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The difficulties of observing sub-Rouse modes (SRM) and Rouse modes (RM) in acrylate polymers has resulted in many arguments and disputes concerning the nature of their glass-rubber transition. Because different modes have different sensitivity to external perturbations, the two-dimensional dynamic analysis mechanical spectra (2D-DMS) was introduced to detect the local segments motion (LSM), SRM, and RM in poly(butyl acrylate) (PBA) and poly(ethyl acrylate) (PEA). The results of the asynchronous spectra showed the LSM, SRM, and RM of PBA and PEA are located, respectively, at about (?46 ~ ?29°C), (?28 ~ ?10°C), (?4 ~ 27°C), and about (?12 ~ ?5°C), (?3 ~ 6°C), and (10 ~ 44°C). Furthermore, the LSM and SRM of PBA and PEA have an overlap in the synchronous spectra. This is suggested to be caused by the higher coupling effect in PBA and PEA when compared with strong glass formation polymers, like polyisobutylene (PIB). 相似文献
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本文合成了既含聚醚柔性链、又含刚性介晶结构单元的活性增韧剂(LCEU(PEG)),用其改性E-51/dicy固化体系。系统研究了增韧剂中柔性链分子量与改性体系动态力学性能、冲击性能之间的关系。动态力学分析表明:改性体系的100℃以下的模量没有降低,并且随LCEU(PEG)中柔性链分子量的降低而略有升高;Tg随LCEU(PEG)的加入而略微降低,随改性剂中柔性链分子量的降低而略微增大。冲击实验结果表明:当LCEU(PEG)柔性链分子链为1000、600时,改性体系的冲击强度可以提高6~7倍;而当LCEU(PEG)柔性链分子链为400、200时冲击强度最大只能提高4倍。 相似文献
34.
Trypsin treatment is frequently used during chromosome preparation for removal of cellular contaminants, and ethidium bromide (EB) staining of bands is often used to facilitate high-resolution observations by optical microscopy. However, conventional optical microscopy is unable to visualize potential aberrations of chromosome structures caused by these physicochemical treatments. In this article, we use atomic force microscopy (AFM) in the tapping mode to obtain and analyze high-resolution images of chromosome surface structure damage associated with trypsinization and EB treatment. According to our results, the trypsin-based digestion effects became more severe as incubations increased across a range from 10 to 40 s; a digestion time of 10 to 20 s appeared to be most suitable for observation by AFM. In terms of chromosomal damage induced by EB treatment, addition of EB into the media of cultured human blood cells induced chromosomal breakage in a dose-dependent fashion, and the results indicate centromeric region damnifyed severer than arms. Together, these results indicate that EB staining and the standard chromosomal preparative techniques of trypsinization can induce chromosomal damage that may affect the observed results. 相似文献
35.
含刚性链节和脲端基聚醚增韧剂改性环氧树脂的研究———反应活性及力学性能 总被引:8,自引:0,他引:8
合成了一系列既含环氧丙烷聚醚(PPG)柔性间隔基、又含刚性介晶结构单元的端脲基活性改性剂(LCEUPPG),并对其改性环氧树脂E 51/双氰双胺(E 51/dicy)体系的固化反应活性、改性剂含量对增韧体系动态力学性能及冲击性能的影响进行了研究.结果表明:LCEUPPG的加入对固化体系具有明显的增韧作用,冲击强度提高了3~7倍;其对E 51/dicy固化反应具有明显的促进作用,可使固化反应表观活化能(Ea)降低50~70KJ/mol、固化温度降低30~40℃;体系的玻璃化转变温度(Tg)略有下降,但模量基本不降低或略有升高;β 转变向低温方向移动. 相似文献
36.
We propose and numerically investigate a kind of high-efficiency T-shaped optical circulator in a two-dimensional square-lattice photonic crystal. In the T-shaped structure, the single-direction light transmission for 90° light-bending is achieved by coupling two magneto-optical rods. And aided with a side-coupled cavity, two paths of single-direction 90° light-bending are effectively combined, which realizes the nonreciprocal light transmission for two waveguides arranged and linked along a straight line. The optical properties of the system are investigated by finite element method. The circulator considered here can be used for isolating light reflections and improving system stabilization in designing photonic crystal integrated circuits. 相似文献
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38.
功能基化介晶高聚物增韧环氧树脂性能研究——材料断裂面形态结构与力学性能的关系 总被引:7,自引:0,他引:7
在系统研究含介晶基团的高聚物LCEUPPG增韧环氧树脂E 51/双氰双胺(dicy)固化体系固化反应活性、反应机制、动态力学行为及冲击性能的基础上,以扫描电镜(SEM)为手段,对材料断裂面的形态结构进行了研究,并对体系的形态结构与动态力学行为、冲击性能之间的关系进行了探讨.结果表明,改性后材料断裂面的形态均呈微观两相网络结构,明显不同于未改性体系,正是由于两相网络结构的存在,导致了改性体系的冲击强度大幅度提高. 相似文献
39.
Initial State Interactions and J/ψ Production-Rate Suppression in High Energy P-A Collisions 下载免费PDF全文
The influence of the initial state intcractions on the J/ψ production-rate supression in p-A collisions is studied. The incident proton energies decrease due to the inelastic interactions with the target nucleus. Considering energy loss of the incident proton,the data are well reproduced by using the final state interaction cross section σfabs=2.1mb. 相似文献
40.
咪唑封端聚氨酯予聚体改性环氧树脂E-51/双氰双胺固化体系性能研究 总被引:2,自引:0,他引:2
以聚丙二醇PPG10 0 0、甲苯二异氰酸酯 (TDI)、咪唑为原料 ,合成了咪唑封端的聚氨酯予聚体 ,简称扩链脲TIEU .利用DSC、粘弹谱仪、冲击试验机及扫描电镜 (SEM)等手段对TIEU改性的环氧树脂E 5 1/双氰双胺(dicy)固化体系的反应活性、动态力学行为、冲击性能、断裂面形态结构进行了系统研究 .实验结果表明 ,改性后的E 5 1 dicy体系反应活性明显提高 ,固化反应的表观活化能由未改性体系的 131kJ mol降至 75~ 80kJ mol.与咪唑促进体系比较结果显示 ,两种固化反应的促进机制具有一定的差异 .另外与未改性体系相比 ,经过改性的环氧树脂体系冲击强度提高 2~ 3倍 ,而玻璃化温度和模量基本不变 ,冲击断面呈韧性断裂 相似文献