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991.
992.
The scope of the reduction of organic halides with trialkylgermanes under homolytic condition has been studied. Germanium hydrides can reduce polyhaloalkane without catalysts under mild conditions, the homolytic mechanism being, however, established for the uncatalyzed reduction. The observed orders of reactivity and selectivity in the reduction are consistent with a radical chain mechanism involving free germyl radicals. Some synthetic applications are described. 相似文献
993.
Laser action on a single spatially chaotic wave function is obtained as a final stable state in a nonlinear dynamical model of a stadium shaped resonant cavity with an active medium. The stable single-mode lasing state corresponds to a particular metastable resonance of the cavity which wins a competition among multiple modes with positive net linear gain and has a distinct lasing threshold. 相似文献
994.
Wu K Fujikawa Y Nagao T Hasegawa Y Nakayama KS Xue QK Wang EG Briere T Kumar V Kawazoe Y Zhang SB Sakurai T 《Physical review letters》2003,91(12):126101
We have systematically investigated Na adsorption on the Si(111)-(7 x 7) surface at room temperature using scanning tunneling microscopy (STM). Below the critical coverage of 0.08 monolayer, we find intriguing contrast modulation instead of localized Na adsorbates, coupled with streaky noise in the STM images, which is accompanied by monotonic work function drop. Above the critical coverage, Na clusters emerge and form a self-assembled array. Combined with first-principles theoretical simulations, we conclude that the Na atoms on the (7 x 7) surface are, while strongly bound ( approximately 2.2 eV) to the surface, highly mobile in "basins" around the Si rest atoms, forming a two-dimensional gas phase at the initial coverage, and that the cluster at the higher coverage consists of six Na atoms together with three Si adatoms. 相似文献
995.
Locking of two resonance modes of different symmetry classes and different frequencies in 2D resonant microcavity lasers is investigated by using a nonlinear dynamical model. The patterns of stationary lasing states and far fields are asymmetric in spite of the symmetric shape of the resonant microcavity. The corresponding phenomenon is actually observed in the experiment of a 2D semiconductor microcavity laser diode. 相似文献
996.
Gando Y Fukuda S Fukuda Y Ishitsuka M Itow Y Kajita T Kameda J Kaneyuki K Kobayashi K Koshio Y Miura M Moriyama S Nakahata M Nakayama S Namba T Obayashi Y Okada A Ooyabu T Saji C Sakurai N Shiozawa M Suzuki Y Takeuchi H Takeuchi Y Totsuka Y Yamada S Desai S Earl M Kearns E Messier MD Stone JL Sulak LR Walter CW Goldhaber M Barszczak T Casper D Gajewski W Kropp WR Mine S Liu DW Smy MB Sobel HW Vagins MR Gago A Ganezer KS Hill J Keig WE Ellsworth RW Tasaka S Kibayashi A Learned JG Matsuno S 《Physical review letters》2003,90(17):171302
We present the results of a search for low energy nu(e) from the Sun using 1496 days of data from Super-Kamiokande-I. We observe no significant excess of events and set an upper limit for the conversion probability to nu(e) of the 8B solar neutrino. This conversion limit is 0.8% (90% C.L.) of the standard solar model's neutrino flux for total energy=8-20 MeV. We also set a flux limit for monochromatic nu(e) for E(nu(e))=10-17 MeV. 相似文献
997.
Takashi?KusakaEmail author Yoshio?Hisamatsu Kou?Kawada Kensuke?Okubo Hitoshi?Okada Masanori?Namba Tadashi?Imai Kenichi?Isobe Susumu?Itoh 《Optical Review》2003,10(5):466-469
Near-infrared spectroscopy (NIRS) has been used for measurement of changes in cerebral hemoglobin concentrations in neonates to study cerebral oxygenation and hemodynamics. In this study, measurements by time-resolved reflectance spectroscopy (TRS) were performed in a piglet model with various degrees of cerebral oxygenation to estimate the differential pathlength factor (DPF). A portable three-wavelength TRS system (TRS-10, Hamamatsu Photonics K.K.) with a probe attached to the head of a piglet was used. Eleven newborn piglets were anesthetized and respired by a ventilator to induce stepwise hypoxia loading. The DPF showed positive linear relationship with arterial hemoglobin (Hb) oxygen saturation and sagittal sinus venous Hb oxygen saturation at 761 and 795 nm. The DPF at 835 nm also showed very slight positive linear relationship with arterial hemoglobin oxygen saturation. The DPF values obtained in this study should contribute to a better understanding of noninvasive measurements by NIRS in neonates. 相似文献
998.
Ihara H Takafuji M Sakurai T Katsumoto M Ushijima N Shirosaki T Hachisako H 《Organic & biomolecular chemistry》2003,1(17):3004-3006
This communication introduces a new class of self-assembling organogelators composed of a double chain-alkylated L-glutamide with a polymeric head group. 相似文献
999.
1000.