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101.
S. Unterricker Kim Jung Ho W. Stolz D. Degering 《Journal of Radioanalytical and Nuclear Chemistry》1988,122(2):271-278
The underground radiation conditions in the mining district of Freiberg and in a rock salt environment of the Werra district were investigated. In a salt mine a very low natural activity level can be found. For selection of proper shielding materials a low-level -spectrometer and an optimum sample geometry must be used. The photopeak differences between sample and blank are small in most cases. Considerable differences can be found in the continuous background below 0.7 MeV. 相似文献
102.
Chi YS Jung YH Choi IS Kim YG 《Langmuir : the ACS journal of surfaces and colloids》2005,21(10):4669-4673
In this paper, we report surface-initiated d(A-T) polymerization by Taq DNA polymerase as a method for constructing DNA-tethered surfaces using an enzyme. The enzymatic polymerization was conducted successfully via two steps: tethering of oligo d(A-T)s onto the surface presenting carboxylic acids by amide coupling and surface-initiated polymerization using Taq DNA polymerase. In this enzymatic polymerization process, the design and construction of carboxylic acid-presenting surfaces were found to be an important factor: DNA growth did not occur on the gold surface coated only with the self-assembled monolayer (SAM) of 16-mercaptohexadecanoic acid (MHDA), but effectively proceeded on the surfaces presenting mixed SAMs of MHDA and 1-pentadecanethiol. The coupling of oligo d(A-T)s and the subsequent DNA polymerization reaction were characterized by polarized infrared external reflectance spectroscopy, ellipsometry, X-ray photoelectron spectroscopy, and atomic force microscopy. 相似文献
103.
Pyun DK Kim BJ Jung HJ Kim JH Lee JS Lee WK Lee CH 《Chemical & pharmaceutical bulletin》2002,50(3):415-418
A new series of 1beta-methylcarbapenems 1a-d bearing 5-methyl-4-mercaptopyrrolidinone rings has been prepared and evaluated for in vitro antibacterial activity and pharmacokinetic parameters. Most compounds showed excellent antibacterial activity and high stability to dehydropeptidase-1. We have synthesized optically active 5-methyl-4-hydroxypyrrolidinones from enantiomerically pure aziridine esters. 相似文献
104.
Ana C. D. Medeiros Lidiane P. Correia Mônica O. da S. Simões R. O. Macêdo 《Journal of Thermal Analysis and Calorimetry》2007,88(2):311-315
A number of disintegrants
are available on the market. They improve tablets’ disintegration. The
objective of this work is the comparison of the technological quality parameters
of disintegrants using different analytical techniques. Three batches of disintegrants
and their binary mixtures (water:disintegrants) were investigated. Cooling
experiments were used from –30 up to 200°C. The data obtained showed
calorimetric differences between the samples. In the binary mixtures water
showed different crystallization behaviour from the one found in the literature.
According to the results DSC technique helped the quality control of different
disintegrants. 相似文献
105.
The energy levels of a series of para substituted N,N-dimethylanilines p-MHnMe3?n C6H4NMe2 (n = 0?3, M = C or Si) for the ground and lower lying excited states have been determined in acetonitrile solution. The levels for the carbon compounds are all slightly destailized relative to N,N-dimethylaniline and the effects are rather insensitive to n. The stabilizations produced by silicon substituents on all levels are markedly affected by silicon's substituents, showing increasing perturbations with increasing n. It is concluded that variations in the interaction of the σ* system of the silyl substituent with the aniline π system, and not d orbital interactions, account for the trends observed. 相似文献
106.
Self-assembling structures of long-chain phenyl glucoside influenced by the introduction of double bonds 总被引:1,自引:0,他引:1
Jung JH John G Yoshida K Shimizu T 《Journal of the American Chemical Society》2002,124(36):10674-10675
Four long-chain phenyl glucoside amphiphiles possessing a saturated or unsaturated long alkyl chain group as the self-assembling unit of a highly organized molecular architecture were synthesized. Their self-assembling properties were investigated by EF-TEM, SEM, CD, FT-IR, and XRD. Compound 2 possessing one double bond in the lipophilic portion showed twisted helical fibers, which formed a bilayered structure with a 3.59 nm period, while compound 3 showed the helical ribbons and left-handed nanotubular structures with 150-200 nm inner diameters and ca. 20 nm of wall. Very interestingly, compound 4 possessing three double bonds showed a nanotubular structure with ca. 70 nm of inner diameter through a helical ribbon, which formed a loose bilayered structure with 4.62 nm. These results indicate that self-assembling properties strongly depend on the number of cis double bonds. 相似文献
107.
