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181.
Yan Zhao Xingbin Yang Ru Jiang Xiaoli Sun Wenmin Liu Shengyong Zhang 《Analytical sciences》2006,22(5):747-751
The investigation on capillary electrophoretic enantioseparation of six synthetic compounds containing vicinal diol groups has been undertaken to acquire the optimum conditions using native beta-cyclodextrin (beta-CD) as chiral selector and borate as a background electrolyte. The separation was carried out in an uncoated capillary (58.5 cm x 75 microm i.d., effective length 48.5 cm) and the effects of several important factors were investigated in detail. The results showed that beta-CD as a chiral selector exhibited good enantioselectivity and that the enantioseparation was greatly influenced by the structure of the diols, the borate concentration and the buffer pH. The optimum performance was obtained for the chiral vicinal diols under the conditions of 200 mM borate buffer of pH 9.8 containing 1.7% beta-CD at an applied voltage of 15 kV and a capillary temperature of 20 degrees C. Under the conditions, four diols were baseline separated with fast analysis time and the good theoretical plate numbers (above 10 x 10(4)) and favorable migration-time reproducibilities (RSDs below 3.0%) were obtained. The separation results were satisfactory. 相似文献
182.
A simple and sensitive method was conducted for the determination of trace amounts of proteins with benzeneazo-8-acetylamino-1-naphthol-3,6-disulfonic acid sodium salt (azophloxine, AP) using a Rayleigh light-scattering (RLS) technique. At pH 2.60 and in the presence of an emulsifier OP microemulsion, the RLS of AP can be greatly enhanced by proteins, owing to the interaction between AP and protein. The enhanced intensity is proportional to the concentration of proteins. Four proteins, including bovine serum albumin (BSA), human serum albumin (HSA), lysozyme (Lys) and gamma globulin (gamma-G) have been tested. For example, the linear range of BSA was 0 - 0.06 microg mL(-1) with detection limits of 2.38 ng mL(-1). The method was applied to the analysis of protein in human urine and penicillin samples with satisfactory results. The relative standard deviation was in all instances less than 4.0%, and the recovery was in the range of 97.5 - 104%. 相似文献
183.
Positive Steady States of a Prey-predator Model with Diffusion and Non-monotone Conversion Rate 总被引:1,自引:0,他引:1
Rui PENG Ming Xin WANG Wen Van CHEN 《数学学报(英文版)》2007,23(4):749-760
In this paper, we study the positive steady states of a prey-predator model with diffusion throughout and a non-monotone conversion rate under the homogeneous Dirichlet boundary condition. We obtain some results of the existence and non-existence of positive steady states. The stability and uniqueness of positive steady states are also discussed. 相似文献
184.
In the present work, ferrites with compositions of (Ni0.27Zn0.64Cux)Fe1.98O4 (x=0.1, 0.2) were prepared by conventional ceramic methods. The relationship between the microstructure and the temperature dependence of relative initial permeability was investigated. It was found that intergranular pores in the ferrites generate large demagnetizing fields, reducing the temperature dependence of the effective anisotropy field Heff, and decreasing the temperature dependence of the relative initial permeability accordingly. However, intragranular pores pin the movement of domain walls. Compared with the permeability induced by domain wall motion, the permeability that resulted from the spin rotation is more sensitive to temperature. As a result, the relative initial permeability of ferrites becomes more sensitive to temperature with increasing micropores within grains. 相似文献
185.
微通道板增益疲劳机理研究 总被引:2,自引:0,他引:2
微通道板的增益疲劳是微通道板的主要问题之一,本文分析了微通道板的表面结构模型,同通道板活性表面上碱金属的逸出和碳的增加是导致微通道板的增益疲劳的主要原因,另外,探讨碱金属逸出的机理和碳污染的来源,介绍延长微通道板工作寿命的有效方法。 相似文献
186.
187.
Differentkindsofopenchaincrownethershavebeensynthesizedasthemodelcompoundsofionophoresandtheirinteractionswithsodium,potassiumandrareearthionshavealsobeenstudiedl'z.PanshowedCe(III)yieldedalf1complexwithl,8-bis(8'-quinolyloxy)-3,6-dioxaandtheCe(IIl)ioncoordinatedbothtoetheroxygenandquinolinenitrogenatoms3.TUmInleridentifiedtwolanthanidenitratecomplexeshavingastoichiometryof3:2(3RE:2L)'.InordertostUdythefunctionsofbothquinolineandbenzenering,introducedintothepolyetherchain,a1inearpolyether… 相似文献
188.
本文介绍了我们研制的“运动粒子瞬态激光全息测试仪”电子线路.该电路经严格的逻辑设计及计算,采用了10MHz时钟电路,并将1MHz的时钟信号巧妙地引入门控电路中,同时在技术上采用了行之有效的措施,消除了可能产生0.1μs的随机误差,时间间隔达到了(1~9)±0.1μs的精度,所输出的激光双脉冲能量接近,整机抗干抗能力强,一次性试验成功率高,可精确地测量雾化粒子场中的微粒的速度、形状、大小及其分布,收到了良好的使用效果. 相似文献
189.
ShiYanYANG ZeMinXIE ChunJuanLIU LiHuaLIU WeiGAO 《中国化学快报》2002,13(12):1225-1226
A new kind of polyorganozircosilazane as Si/Zr/C/N-based ceramic precursor was synthesized from the condensation reaction of hexamethyleyclotrisilazane lithium salts(D3^NLi)and zirconium tetrachloride(ZrCl4).In the presence of N,N,N’,N’-tetramethyl ethylene diamine(TMEDA),polyorganozircosilazane was obtained in high yield. 相似文献
190.