Enynones in organic synthesis. II. An electron transfer mediated synthesis of methylenecyclopentenones

The electrocyclizaton of enynones to methylenecyclopentenones is markedly accelerated by phenols and catechols having a low oxidation potential.     

Muon spin relaxation and susceptibility studies of the pure and diluted spin 1/2 kagomé-like lattice system (CuxZn(1-x))3V2O7(OH2) 2H2O

Muon spin relaxation and magnetic susceptibility measurements have been performed on the pure and diluted spin 1/2 kagomé system (CuxZn(1-x))3V2O7(OH)2 2H2O. In the pure x=1 system we found a slowing down of Cu spin fluctuations with decreasing temperature towards T approximately 1 K, followed by slow and nearly temperature-independent spin fluctuations persisting down to T=50 mK, indicative of quantum fluctuations. No indication of static spin freezing was detected in either of the pure (x=1.0) or diluted samples. The observed magnitude of fluctuating fields indicates that the slow spin fluctuations represent an intrinsic property of kagomé network rather than impurity spins.     

Local magnetic susceptibility of the positive muon in the quasi-one-dimensional S=1/2 antiferromagnet dichlorobis (pyridine) copper (II)

We report muon spin rotation measurements of the local magnetic susceptibility around a positive muon in the paramagnetic state of the quasi-one-dimensional spin 1/2 antiferromagnet dichlorobis (pyridine) copper (II). Signals from three distinct sites are resolved and have a temperature dependent frequency shift which is significantly different than the magnetic susceptibility. This difference is attributed to a muon induced perturbation of the spin 1/2 chain. The obtained frequency shifts are compared with transfer matrix density-matrix renormalization-group numerical simulations.     

Distributed three-dimensional fiber Bragg grating refractometer for biochemical sensing

We demonstrate a three-dimensional (3-D) distributed refractometer that measures refractive index in a small volume. The sensor is based on an evanescent-wave fiber Bragg grating that is interrogated by low-coherence spectral interferometry. The measurement can be performed on a short time scale without the need for a mechanical scan. The new sensor was used to simultaneously measure glucose concentration in several droplets along a single sensor and to interrogate the time-dependent evaporation process of a water droplet. The new measurement technique might enable novel 3-D distributed sensors to be developed and multiple discrete measurements to be made in a small volume.     

Space charge effects in a gyrotron employing a solid electron beam

The influence of space charge forces on the performance of a single cacity gyrotron oscillator which uses a solid electron beam was investigated. It was found that space charge effects cause a large efficiency degradation as the beam current is increased, if the other experimental parameters are unchanged. A small increase in the magnetic field, however, can restore the efficiency to higher values.This research was supported by the U.S. Office of Naval Research.     

Dynamic properties of a diluted pyrochlore cooperative paramagnet (Tb(p)Y(1-p))2Ti2O7

Investigations of the spin dynamics of the geometrically frustrated pyrochlore (Tb(p)Y(1-p))2Ti2O7, using muon spin relaxation and neutron spin echo, as a function of magnetic coverage p, have been carried out. Our major finding is that paramagnetic fluctuations prevail as T-->0 for all values of p, and that they are sensitive to dilution, indicating a cooperative spin motion. However, the percolation threshold pc is not a critical point for the fluctuations. We also find that the low temperature spectral density has a 1/f behavior, and that dilution slows down the spin fluctuations.     

Pure nuclear quadrupole resonance determination of the electric field gradient asymmetry for broad lines

We present an angle dependent nuclear quadrupole resonance (ADNQR) method to determine the electric field gradient asymmetry parameter eta in systems where the resonance line is so broad that the radio frequency field can excite only a portion of the nuclear spins. In this situation, the recently developed spectroscopic methods are not applicable. ADNQR is useful for single crystals and oriented powders, and, for small eta determines eta4. Therefore, it can be used to evaluate fluctuations in eta due to inhomogeneities. We demonstrate the application of ADNQR experimentally to oriented superconducting YBa2Cu3O7 powder.     

Synthesis of cobalt-based magnetic nanoporous carbon core-shell molecularly imprinted polymers for the solid-phase extraction of phthalate plasticizers in edible oil

Analytical and Bioanalytical Chemistry - In this work, cobalt magnetic nanoporous carbon (Co-MNPC) is employed as an alternative to intensively used Fe3O4 cores for the preparation of magnetic...     

Explaining μ+ spin-lattice relaxation in MnF2, belowT N,by scattering function

A relation between the spin-lattice relaxation rate (1/T ₁) of positive muons and the scattering functionS ^T (q,) is derived for the antiferromagnet MnF₂. We find good agreement between previousSR measurements of 1/T ₁ and our calculation using neutron scattering measurements ofS ^T (q,).