全文获取类型
收费全文 | 2947篇 |
免费 | 134篇 |
国内免费 | 14篇 |
专业分类
化学 | 2329篇 |
晶体学 | 47篇 |
力学 | 24篇 |
数学 | 110篇 |
物理学 | 585篇 |
出版年
2023年 | 13篇 |
2022年 | 23篇 |
2021年 | 23篇 |
2020年 | 32篇 |
2019年 | 34篇 |
2018年 | 31篇 |
2017年 | 24篇 |
2016年 | 58篇 |
2015年 | 62篇 |
2014年 | 67篇 |
2013年 | 150篇 |
2012年 | 179篇 |
2011年 | 192篇 |
2010年 | 118篇 |
2009年 | 124篇 |
2008年 | 176篇 |
2007年 | 198篇 |
2006年 | 198篇 |
2005年 | 193篇 |
2004年 | 146篇 |
2003年 | 160篇 |
2002年 | 137篇 |
2001年 | 38篇 |
2000年 | 36篇 |
1999年 | 45篇 |
1998年 | 23篇 |
1997年 | 35篇 |
1996年 | 50篇 |
1995年 | 15篇 |
1994年 | 22篇 |
1993年 | 21篇 |
1992年 | 32篇 |
1991年 | 22篇 |
1990年 | 14篇 |
1989年 | 15篇 |
1988年 | 13篇 |
1987年 | 12篇 |
1986年 | 14篇 |
1985年 | 49篇 |
1984年 | 50篇 |
1983年 | 12篇 |
1982年 | 38篇 |
1981年 | 39篇 |
1980年 | 35篇 |
1979年 | 28篇 |
1978年 | 25篇 |
1977年 | 14篇 |
1976年 | 16篇 |
1975年 | 10篇 |
1973年 | 10篇 |
排序方式: 共有3095条查询结果,搜索用时 15 毫秒
11.
12.
Kenji Hara Keiji Iwahashi Satoru Takakusagi Kohei Uosaki Masaya Sawamura 《Surface science》2007,601(22):5127-5132
Functionalization of self-assembled monolayer (SAM) of alkanethiolate with metal containing unit is one of the versatile methods to obtain functional surfaces such as heterogeneous catalysts. However, organic molecules that strongly bind to transition metals at SAM terminal are limited. Recently N-heterocyclic carbenes (NHCs) such as cyclic diaminocarbenes have emerged as strongly σ-donating ligands forming a robust bond with broad spectrum of transition metals. In the present study, for the purpose of establishment of a new robust basement for heterogeneous metal catalysts, a SAM of the alkanethiolate terminated with NHC-rhodium(I) complex moiety was prepared by utilizing a newly designed disulfide molecule bearing NHC-metal complex terminals. X-ray photoelectron spectroscopy (XPS) analysis and angle resolved XPS measurement revealed successful formation of the Rh-complex-terminated SAM on a gold substrate. Infrared reflection absorption spectroscopy (IRRAS) analysis suggested that the linker methylene chains connecting the rhodium complex moiety and the gold surface are in a loosely packed structure. This unique chemical species, NHC, would be a promising candidate as a basement for the construction of functional surface. 相似文献
13.
Kentaro Suzuya Tomoaki Kamiyama Takemi Yamamura Kiyohito Okamura Kenji Suzuki 《Journal of Non》1992,150(1-3):167-171
A small-angle X-ray scattering (SAXS) study was performed to reveal the nanometer scale hybrid structure of Si---Ti---C---O fibers prepared by the pyrolysis of polytitanocarbosilane. The SAXS profile for Si---Ti---C---O fibers is attributed to two different types of scattering entities: an anisotropic contribution from long filaments with diameters hundreds to thousands of Ångströms and an isotropic contribution from β-SiC fine clusters of about a nanometer in diameter. A drastic degradation in the tensile strength of the fibers is correlated to the characteristic variations in their long-and medium-range structure. 相似文献
14.
We discuss basic statistical properties of systems with multifractal structure. This is possible by extending the notion of the usual Gibbs-Shannon entropy into more general framework—Rényi’s information entropy. We address the renormalization issue for Rényi’s entropy on (multi)fractal sets and consequently show how Rényi’s parameter is connected with multifractal singularity spectrum. The maximal entropy approach then provides a passage between Rényi’s information entropy and thermodynamics of multifractals. Important issues such as Rényi’s entropy versus Tsallis-Havrda-Charvat entropy and PDF reconstruction theorem are also studied. Finally, some further speculations on a possible relevance of our approach to cosmology are discussed. 相似文献
15.
