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Herein, we introduce a facile, inexpensive and fast, and additive-/template-free method to fabricate highly stable nickel hydroxide nanofibers for supercapacitor applications. Ni(OH)2 nanofibers were electrodeposited on electro-etched carbon fiber paper by a potential step method (Ni(OH)2-ECFs) and characterized using scanning electron microscopy and X-ray diffraction analysis. Electrochemical performance of Ni(OH)2-ECF was studied in symmetric two-electrode assembly by cyclic voltammetry, galvanostatic charge–discharge method, and electrochemical impedance spectroscopy. A specific capacitance of 277.5 F g?1 was achieved for the symmetric supercapacitor based on two identical Ni(OH)2-ECFs. Our findings demonstrate high-rate capability with excellent stability (approximately 100 % capacitance retention) for Ni(OH)2-ECF supercapacitor, originated from the intimate contact between Ni(OH)2 and ECF. Our studies suggest the Ni(OH)2-ECF electrode as an excellent material for supercapacitor applications. 相似文献
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Synthesis,Structural and Energetic Properties of Copper(II) Perchlorate Complex with Aminoguanidine
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The complexation of copper(II) perchlorate with aminoguanidine hemesulfate (AGHS) yield related mononuclear complex bis(aminoguanidine)copper(II) perchlorate; [Cu(AG)2](ClO4)2 ( I ). The characterization of complex I was done by elemental analysis, electronic spectra, IR studies, and X‐ray diffraction. From analytical data, a stoichiometry of 1:2 of metal to ligand was determined for the complex. The structure consists of centrosymmetric square planar [Cu(AG)2]2+ cations and perchlorate counterions. The CuII atom is four‐coordinate by two imine N atoms and two amine N atoms from two aminoguanidine ligands, forming a slightly distorted square‐planar coordination. In the crystal structure, molecules are linked through intermolecular N–H ··· O hydrogen bonds, forming a network. The thermal decomposition process of this complex was investigated through differential scanning calorimetry (DSC) and the sensitivities toward impact and friction were assessed using a BAM drophammer and a BAM friction tester. 相似文献
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Mohammad Hakimi Zahra Mardani Keyvan Moeini Nourollah Feizi Fabian Mohr 《Journal of Coordination Chemistry》2017,70(7):1247-1259
The binding modes of 2-((2-aminoethyl)amino)ethanol-based ligands were explored using the Cambridge Structural Database (CSD). To extend this field, a new cadmium complex containing 2-((2-aminoethyl)amino)ethanol (AEAE), [Cd(AEAE)2][Cd(AEAE)2]′[CdI4]2 (1), was prepared and characterized by spectroscopic methods and single-crystal X-ray diffraction. The reaction of AEAE with a 1:1 mixture of CdI2 and HgI2 was also investigated. The complex, [Cd(AEAE)2][I2Hg(μ-I2)2HgI2] (2), was synthesized and characterized. Compounds 1 and 2 represent the first tridentate binding modes of an AEAE type ligand with Cd2+. Geometrical investigation for complexes containing Cd(Namine2Oalcohol)2, CdIn, and HgIn environment were carried out using the CSD software. Also different possible diastereomers which can be formed in coordination of a pair of tridentate AEAE ligands in octahedral geometry were studied and discussed. 相似文献
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Avat Arman Taherpour Farshid Keyvan 《Phosphorus, sulfur, and silicon and the related elements》2013,188(8):1604-1614
Various empty carbon fullerenes with different carbon atoms have been obtained and investigated. The dithiazolyl radicals have shown important electron-transfer properties. Topological indices are digital values that are assigned based on chemical composition. These values are purported to correlate chemical structures with various chemical and physical properties. They have been successfully used to construct effective and useful mathematical methods to establish clear relationships between structural data and the physical properties of these materials. In this study, the number of carbon atoms in the fullerenes was used as an index to establish a relationship between the structures of 2,3-naphthalene-1,3,2-dithiazolyl (NDTA), 2,3-quinoxaline-1,3,2-dithiazolyl (QDTA), and 1,2,5-thiazolo[3,4-b]-1,3,2-dithiazolo[3,4-b]pyridazin-2-yl (TDP-DTA), radicals, 1–3 as molecular conductor radicals and fullerenes Cn (n = 60, 70, 76, 82, and 86), which create [1,3,2-DTA(s)]@Cn, A-1 to A-5 (NDTA]@Cn), B-1 to B-5 ([QDTA]@Cn), and C-1 to C-5 ([TDP-DTA]@Cn). The relationship between the number of carbon atoms and the free energies of electron transfer (ΔGet(1) to ΔGet(4) ) are assessed using the Rehm–Weller equation for A-1 to A-5, B1 to B-5, and C-1 to C-5 supramolecular [1,3,2-DTA(s)]@Cn complexes. Calculations are presented for the four reduction potentials ( Red.E1 to Red.E4 ) of fullerenes Cn . The results were used to calculate the four free energies of electron transfer (ΔGet(1) to ΔGet(4) ) of supramolecular complexes A-1 to A-18, B-1 to B-18, and C-1 to C-18 (5–60) for fullerenes C60 to C300. 相似文献
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Mir Mohammad Alavi Nikje Mohammadreza Khanmohammad Amir Bagheri Garmarudi Keyvan Ghasemi 《高分子科学杂志,A辑:纯化学与应用化学》2013,50(1):116-120
Epoxy based nanocomposite samples containing SiO2 nanoparticles (0.0–3.0 %w) were prepared for physical and mechanical evaluation. Some thermomechanical and physical properties of samples were investigated using dynamic mechanical analysis (DMA), tensile strength, hardness and abrasion tests. The main aim of experimentation was to realize the optimum amount of nano-SiO2 which would demonstrate the best improving effect on mechanical and physical properties of nanocomposite samples and finding how significant a factor is for improving in physical and mechanical properties. Analysis of variance (ANOVA) was applied for optimization of SiO2 content in epoxy based nanocomposites. 相似文献
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Moslem Mansour Lakouraj Mahmood Tajbakhsh Farhad Ramzanian-Lehmali Keyvan Ghodrati 《Monatshefte für Chemie / Chemical Monthly》2008,139(5):537-541
Oxidative deprotection of trimethylsilyl and tetrahydropyranyl ethers, and deprotection of phenylhydrazones, semicarbazones,
and oximes to their corresponding carbonyl compounds carried out in water at reflux condition using ionene supported peroxodisulfates
is reported. The reagents are recyclable and products are obtained in excellent yield under environmentally benign conditions
without overoxidation to carboxylic acid.
