Optimization of reaction parameters for the sonophotocatalytic degradation of hydroquinone

Research on Chemical Intermediates - In the present work, the degradation of hydroquinone in synthetic wastewater under sonocatalytic, photocatalytic, and sonophotocatalytic conditions was...     

Relative Cohen–Macaulayness of bigraded modules

In this paper we study the local cohomology of finitely generated bigraded modules over a standard bigraded polynomial ring which have only one nonvanishing local cohomology with respect to one of the irrelevant bigraded ideals.     

Application and analysis of functionally graded piezoelectrical rotating cylinder as mechanical sensor subjected to pressure and thermal loads

The exact thermoelastic analysis of a functionally graded piezoelectrical (FGP) rotating cylinder is investigated analytically. The cylinder is subjected to a combination of electrical, thermal, and mechanical loads simultaneously. The structure is a simplified model of a rotational sensor or actuator. The basic governing differential equation of the system is obtained by using the energy method. A novel term, named as the additional energy, is introduced to exact the evaluation of the energy functional. The solution to the governing differential equation is presented for two types of boundary conditions including free rotating and rotating cylinders exposed to the inner pressure. The effect of the angular velocity is investigated on the radial distribution of various components. The mentioned structure can be considered as a sensor for measuring the angular velocity of the cylinder subjected to the pressure and temperature. The obtained results indicate that the electrical potential is proportional to the angular velocity.     

Biodegradable ultra high strength poly(L-lactide) rods for bone fixation

The hydrostatic molecular orientation technique was used to explore the highest mechanical improvements achievable for poly-L-lactide (PLLA). The mechanical attributes of these materials designed for bone fracture fixation devices, i.e. bending strength and modulus were measured and compared with those prepared by stretching method. The starting samples were prepared by conventional melt extrusion at 200 °C followed by hydrostatic extrusion at 140 °C using glycerin filled extruder. Uniaxially stretched rods were prepared by drawing in silicon oil at 120 °C. The physical properties of these rods are inadequate as mechanical supports in the dynamic healing process of the bone. Moreover, they underwent a marked strength deterioration when immersed in aqueous buffered solution for 90 days. On the other hand, the hydrostatic extrusion technique produced rods with progressively higher bending strength that showed only a small drop after 90 days hydrolytic degradation. Micrographs suggested a superior molecular orientation and packing, which could be associated with the improved performance. The hydrostatic extrusion technique proved to be a safe and effective approach for strengthening biodegradable polymeric materials for dynamic mechanical support in orthopedic medical devices.