyanidin-3-O-rutinoside were the major compounds in the pulp extracts, where the mean values were 5.23 ± 4.03 and 9.01 ± 5.67 µg/g dw, respectively. A two-dimensional hierarchically clustered heatmap was applied to the dataset to explore correlations in the dataset and similarities between cultivars, without dimensionality reduction. Results showed that anthocyanins, particularly pelargonidin-3-O-rutinoside, cyanidin-3,5-diglucoside and cyanidin-3-O-rutinoside, were the main contributors to the peels’ free radical scavenging capacity. This capacity was particularly higher in the peel of dark-colored figs compared to the fruit pulp. The local cultivar “INRA 1301” showed the most promising phenolic profile due to its very high levels of almost all detected PCs, especially (−)-epicatechin, quercetin-3-O-rutinoside, quercetin-3-O-glucoside, cyanidine-3,5-diglucoside, cyanidine-3-O-rutinoside and pelargonidin-3-O-rutinoside (54.66, 141.08, 35.48, 494.08, 478.66, 12.56 µg/g dw, respectively). Having the darkest figs in the collection (L* = 25.72, c* = 22.09 and h° = 20.99), this cultivar has also combined promising IC50 values, which were of 19.85, 40.58 and 124.78 µg/mL for DPPH, ABTS and LPIC essays, respectively. 相似文献
102.
103.
An asymptotic formula for the voltage potential in the case of a near-surface conductivity inclusion
Habib Ammari Hyeonbae Kang Karim Touibi 《Zeitschrift für Angewandte Mathematik und Physik (ZAMP)》2006,57(2):234-243
We rigorously derive an asymptotic expansion of the steady-state voltage potentials in the presence of a conductivity inclusion
of small volume that is close to a planar surface. This new formula is motivated by the practically important inverse problem
of imaging a conductivity inclusion near a planar interface.
Partly supported by ACI Jeunes Chercheurs (0693) from the Ministry of Education and Scientific Research, France.
Partially supported by grant R02-2003-000-10012-0 from the Korea Science and Engineering Foundation.
Received: December 2, 2003; revised: January 18, 2004 相似文献
104.
Karim Kadir Tetsuo Sakai Itsuki Uehara Lars Eriksson 《Acta Crystallographica. Section C, Structural Chemistry》2001,57(9):999-1000
Yttrium tricopper dialuminium, YCu3Al2, is isostructural with hexagonal CaCu5, in which each Cu atom at the 3g(½,0,½) position in space group P6/mmm (No. 191) is partially replaced by an Al atom. The hydrogen‐uptake properties are usually enhanced in other AB5 structures by aluminium substitution. YCu5 does not show any hydrogen absorption, and the goal of the present work is to investigate whether aluminium substitution could expand the metal‐atom lattice enough to provide better interstitial positions for hydrogen storage. However, no enthalpy change was observed up to 773 K under 3 MPa static H2 pressure by differential thermal analysis (DTA) for the title compound. The compound does not show any significant hydrogen absorption/desorption in the pressure‐composition isotherms (P–C–T diagrams) in the temperature range 298–673 K under 3.3 MPa H2 pressure. 相似文献
105.
A method is described for the determination of 10–100 nmole of methanal and 20–150 nmole of ethanal and propanal. The method is based on the oxidation of aldehydes to the corresponding acids by mercuric ion which in turn is reduced to elemental mercury, followed by cold-vapour atomic absorption spectrometry. Calibration plots were constructed between the concentration of each aldehyde and absorbance, while the calibration from the conventional cold vapour procedure was used for total aldehydes determination. The method is selective and can be used for aldehyde determination in the presence of ketones, acetals, alcohols, acids, esters, ethers, organic chlorides and epoxides. This simple method is characterised by 98–102% recoveries and standard deviations of 3%. 相似文献
106.
P. Bosetti M. Deutschmann H. Grässler G. Otter H.H. Seyfert K. Böckmann J. Hofmann J. Lowsky G. Zobernig V.T. Cocconi T. Coghen V. Karimäki G. Kellner D.R.O. Morrison J. Zaorska 《Nuclear Physics B》1975,94(1):21-38
The production of is measured in π+p reactions at 16 GeV/c. The total strange particle cross section is found to be 4.0 ± 0.3 mb, about 20% of the inelastic cross section. Cross sections for single strange particles and for strange particle pairs are determined, both inclusively and as functions of the charged multiplicity. Relative production rates for different strange particle combinations are compared with the prediction of the isospin statistical model. Inclusive spectra for single particles are studied and it is found the KS0 are produced mostly in the forward hemisphere, most probably by fragmentation of the incident pion into . The Λ are mostly backwards, probably deriving from fragmentation of the proton into ΛK pairs. The tend to be produced forwards, but evidence is found for central production. Distributions in rapidity of the Λ particles from π+p interactions are compared in terms of the factorisation hypothesis. Results are given on the Λ transversal polarisation. 相似文献
107.
108.
109.
110.
Awenat KM Davis PJ Moloney MG Ebenezer W 《Chemical communications (Cambridge, England)》2005,(8):990-992
A method for the application of carbenes as reactive intermediates for surface modification of polymeric substrates has been developed; the efficacy of the process has been demonstrated by irreversible dyeing of polystyrene, polythene, nylon, silica, and controlled pore glass, and to a limited extent, polytetrafluoroethylene. 相似文献