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81.
Guldi DM Rahman GM Qin S Tchoul M Ford WT Marcaccio M Paolucci D Paolucci F Campidelli S Prato M 《Chemistry (Weinheim an der Bergstrasse, Germany)》2006,12(8):2152-2161
Dispersible single-walled carbon nanotubes grafted with poly(4-vinylpyridine), SWNT-PVP, were tested in coordination assays with zinc tetraphenylporphyrin (ZnP). Kinetic and spectroscopic evidence corroborates the successful formation of a SWNT-PVPZnP nanohybrid. Within this SWNT-PVPZnP nanohybrid, static electron-transfer quenching (2.0+/-0.1) x 10(9) s(-1) converts the photoexcited-ZnP chromophore into a radical-ion-pair state with a microsecond lifetime, namely one-electron oxidized-ZnP and reduced-SWNT. 相似文献
82.
Double alkylated L-glutamide-derived noncrystalline stationary phases Sil-DSG and Sil-DBG have been prepared by coupling N',N'-dioctadecyl-N-[4-carboxybutanoyl]-L-glutamide (DSG) and N',N',-dibutyl-N-[4-carboxybutanoyl]-L-glutamide (DBG) with aminopropylated silica (Sil-APS). TEM observations of DSG and DBG showed that lipid DSG can aggregate in organic solvents (methanol, chloroform, toluene, etc.) and self-assembled nano fibers are observed while such fibrous aggregations are not observed for DBG. The resulting chromatographic data have been provided information about its selective interaction with guest molecules (PAHs) in RP-HPLC. We have observed that the carbonyl groups in Sil-DSG exist in ordered state by forming a condensing thin layer over silica surface while DBG cannot form such an ordered state due to its lower order of short alkyl chain. The ordered carbonyl groups present in Sil-DSG promotes multiple carbonyl pi-benzene pi interactions with guest PAHs isomers which enhance the selectivity for these compounds. The contribution of pi-pi interactions was also supported by the substantial effects on the selectivity of benzene and nitrobenzenes. The effect of pi-electron containing solvent on the retention behavior of the PAHs was also studied. The selectivity for nucleic acid constituents, i.e. nucleosides and its bases were also evaluated by Sil-DSG and the selectivity for these compounds on Sil-DSG was compared with the selectivity of conventional polymeric ODS phase. It has been found that Sil-DSG provided higher selectivity for nucleic acid constituents than polymeric ODS and that HPLC packing materials can be efficiently employed for routine analysis of these compounds. The effect of methanol content on the separation behavior of nucleosides was also studied. 相似文献
83.
Inanaga S Kiyonaga T Rahman F Khanom F Namiki A Lee J 《The Journal of chemical physics》2006,124(5):054715
We measured angular distributions of HD and D2 molecules desorbed via the reactions H+DSi(100)-->HD [abstraction (ABS)] and H+DSi(100)-->D2 [adsorption-induced-desorption (AID)], respectively. It was found that the angular distribution of HD molecules desorbed along ABS is broader than that of D2 molecules desorbed along AID, i.e., the former could be fit with cos(2.0+/-0.2) theta, while the latter with cos(5.0+/-0.5) theta. This difference of the angular distributions between the two reaction paths suggests that their dynamic mechanisms are different. The observed cos2 theta distribution for the ABS reaction was reproduced by the classical trajectory calculations over the London-Eyring-Polanyi-Sato potential-energy surfaces. The simulation suggests that the HD desorption along the ABS path takes place along the direction of Si-D bonds, but the apparent angular distribution is comprised of multiple components reflecting the different orientations of D-occupied Si dimers in the (2 x 1) and (1 x 2) double domain structures. 相似文献
84.