Correspondence: Moslem Mansour Lakouraj, Department of Chemistry, Mazandaran University, Babolsar, Iran. 相似文献
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Mohammad Hakimi Fereshteh Sadeghi Nourollah Feizi Keyvan Moeini Monika Ku
erkov Michal Duek 《Acta Crystallographica. Section C, Structural Chemistry》2019,75(6):750-757
Two new N‐oxide compounds, namely glycinium 2‐carboxy‐1‐(λ1‐oxidaneyl)‐1λ4‐pyridine‐6‐carboxylate–glycine–water (1/1/1), C2H6NO2+·C7H4NO5?·C2H5NO2·H2O or [(2,6‐HpydcO)(HGLY)(GLY)(H2O)], 1 , and methyl 6‐carboxy‐1‐(λ1‐oxidaneyl)‐1λ4‐pyridine‐2‐carboxylate, C8H7NO5 or 2,6‐HMepydcO, 2 , were prepared and identified by elemental analysis, FT–IR, Raman spectroscopy and single‐crystal X‐ray diffraction. The X‐ray analysis of 1 revealed an ionic compound containing a 2,6‐HpydcO? anion, a glycinium cation, a neutral glycine molecule and a water molecule. Compound 2 is a neutral compound with two independent units in its crystal structure. In addition to the hydrogen bonds, the crystal network is stabilized by π–π stacking interactions of the types pyridine–carboxylate and carboxylate–carboxylate. The thermodynamic stability and charge‐distribution patterns for isolated molecules of 2,6‐H2pydcO and 2,6‐HMepydcO, and their two similar derivatives, pyridine‐2,6‐dicarboxylic acid (2,6‐H2pydc) and dimethyl 1‐(λ1‐oxidaneyl)‐1λ4‐pyridine‐2,6‐dicarboxylate (2,6‐Me2pydcO), were studied by density functional theory (DFT) and natural bond orbital (NBO) analysis, respectively. The ability of these compounds and their analogues to interact with nine selected biomacromolecules (BRAF kinase, CatB, DNA gyrase, HDAC7, rHA, RNR, TrxR, TS and Top II) was investigated using docking calculations. 相似文献
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Mir Mohammad Alavi Nikje Sahebeh Tamaddoni Moghaddam Maede Noruzian Mohammad Amin Farahmand Nejad Keyvan Shabani Moslem Haghshenas Saeed Shakhesi 《Colloid and polymer science》2014,292(3):627-633
Novel magnetic polyurethane flexible foam nanocomposites were synthesized by incorporation of aminopropyltriethoxysilane (APTS) functionalized magnetite nanoparticles (MNPs) via one-shot method. The functionalized MNPs (Fe3O4@APTS) were synthesized by co-precipitation of the Fe2+ and Fe3+ with NH4OH and further functionalization with APTS onto the surface of MNPs by sol–gel method. The magnetic core-shell NPs were used up to 3.0 % in the foam formulation and the magnetic nanocomposites prepared successfully. The results of thermogravimetric analysis (TGA) showed an increasing in thermal stability of polyurethane nanocomposite foam at initial, 5 and 10 %, and maximum thermal decomposition temperatures by incorporation of Fe3O4@APTS. In addition SEM images revealed the uniformity of the foam structures and decreasing in pore sizes. Furthermore, VSM result showed super paramagnetic behavior for Fe3O4@APTS-PU nanocomposites. 相似文献
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Hollow microblocks of [Zn(anic)_2], as a novel coordination compound, were synthesized using 2-aminonicotinic acid(Hanic) and zinc(Ⅱ) nitrate tetrahydrate. The chemical composition of the zinc complex, ZnC_(12)H_(10)N_4O_4, was determined by Fourier transform infrared(FTIR) spectroscopy and elemental analysis. The synthesized zinc complex was used as a precursor to produce ZnO nanostructures by calcination at 550 °C for 4 h. Morphological studies by scanning electron microscopy and transmission electron microscopy revealed the formation of porous microbricks of ZnO nanoparticles. N_2 adsorption-desorption analysis showed that the obtained ZnO microbricks possess a mesoporous structure with a surface area of 8.13 m~2/g and a pore size of 22.6 nm. The X-ray diffraction pattern of the final product proved the formation of a pure ZnO composition with a hexagonal structure. Moreover, FTIR analyses showed that the 2-aminonicotinic acid ligand peaks were absent after the calcination step. Diffuse reflectance spectroscopy was used to determine the band gap energy of the produced ZnO and it was about 3.19 eV. To investigate the photocatalytic activity of the porous ZnO nanostructure, a series of photocatalytic tests were carried out to remove Congo red, as a representative toxic azo dye, from aqueous solution. The results show that the product can be used as an efficient photocatalyst for waste water treatment with high degradation efficiency. 相似文献