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101.
Kang JH Asai D Kim JH Mori T Toita R Tomiyama T Asami Y Oishi J Sato YT Niidome T Jun B Nakashima H Katayama Y 《Journal of the American Chemical Society》2008,130(45):14906-14907
We succeeded in cancer cell specific gene expression by using a polyplex responsive to protein kinase Calpha, which is activated in various types of cancer cells. 相似文献
102.
Kadoma Y Kumada W Asai Y Sugita Y Yokoe I Fujisawa S 《Molecules (Basel, Switzerland)》2007,12(8):1836-1844
The reaction products in the presence of Lewis acid of isoeugenol (1) with ethanethiol, thiophenol, 2-mercaptothiazoline or 2-mercapto-1-methylimidazole (ISO-S1-ISO-S-4) were obtained. The radical-scavenging activity of these compounds was investigated using the induction period method for polymerization of methyl methacrylate (MMA) initiated by thermal decomposition of 2,2'-azobisisobutyronitrile (AIBN) and benzoyl peroxide (BPO) and monitored by differential scanning calorimetry (DSC). For BPO, the stoichiometric factor (number of free radicals trapped by one mole of antioxidant moiety, n) declined in the order isoeugenol (1.8) > ISO-S-1 (1.6) > ISO-S-2 (1.2) > ISOS- 3 (0.9) > ISO-S-4 (0.3), whereas for AIBN, their n values were about 1, except for ISOS- 3 (0.6). The ratio of the rate constant of inhibition to that of propagation (k(inh)/k(p)) for BPO declined in the order ISO-S-4 (56) > ISO-S-3 (15) > ISO-S-2 (11) >ISO-S-1 (9) > isoeugenol (8). Similarly, for AIBN the k(inh)/k(p) of the reaction products (33-57) was greater than that of isoeugenol (31). The reaction products of isoeugenol with a SH group showed greater inhibition rate constants (kinh) than the parent compound isoeugenol. 相似文献
103.
Yamamoto H Pandey G Asai Y Nakano M Kinoshita A Namba K Imagawa H Nishizawa M 《Organic letters》2007,9(20):4029-4032
A novel catalytic activation of the leaving group in the S(N)2 reaction is achieved as an extension of our mercuric triflate-catalyzed reactions. Derivatives of anilinoethyl 4-pentynoate reacted smoothly with catalytic amounts of Hg(OTf)(2) to give indoline derivatives in excellent yield with efficient catalytic turnovers under very mild conditions. The reaction of optically pure secondary alcohol derivatives resulted in inversion of stereochemistry, which is a definitive feature of the S(N)2 reaction. The procedure is applicable for benzoazepine synthesis. 相似文献
104.
Tsutomu Oishi Kenjiro Onimura Yukio Isobe Hiroaki Yanagihara Hiromori Tsutsumi 《Journal of polymer science. Part A, Polymer chemistry》2000,38(2):310-320
Asymmetric anionic homopolymerizations of N‐substituted maleimide (RMI) bearing bulky substituents [R = benzyl, diphenylmethyl (DPhMI), 9‐fluorenyl (9‐FlMI), triphenylmethyl, (diphenylmethyloxycarbonyl)methyl, (9‐fluorenyloxycarbonyl)methyl] were carried out with complexes of organometal compounds (alkyllithium, diethylzinc) with six chiral ligands to obtain optically active polymers. The chiroptical properties of the polymers were affected strongly by the substituents on nitrogen in the maleimide ring, the organometal and chiral ligands. Poly(DPhMI) initiated by an n‐butyllithium/(−)‐sparteine (Sp) complex showed a positive specific rotation ([α] +60.3°). Poly(9‐FlMI) prepared with a florenyllithium/Sp complex exhibited the highest specific rotation (+65.7°). The specific rotations of the poly(RMI) obtained were attributed to different contents between the stereogenic centers (S,S) and (R,R) based on threo‐diisotactic structures of the main chain. © 2000 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 38: 310–320, 2000 相似文献
105.
Ritsuko Nagahata Jun‐Ichi Sugiyama Meenakshi Goyal Michihiko Asai Mitsuru Ueda Kazuhiko Takeuchi 《Journal of polymer science. Part A, Polymer chemistry》2000,38(18):3360-3368
Thermal ring‐opening polymerization of a uniform macrocyclic ethylene terephthalate dimer with and without catalyst was investigated for the first time. Although polymerization progressed without a catalyst, the reaction was extremely slow and all the products were colored. Various transesterification catalysts were tested for their activity toward this ring‐opening polymerization. Among the various catalysts, 1,3‐dichloro‐1,1,3,3‐tetrabutyldistannoxane exhibited the highest catalytic activity, and a colorless polymer with a weight‐average molecular weight of 36,100 was obtained in 100% yield by heating for 3 min at 200 °C. It is noteworthy that our method does not need a vacuum because no side products are formed during the process. © 2000 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 38: 3360–3368, 2000 相似文献
106.
