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71.
T. Tanabe K. Haga M. Yasue K. Sato K. Ogino Y. Kadota M. Tochi K. Makino T. Kitahara T. Shiba 《Nuclear Physics A》1983,399(1):241-258
The 24, 26Mg(6Li, d)28, 30Si reactions have been studied at 73 MeV bombarding energy. The angular distributions were analyzed with exact finite-range distorted wave Born approximation calculations assuming a direct α-cluster transfer. Extracted spectroscopic strengths leading to low-lying levels of 28Si and relative spectroscopic strengths between transitions to 28Si and 30Si ground states are consistent with those previously obtained by several α-transfer reactions. Many strongly populated levels have been observed at Ex ? 10 MeV for 28Si. A marked similarity was found between the deuteron spectrum and the 24Mg(α, α)24Mg excitation function in this excitation energy region. A brief comparison of the present α-transfer results with previous two-nucleon transfer data leading to 28,30Si is also presented. 相似文献
72.
Synthesis of fluorinated chitin derivatives has been achieved using chitinase from Bacillus sp. as a catalyst. 6'-Fluoro- (1a), 6-fluoro- (1b) and 6,6'-difluoro- (1c) chitobiose oxazoline derivatives were newly prepared as TSAS monomers for chitinase. Ring-opening polyaddition of these monomers proceeded effectively at pH 8.0-9.0 and 30-40 degrees C, giving rise to alternatingly 6-fluorinated chitin derivatives (2a and 2b) from 1a and 1b, and fully 6-fluorinated chitin derivative (2c) from 1c under total control of regioselectivity and stereochemistry. XRD measurements revealed that polysaccharides 2a and 2b had crystalline structures similar to that of alpha-chitin. [reaction: see text] 相似文献
73.
Kazuhisa Makino 《Discrete Applied Mathematics》2010,158(18):2024-2030
Gopalan et al. studied in [P. Gopalan, P.G. Kolaitis, E.N. Maneva, C.H. Papadimitriou, The connectivity of Boolean satisfiability: computational and structural dichotomies, in: Proceedings of the 33rd International Colloquium on Automata, Languages and Programming, ICALP 2006, 2006, pp. 346-357] and [P. Gopalan, P.G. Kolaitis, E.N. Maneva, C.H. Papadimitriou, The connectivity of Boolean satisfiability: computational and structural dichotomies, SIAM J. Comput. 38 (6) (2009) 2330-2355] connectivity properties of the solution-space of Boolean formulas, and investigated complexity issues on the connectivity problems in Schaefer’s framework. A set S of logical relations is Schaefer if all relations in S are either bijunctive, Horn, dual Horn, or affine. They first conjectured that the connectivity problem for Schaefer is in P. We disprove their conjecture by showing that there exists a set S of Horn relations such that the connectivity problem for S is -complete. We also investigate a tractable aspect of Horn and dual Horn relations with respect to characteristic sets. 相似文献
74.
Hasegawa T Iijima K Hirota K Nakajima T Makino K Terada H 《Colloids and surfaces. B, Biointerfaces》2008,63(2):209-216
A method for exact determination of phagocytic activity of alveolar macrophage (M) cells toward synthetic microspheres (MS) by optical microscopy was developed. We examined the effectiveness of the treatment of M samples with trypsin, acid or xylene to remove the polystyrene latex microspheres (PSL MS) attached to M cell membranes during their phagocytosis by M cells. We found that centrifugation, which was employed to collect M samples after incubation with MS, affected significantly the efficiency of the various treatments. Of the three treatments, xylene treatment without centrifugation was the most effective to determine the phagocytic activity of M cells, as xylene dissolved the PSL MS on the cell surface almost completely. This treatment was also effective in the case of poly(lactic-co-glycolic acid) MS (PLGA MS), which have been commonly used as an efficient vehicle for drug delivery system. 相似文献
75.
We have developed a program, ELECT++ (Effective LEssening of Conformations by Template molecules in C++), to speed up the conformational search for small flexible molecules using the similar property principle. We apply this principle to molecular shape and, importantly, to molecular flexibility. After molecules in a database are clustered according to flexibility and shape (FCLUST++), additional reagents are generated to screen the conformational space of molecules in each cluster (TEMPLATE++). We call these representative reagents of each cluster template reagents. Template reagents and clustered reagents produce, after reaction, template molecules and clustered molecules, respectively (tREACT++). The conformations of a template molecule are searched in the context of a macromolecular target. Acceptable conformational choices are then applied to all molecules in its cluster, thus effectively biasing conformational space to speed up conformational searches (tSEARCH++). In our incremental search method, it is necessary to calculate the root-mean-square deviations (RMSD) matrix of distances between different conformations of the same molecule to reduce the number of conformations. Instead of calculating the RMSD matrix for all molecules in a cluster, the RMSD matrix of a template molecule is chosen as a reference and applied to all the molecules in its cluster. We demonstrate that FCLUST++ clusters the primary amine reagents from the Available Chemicals Directory (ACD) successfully. The program tSEARCH++ was applied to dihydrofolate reductase with virtual molecules generated by tREACT++ using clustered primary amine reagents. The conformational search by the program tSEARCH++ was about 4.8 times faster than by SEARCH++, with an acceptable range of errors. © 1998 John Wiley & Sons, Inc. J Comput Chem 19: 1834–1852, 1998 相似文献
76.
77.
IR spectroscopic and volumetric study under reaction conditions of the mechanism of photocatalytic hydrogen production from gaseous methanol and water revealed that CO2 and H2 were produced by reaction between adsorbed CH3O(ad) and H2O. Another reaction path for H2 production, CH3 OH(ad) → H2 + HCHO, was suggested which is dominant in the absence of water. 相似文献
78.
p-Polyphenyl-α,ω-quinododimethides were predicted to be moderately aromatic and diatropic, although they exist only in a single
classical resonance structure with no aromatic conjugated circuits. Such a dichotomy was resolved using our graph theory of
aromaticity and ring-current diamagnetism. Six-site non-conjugated circuits were found to contribute appreciably to aromaticity
and ring-current diamagnetism. Within each quinododimethide molecule, local aromaticity increases on going from the outermost
to inner phenylene rings. 相似文献
79.
The parallel factor (PARAFAC) kernel matrix to analyze a sample system stimulated by more than one type of perturbation is described. PARAFAC kernel is a quantitative representation of the synchronicity and asynchronicity observed within the PARAFAC score matrices generated by carrying out two-dimensional (2D) correlation analyses. Thus, kernel matrix representation provides more intuitively understandable interpretation to the conventional PARAFAC trilinear model. In this study, the utility of PARAFAC kernel is demonstrated by the study of poly(lactic acid)-nanocomposite undergoing a structural change depending on the temperature as well as the clay content in the sample. Seemingly complicated variation of nuclear magnetic resonance (NMR) spectra induced by the change in the temperature and clay content are readily analyzed by the multiple-perturbation 2D correlation spectroscopy and PARAFAC kernel. PARAFAC kernel revealed that crystalline and amorphous structures of the PLA substantially undergo thermal deformation, and these variations are also influenced by the presence of the clay. 相似文献
80.
Taketoshi Makino Tetsuji Nunozawa Naomichi Baba Junichi Oda Yuzo Inouye 《Tetrahedron letters》1979,20(19):1683-1686
Asymmetric reduction of α-ketoester with a chiral dihydronicotinamide was significantly affected by chiral aromatic additives, capable of exerting an attractive interaction with dihydropyridine ring, which was further consolidated through with magnesium. 相似文献