A validated kinetic spectrophotometric method has been developed for the determination of losartan potassium in pure and dosage forms. The method is based on oxidation of the losartan potassium with alkaline potassium permanganate at room temperature (25 ± 1 °C). The reaction is followed spectrophotometrically by measuring the increase in absorbance with time at 603 nm, and the initial rate, fixed time (at 12.0 min) and equilibrium time (at 90.0 min) methods are adopted for constructing the calibration graphs. All the calibration graphs are linear in the concentration range of 7.5–60.0 μg mL?1 and the calibration data resulted in the linear regression equations of n? = ?6.422 × 10?7 + 1.173 × 10?5 C, A =3.30 × 10?4 + 5.28 × 10?3 C and A = ?2.09 × 10?2 + 1.05 × 10?1 C for initial‐rate, fixed time and equilibrium time methods, respectively. The limits of detection for initial rate, fixed time and equilibrium time methods are 0.71, 0.21 and 0.19 μg mL?1, respectively. The activation parameters such as Ea, ΔH?, ΔS?, and ΔG? are also determined for the reaction and found to be 87.34 KJ mol?1, 84.86 KJ mol?1, 50.96 JK?1 mol?1 and ?15.10 KJ mol?1, respectively. The variables are optimized and the proposed methods are validated as per ICH guidelines. The method has been applied successfully to the estimation of losartan potassium in commercial tablets. The performance of the proposed methods was judged by calculating paired t‐ and F‐ values. The analytical results of the proposed methods when compared with those of the reference method show no significant difference in accuracy and precision and have acceptable bias. 相似文献
85.
Mahnaz M.Abdi H.N.M.Ekramul Mahmud Luqman Chuah Abdullah Anuar Kassim Mohamad Zaki Ab.Rahman Josephine Liew Ying Chyi 《高分子科学》2012,(1):93-100
Electrical conductivity and optical properties of polypyrrole-chitosan(PPy-CHI) conducting polymer composites have been investigated to determine the optical transition characteristics and energy band gap of composite films.The two electrode method and I-V characteristic technique were used to measure the conductivity of the PPy-CHI thin films,and the optical band gap was obtained from their ultraviolet absorption edges.Depending upon experimental parameter,the optical band gap(Eg) was found within 1.30-2.32 eV as estimated from optical absorption data.The band gap of the composite films decreased as the CHI content increased.The room temperature electrical conductivity of PPy-CHI thin films was found in the range of 5.84×10-7-15.25×10-7 S·cm-1 depending on the chitosan content.The thermogravimetry analysis(TGA) showed that the CHI can improve the thermal stability of PPy-CHI composite films. 相似文献
86.
M. J.B. Alam A. K. Dikshit M. Banerjee I. Reza A. M. Rahman 《Journal of Dispersion Science and Technology》2013,34(6):843-849
From this study it was evident that outer peristaltic parts of waste tire granules gave the highest removal. Film and pore diffusions are the major factors controlling rates of sorption from solution by porous adsorbents. For sorption of 2,4‐D on waste tire rubber granules, the sorption rate coefficient of second‐order kinetic equation was utilized indirectly to determine the rate‐limiting step. The diffusion coefficient lies in the scale of 10?8 cm2/s, and the pore diffusion coefficient is in the range of 10?9–10?10 cm2/s. So both film and pore diffusion are rate limiting. Considering external mass transfer from fluid to particle, using the effect of initial concentration, and using the effect of adsorbent size, no conclusion was reached regarding rate‐controlling steps. It is apparent from the study that external mass transfer (film diffusion) as well as intra‐particle diffusion (pore diffusion) play significant roles in the sorption process for 2,4‐D removal from water onto rubber granules. 相似文献
87.