The separation, characterization, and determination of mixtures of alkyl ether sulfates (AES) and fatty acids (C10-C16) in background electrolytes (BGEs) containing acetonitrile (ACN)-water mixtures is addressed. Due to inhibition of the ionization of the carboxylate groups, the migration time and the resolution between the fatty acids decreased when the water content of the BGE was reduced, but efficiency and resolution between the AES oligomers improved. The migration times increased and resolution improved by substituting 5% ACN by an equivalent amount of dioxane. A complete separation of the two surfactant classes, up to the AES oligomers with 8 ethylene oxide units (EOs) with respect to C10, with excellent resolution between the AES oligomers, while preserving a satisfactory resolution between the fatty acids, was achieved with a BGE containing 5 mM trimethoxybenzoic acid, 7 mM dipentylamine, 85% ACN, 5% dioxane, and 10% water. The two surfactant classes were increasingly resolved by further reducing the water content of the BGE. Thus, C2 (acetate) was resolved from the AES oligomers up to 7 EOs using 90% ACN and 5% dioxane, but the resolution between the heavier fatty acids was poor with this BGE. Identification of the AES oligomers was eased by the excellent regularity of the successive migration times; thus, within each AES subclass or series of oligomers with the same number of carbon atoms in the alkyl chain, the migration times decreased following a mild curve as the number of EOs increased. The way how the data obtained by indirect photometry (corrected peak areas that are proportional to the molar concentrations) should be managed to avoid systematic error when the calibration curve is constructed using an AES standard with an oligomer distribution different from that of the samples is discussed and equations are given. Decyl sulfate was successfully used as internal standard. The detection limits (S/N = 3) were of ca. 2 microM for individual AES oligomers. 相似文献
108.
Sautter A Kaletas BK Schmid DG Dobrawa R Zimine M Jung G van Stokkum IH De Cola L Williams RM Würthner F 《Journal of the American Chemical Society》2005,127(18):6719-6729
A molecular square with dimensions of about 4 nm, incorporating sixteen pyrene chromophores attached to four ditopic bay-functionalized perylene bisimide chromophores, has been synthesized by coordination to four Pt(II) phosphine corner units and fully characterized via NMR spectroscopy and ESI-FTICR mass spectrometry. Steady-state and time-resolved emission as well as femtosecond transient absorption studies reveal the presence of a highly efficient (>90%) and fast photoinduced energy transfer (k(en) approximately equal to 5.0 x 10(9) s(-1)) from the pyrene to the perylene bisimide chromophores and a very fast and efficient electron transfer (>94%, k(et) approximately equal to 5 x 10(11) up to 43 x 10(11) s(-1)). Spectrotemporal parametrization indicates upper excited-state electron-transfer processes, various energy and electron-transfer pathways, and chromophoric heterogeneity. Temperature-dependent time-resolved emission spectroscopy has shown that the acceptor emission lifetime increases with decreasing temperature from which an electron-transfer barrier is obtained. The extremely fast electron-transfer processes (substantially faster and more efficient than in the free ligand) that are normally only observed in solid materials, together with the closely packed structure of 20 chromophoric units, indicate that we can consider the molecular square as a monodisperse nanoaggregate: a molecularly defined ensemble of chromophores that partly behaves like a solid material. 相似文献
109.
Micropatterning of a semicrystalline poly(vinylidene fluoride) (PVDF) solution was performed by a temperature controlled capillary micromolding where the rate of solvent evaporation was controlled by substrate temperature. In order to choose proper solvents for micropatterning, we have investigated the solubility of PVDF in various organic solvents and crystal structures of the PVDF bulk films cast from the solvents. The films prepared from the polar solvents such as dimethylformamide (DMF), dimethyl sulfoxide (DMSO) dominantly showed γ type crystals regardless of preparation temperature, while the films from tetrahydrofuran (THF) exhibit α type crystals and the ones from acetone and methyl ethyl ketone (MEK) show the characteristics of both α- and γ-PVDF. The quality of micropatterns and shapes of the PVDF crystals in the patterns significantly depend on solvent evaporation rates. Micropatterns of PVDF formed in DMF at 120 °C showed the best uniformity in shape. Crystals of the PVDF nucleated at the center regions of microchannels tended to be elongated with the b-axis of γ-PVDF crystals along the channels as the concentration of the solution decreased. In contrast, crystals nucleated at the corner regions of the channels had their b-axis oriented perpendicular to the channels. In line patterns with the width of 2 μm, the corner nucleated crystals were dominant and a resulting bamboo-like crystalline microstructure was observed in which the b-axis of γ-PVDF crystals, fast growth direction, is oriented normal to the microchannels. The crystal structures of the bulk films and the micropatterns were characterized by X-ray diffractometer, Fourier transform infrared spectroscope in Attenuated Total Reflection mode, Polarized Optical and Scanning Electron Microscope. 相似文献
110.
Jung-Hoon Oh Mun-Chual Rho Hyeong Kyu Lee Jae Nyoung Kim Sang-Hun Jung 《Tetrahedron letters》2004,45(38):7077-7079
Asymmetric synthesis of four possible stereoisomers of (9,10)-epoxyheptadecan-4,6-diyn-3-one was accomplished, and the absolute configuration of the naturally occurring (9R,10S)-epoxyheptadecan-4,6-diyn-3-one (1) was elucidated. 相似文献