We developed DNA-conjugated polymer for DNA chip fabrication. A 30 mer probe DNA and disulfide bridges were covalently attached to the polymer side chain. The DNA-conjugated polymer can be specifically adsorbed on a gold substrate surface by a self-assembly technique. The interaction between fully matched DNA and DNA-conjugated polymer was investigated by surface plasmon resonance (SPR) technique. The DNA-conjugated polymer-modified gold surface highly recognized fully matched DNA, rather than unmatched DNA. Therefore, DNA-conjugated polymer can be used for novel DNA chip fabrication. 相似文献
16.
Kenji Handa 《Journal of statistical physics》1996,83(3-4):555-571
Entropy production per site in a (nonreversible) spin-flip process is studied. We give it a useful expression, from which a property stronger than affinity of the entropy production per site follows. Furthermore, quasi-invariance of nonequilibrium measures in the spin-flip processes is discussed via entropy production. 相似文献
17.
High-temperature isothermal capacitance transient spectroscopy (H-ICTS) measurements were conducted to characterize near mid-gap defects, which are the origin of the memory effect in Ni/p-GaN Schottky contacts. A large single peak was detected only under the forward bias conditions. This indicates that the defects were located in the vicinity of the interface. The change of the peak height and position of the ICTS curves under various bias conditions were qualitatively interpreted by the distribution of the defects and the current flow effect. 相似文献
18.
Kimio Asaka Yoshihito Hirano Kenji Tatsumi Kumio Kasahara Toru Tajime 《Optical Review》1998,5(5):310-314
We propose a new detection method for a pseudo-random frequency modulation continuous wave (RM-CW) coherent lidar. The feature of this method is modulation of local beam with a time delayed pseudo-random sequence. Heterodyne detection and correlation detection between the received beam and the local beam are simultaneously carried out in an optical field. In the RM-CW coherent lidar using the optical field correlation detection method, the received equipment is greatly simplified. We carried out preliminary experiments and demonstrated that the new method is effective for detection of a CW coherent lidar. 相似文献
19.
Makoto Kato Azusa Tsukigase Hiromitsu Tanaka Arimitsu Usuki Isamu Inai 《Journal of polymer science. Part A, Polymer chemistry》2006,44(3):1182-1188
Isobutylene isoprene rubber (IIR)‐clay nanocomposites have been prepared successfully by melt intercalation with maleic anhydride‐grafted IIR (Ma‐g‐IIR) and organophilic clay. In IIR‐clay nanocomposites, the silicate layers of the clay were exfoliated and dispersed into the monolayer. The nanocomposites exhibited greater gas barrier properties compared with those of Ma‐g‐IIR. When 15 phr clay was added, gas barrier properties were 2.5 times greater than those of Ma‐g‐IIR. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 1182–1188, 2006 相似文献
20.
Takahiro Gunji Ryosuke Shimano Koji Arimitsu Yoshimoto Abe 《Journal of polymer science. Part A, Polymer chemistry》2006,44(8):2542-2550
Tetraethoxysilane (TEOS) and polyethoxysiloxanes (PEOSs; prepared by the acid‐catalyzed hydrolytic polycondensation of TEOS) were subjected to the sol–gel process in the presence of cetyltrimethylammonium bromide (CTAB), respectively. The PEOSs with Mw 700–26,000, as prepared by sol–gel coating of TEOS and PEOS under various conditions, were used. Uniform and crack‐free thin films of thickness 276–613 nm were prepared by spin‐coating of a PEOS solution containing CTAB. When the coating films were sintered at 400 °C, the combustion of ethoxy groups and CTAB took place to provide porous silica thin films. The structure of the thin films was found to be dependent on the molecular weight of PEOS and the molar ratio of CTAB/Si: lamellar or hexagonal phase was observed for Mw less than 15,000 and for CTAB/Si molar ratios greater than 0.10. Honeycomb structures were observed for Mw less than 5000 and for CTAB/Si molar ratios of 0.15. The honeycomb structure was also observed by atomic force microscopy and transmission electron microscope. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 2542–2550, 2006 相似文献