Akinori Nishio Amane Mochizuki Jun‐Ichi Sugiyama Kazuhiko Takeuchi Michihiko Asai Koichiro Yonetake Mitsuru Ueda 《Journal of polymer science. Part A, Polymer chemistry》2000,38(11):2106-2114
An ordered polyurethane with a head‐to‐head (H‐H) or tail‐to‐tail (T‐T) content over 95% was prepared by polyaddition reaction of a nonsymmetric monomer, p‐isocyanatobenzyl isocyanate (1) with a symmetric monomer, ethylene glycol (2). The model reactions were studied in detail to demonstrate the feasibility of polymer formation. The polymerization was conducted in THF in the presence of triethylamine (TEA) at 0 °C by slow addition of a half amount of 2 to 1, followed by removing THF and then adding the rest of 2 in DMF at once at 30 °C in the presence of dibutyltin dilaurate (DBTL). The microstructure of the polymer obtained was investigated by 13C NMR spectroscopy, and it was found that the polymer had the expected structural regularity. The constitutional regularity of polymers influenced their thermal properties. © 2000 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 38: 2106–2114, 2000 相似文献
107.
We observed persistent photoconductivity (PPC) in La-based perovskite manganese oxides, La0.9Sr0.1MnO3 (LSMO) and La0.9Ca0.1MnO3 (LCMO), under X-ray irradiation. The PPC in LSMO was attributed to the collapse of the charge- and orbital-ordered (CO and OO, respectively) states, similar to that reported in previous papers. This PPC effect was different from that observed in a similar compound with a slightly different composition. This difference was explained in terms of doped carriers. This observation of PPC in LCMO is the first result of the PPC in a compound in which the ground state is not the CO phase; it was attributed to the collapse of the OO ground state. We proposed that OO ground state is a prerequisite for the occurrence of PPC in these compounds. 相似文献
108.
Acylglycerols (=Glycerides) from the Glandular Trichome Exudate on the Leaves of Paulownia tomentosa
Teigo Asai Noriyuki Hara Sawa Kobayashi Shiro Kohshima Yoshinori Fujimoto 《Helvetica chimica acta》2009,92(8):1473-1494
Chemical investigations of the glandular trichome exudates on the leaves of Paulownia tomentosa (Scrophulariaceae) led to the identification of the thirty acylglycerols (=glycerides) 1 – 30 , including five known ones ( 2, 3, 6, 9 , and 15 ) (Fig. 1). Spectroscopic analysis combined with GC/MS studies of the glycerides and the liberated fatty acids, in the form of trimethylsilyl ether derivatives and trimethylsilylated methyl esters, respectively, established that the constituents belonged to 1,3‐di‐O‐acetyl‐2‐O‐(fatty acyl)glycerols, 1‐O‐acetyl‐2‐O‐(fatty acyl)‐sn‐glycerols, and 2‐O‐(fatty acyl)glycerols, wherein the fatty acyl moiety was either an eicosanoyl or an octadecanoyl group bearing OH and/or AcO groups at the 3‐, 3,6‐, 3,7‐, 3,8‐, or 3,9‐positions. The 1‐O‐acetyl‐2‐O‐[(3R,6S)‐3‐(acetyloxy)‐6‐hydroxyeicosanoyl]‐sn‐glycerol ( 12 ; 20% of the total glycerides), 2‐O‐[(3R,8R)‐3,8‐bis(acetyloxy)eicosanoyl]glycerol ( 17 ; 14%), 2‐O‐[(3R,9R)‐3,9‐bis(acetyloxy)eicosanoyl]glycerol ( 18 ; 12%), and 2‐O‐[(3R)‐3‐(acetyloxy)eicosanoyl]glycerol ( 10 ; 12%) were relatively abundant constituents. The configurations of the stereogenic centers of the fatty acyl moieties were determined by 1H‐NMR analysis of the monoesters obtained from (R)‐ and (S)‐2‐(naphthalen‐2‐yl)‐2‐methoxyacetic acid ((R)‐ and (S)‐2NMA? OH and the hydroxy‐substituted fatty acid methyl esters (Fig. 2). The configuration at C(2) of the glycerol moiety of the 1‐O‐acetyl‐2‐O‐(fatty acyl)glycerols was determined to be (2S) by chemical conversion of, e.g., G‐2 (= 2 / 3 1 : 10) to (+)‐3‐O‐[tert‐butyl)diphenylsilyl]‐sn glycerol of known absolute configuration. 相似文献
109.
Hao J Matsuura F Kishi Y Kita M Uemura D Asai N Iwashita T 《Journal of the American Chemical Society》2006,128(24):7742-7743
The C34 and C2' stereochemistry of pteriatoxins A-C has been established. The availability of all the stereoisomers via total synthesis has played an indispensable role. 相似文献
110.
Martin Bitter Tatsuya Hara Rainer Hain Daisuke Yorita Keisuke Asai Christian J. K?hler 《Experiments in fluids》2012,53(6):1737-1749
This collaborative work discusses the results of time-resolved pressure-sensitive paint measurements performed on a model of a generic spacecraft under sub- and transonic test conditions. It is shown that optical pressure measurements using an active layer from platinum?Cporphyrin complexes (PtTFPP) in combination with a polymer-ceramic base layer are able to measure dynamic flow phenomena in the trisonic wind tunnel facility up to sampling rates of 2?kHz. Low amplitude fluctuations in the order of 0.1?kPa were determined by means of this measurement technique. The buffet dynamics, as well as the spatial extent of the recirculation area in the near-wake, compare well with numerical predictions and PIV measurements. Furthermore, characteristic coherent pressure modes on the base were resolved, which were predicted by large-eddy simulations. 相似文献