A generalized technique for the encapsulation of nano‐sized NiO particles by styrene‐2‐hydroxyethyl methacrylate copolymer 下载免费PDF全文
M. Shamim Hossan M. Abdur Rahman Klaus Tauer Hideto Minami Hasan Ahmad 《先进技术聚合物》2015,26(9):1047-1052
Encapsulation of nickel oxide (NiO) particles is of great interest to the researchers as such modification produces remarkable improvement in properties and versatility in application potential. In this investigation, nanosized NiO particles were first prepared by calcination of nickel hydroxide precursor obtained using a simple liquid‐phase process. The produced NiO particles were stabilized with oleic acid and then treated with tetraethylorthosilicate to produce NiO/SiO2 composite seed particles. Finally tri‐layered inorganic/organic composite particles were prepared by seeded copolymerization of styrene and 2‐hydroxyethyl methacrylate (HEMA) in the presence of NiO/SiO2 composite seed particles. The produced composite particles named as NiO/SiO2/P(S‐HEMA) were colloidally stable, and the obtained particles were characterized by Fourier transform infrared spectroscopy, scanning electron microscopy, X‐ray diffraction, X‐ray photoelectron spectroscopy and thermogravimetric analyses. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
88.
Instrumental neutron activation analysis (INAA) and atomic absorption spectrophotometry (AAS) were used to verify the protocols
for the quantification of zinc and magnesium in human whole blood. A study was conducted on group of volunteers consisting
of 131 patients having cardiovascular diseases (CVD) and 23 malignant hypertension (MH) patients along with 432 control subjects
with 218 male and 214 females. The elemental data of these elements has been exploited to establish the base line values in
control subjects. The possibility of any relationship between blood Mg and Zn levels with CVD and MH has also been investigated.
The mean blood Mg and Zn levels were found to be depleted in both CVD and MH patients as compared to normal subjects. In our
findings Mg and Zn were found to have an inverse relation with systolic and diastolic pressure. The reliability of the methods
was checked by the concurrent analysis of the IAEA reference material (RM) employing the optimized INAA and AAS protocols.
The determined values by both techniques were found to be in good agreement with the IAEA reference values. The elemental
data in whole blood samples of normal volunteers has also been compared with Mg and Zn contents reported by other countries. 相似文献
89.
M. Jafarzadeh I. A. Rahman C. S. Sipaut 《Journal of Sol-Gel Science and Technology》2009,50(3):328-336
A modified preparation of silica nanoparticles via sol–gel process was described. The ability to control the particle size
and distribution was found highly dependent on mixing modes of the reactants and drying techniques. The mixture of tetraethoxysilane
and ethanol followed by addition of water (Mode-A) produced monodispersed powder with an average particle size of 10.6 ± 1.40 nm
with a narrow size distribution. The freeze drying technique (FD) further improved the quality of powder. In addition, the
freeze dried samples have shown unique TGA decomposition steps which might be related to the well-defined structure of silica
nanoparticles as compared to the heat dried samples. DSC analysis showed that FD preserved the silica surface with low shrinkage
and generated remarkably well-order, narrow and bigger pore size and pore volume and also large endothermic enthalpies (ΔH
FD = −688 J g−1 vs. ΔH
HD = −617 J g−1) that lead to easy escape of physically adsorbed water from the pore at lower temperature. 相似文献
90.
Hadi Beitollahi Jahan-Bakhsh Raoof Hassan Karimi-Maleh Rahman Hosseinzadeh 《Journal of Solid State Electrochemistry》2012,16(4):1701-1707
This paper reports the selective determination of isoproterenol (IP) in the presence of uric acid (UA) and folic acid (FA)
using 2,7-bis(ferrocenyl ethyl)fluoren-9-one modified carbon nanotube paste electrode (2,7-BFCNPE) in 0.1 M phosphate buffer
solution (PBS) (pH 7.0). The bare carbon paste electrode does not separate the voltammetric signals of IP, UA, and FA. However,
2,7-BFCNPE not only resolved the voltammetric signals of IP, UA, and FA with potential differences of 150, 325, and 475 mV
between IP–UA, UA–FA, and IP–FA, respectively, but also dramatically enhanced the oxidation peak currents of them when compared
to bare carbon paste electrode. In PBS of pH 7.0, the oxidation current increased linearly with two concentration intervals
of IP, one is 0.08 to 17.5 μM and the other is 17.50 to 700.0 μM. The detection limit (3σ) obtained by DPV was 26.0 ± 2 nM. The practical application of the modified electrode was demonstrated by determining IP
in IP injection, urine, and human blood serum. 相似文献