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71.
72.
Alexander S. Romanov Joseph M. Mulroy Victor N. Khrustalev Mikhail Yu. Antipin Tatiana V. Timofeeva 《Acta Crystallographica. Section C, Structural Chemistry》2009,65(11):m426-m430
The structures of the three title monosubstituted ferrocenes, namely 1‐chloroferrocene, [Fe(C5H5)(C5H4Cl)], (I), 1‐bromoferrocene, [Fe(C5H5)(C5H4Br)], (II), and 1‐iodoferrocene, [Fe(C5H5)(C5H4I)], (III), were determined at 100 K. The chloro‐ and bromoferrocenes are isomorphous crystals. The new triclinic polymorph [space group P, Z = 4, T = 100 K, V = 943.8 (4) Å3] of iodoferrocene, (III), and the previously reported monoclinic polymorph of (III) [Laus, Wurst & Schottenberger (2005). Z. Kristallogr. New Cryst. Struct. 220 , 229–230; space group Pc, Z = 4, T = 100 K, V = 924.9 Å3] were obtained by crystallization from ethanolic solutions at 253 and 303 K, respectively. All four phases contain two independent molecules in the unit cell. The relative orientations of the cyclopentadienyl (Cp) rings are eclipsed and staggered in the independent molecules of (I) and (II), while (III) demonstrates only an eclipsed conformation. The triclinic and monoclinic polymorphs of (III) contain nonbonded intermolecular I...I contacts, causing different packing modes. In the triclinic form of (III), the molecules are arranged in zigzag tetramers, while in the monoclinic form the molecules are arranged in zigzag chains along the a axis. Crystallographic data for (III), along with the computed lattice energies of the two polymorphs, suggest that the monoclinic form is more stable. 相似文献
73.
Mikhail S. Nechaev Oleg V. Chernov Ivan A. Portnyagin Victor N. Khrustalev Valery V. Lunin 《Journal of organometallic chemistry》2010,695(3):365-369
Alkylation of Sn(OCH2CH2NMe2)2 (1) by MeI or MeOTf leads to a mixture of quaternary ammonium salts by alkylation of the NMe2 moiety. Reaction of Sn(acac)2 (2) with MeOTf gives unexpected redistribution product Sn(acac)OTf (3), which is a rare example of mono acetylacetonato tin (II) derivatives. Pentacoordinated monoorgano stannyl cation was generated by salt metathesis from PhSn(OCH2CH2NMe2)2Cl (5) and Ag[Al(OCH(CF3)2)4] or Ag[B(C6F5)4]. This cation was not isolated due to its strong electrophilic nature. It abstracts substituents from aluminate and borate weakly coordinating anions (WCAs) leading to redistribution products [Al[OCH(CF3)2]2OCH2CH2NMe2]2 (6) and [Ph(C6F5)Sn(OCH2CH2NMe2)2][H2OB(C6F5)3] (9), respectively. Structures of 3 and 6 were established by single-crystal X-ray diffraction analysis. 相似文献
74.
75.
S. A. Pogozhikh Yu. E. Ovchinnikov V. N. Khrustalev M. Yu. Antipin R. G. Karpenko S. P. Kolesnikov 《Russian Chemical Bulletin》1999,48(1):117-123
Germylated steroids were studied by X-ray diffraction analysis for the first time. The conformational parameters of the molecules
in the crystals are discussed. The three-center hypervalent O−Ge−Cl bonds are observed in two β-isomers. The geometric parameters
of the hypervalent units are compared.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 116–122, January, 1999. 相似文献
76.
A.V. Borisov Zh. V. Matsulevich V. K. Osmanov G. N. Borisova G. Z. Mammadova A. M. Maharramov V. N. Khrustalev 《Chemistry of Heterocyclic Compounds》2012,48(6):963-968
Cycloalkenes react with di(2-pyridyl) diselenide in the presence of antimony pentachloride with the formation of products of the selenenylating electrophile cycloaddition at the multiple bond. The final products of heterocyclization, chloroantimonates(III) of 2,3-dihydro[1,3]selenazolo[3,2-a]pyridinium derivatives were isolated. 相似文献
77.
78.
A. M. Magerramov A. V. Kurbanov V. N. Khrustalev S. S. Godzhaeva é. N. Garibov V. M. Farzaliev M. A. Allakhverdiev 《Journal of Structural Chemistry》2010,51(5):968-971
Three-component condensation of N1-phenylthiocarbamide with salicylaldehyde and with the ether of acetoacetic acid in the
presence of trifluoroacetic acid provides a productive synthesis of ethyl 9-methyl-10-phenyl-1 1-thioxo-8-oxa-10,12-diazatricyclo[7.3.1.02.7]trideca-2(7),3,5-trien-13-carboxylate I. Single crystal XRD is used to determine the crystal structure of I and to identify the conformation properties of the structures. 相似文献
79.
Siaka Sorho P. M. Lukin O. E. Nasakin V. N. Nesterov M. Y. Antipin V. N. Khrustalev 《Russian Chemical Bulletin》1998,47(3):438-440
Hydrolysis of hexacyanocyclopropane (1a), ethyl 1,2,2,3,3-pentacyanocyclopropane-1-carboxylate (1b), 1,2,2,3,3-pentacyanocylopropane-1-carboxamide (1c), andN,N-dimethyl-1,2,2,3,3-pentacyanocylopropane-1-carboxamide (1d) in 95% acetic acid yieldsr-1,c-2,c-3-tricyanocyclopropane-t-1-carboxamide (3). The structure of3 was proved by X-ray diffraction analysis.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 454–456, March, 1998. 相似文献
80.
V. N. Khrustalev O. V. Shishkin S. V. Lindeman Yu. T. Struchkov M. A. Galkina Yu. G. Gololobov 《Russian Chemical Bulletin》1996,45(9):2172-2176
I-Adamantylmethyl 2-cyanoacrylate (1) was prepared by the reaction of 2-cyanoacryloyl chloride with 1-adamantylmethanol . 1,10-Decanediol bis-2-cyanoacrylate (2) was synthesized by transesterification of methyl 2-cyanoacrylate with 1,10-decanediol. Esters1 and2 were studied by X-ray structural analysis.Deceased in 1995.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 2288–2292, September, 1996. 相似文献