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101.
Kenichi Futamura 《Annals of Operations Research》2000,93(1-4):71-90
Traditionally, studies on tandem queueing networks concentrate on systems with infinite buffers, exponential service times, and/or single servers where solutions are more tractable. Less research can be found on more general, less tractable systems. We examine multipleserver systems with finite buffers and nonexponential service times, studying the effects of coefficient of variation (cv) of the servicetime distribution on the throughput of these systems, where cv differs among stations.Starting with the single station, we examine the effects of cv and the number of servers at the station on the distribution of interdeparture times. This insight helps explain the differences in throughput seen in the single (fast) server vs. multiple (slow) server problem. These results, in turn, shed light on the server allocation problem when cv differs among stations. We present some observations, as well as the intuition behind them. 相似文献
102.
Thallada Bhaskar Kazuya Murai Toshiki Matsui Mihai Adrian Brebu Md. Azhar Uddin Akinori Muto Yusaku Sakata Katsuhide Murata 《Journal of Analytical and Applied Pyrolysis》2003,70(2):369-381
The thermal degradation of acrylonitrile-butadiene-styrene copolymer (ABS-Br; 10 g) containing brominated flame retardant (Br: 9.59 wt.%) was carried out at 450 °C using a semi batch operation using two different temperature programs. The heating rate was found to affect the quality of the degradation oil and yield of products (liquid, gas and residue). Data on the effect of the temperature program on the accumulation of liquid products was presented. It was found that the majority of the bromine was concentrated in the carbon residue and while majority of the nitrogen accumulates in the liquid products irrespective of degradation mode. The use of a one step constant heating rate process (I) produced a higher liquid yield (39%), than a two step process (29%). Differences were also noted in the Br and N contained in the liquids produced by the two processes. 相似文献
103.
Kakiuchi F Kan S Igi K Chatani N Murai S 《Journal of the American Chemical Society》2003,125(7):1698-1699
The ruthenium-catalyzed reaction of aromatic ketones with arylboronic acid esters (arylboronates) gave the ortho arylation product. For this coupling reaction, a RuH2(CO)(PPh3)3 complex exhibited the highest catalytic activity among the complexes screened. Several aromatic ketones, for example, acetophenones, acetonaphthone, alpha-tetralone, and benzosuberone, can be used in this coupling reaction. A variety of arylboronates containing electron-donating (OMe and NMe2) and -withdrawing (F and CF3) groups were found to react with aromatic ketones to give the corresponding aylation products. The corresponding arylboronic acids could be used in this coupling reaction, but the yields were slightly lower, as compared to those of the reaction using the corresponding arylboronates. 相似文献
104.
Hamada T Sato YT Yoshikawa K Nagasaki T 《Langmuir : the ACS journal of surfaces and colloids》2005,21(17):7626-7628
A photosensitive amphiphilic molecule can switch the shape of an assembled vesicle as determined by microscopic observation. Photoisomerization induces a change in membrane fluctuation behavior or a morphological transition between ellipsoid and bud shapes, depending on the asymmetrical degree of the initial shape. The mechanism of this reversible photoswitching in the vesicle morphology is interpreted in terms of a change in the effective cross-sectional area of the photosensitive molecule. 相似文献
105.
Dova E Peschar R Sakata M Kato K Schenk H 《Chemistry (Weinheim an der Bergstrasse, Germany)》2006,12(19):5043-5052
The spin-crossover complex [Fe(teec)(6)](ClO(4))(2) (teec = chloroethyltetrazole) exhibits a 50 % incomplete spin crossover in the temperature range 300-30 K. Time-resolved synchrotron powder diffraction experiments have been carried out to elucidate its structural behavior. We report crystal structure models of this material at 300 K (high spin) and 90 K (low spin), as solved from synchrotron powder diffraction data by using Genetic Algorithm and Parallel Tempering techniques and refined with Rietveld refinement. During short synchrotron powder diffraction experiments (five minutes duration) two distinguishable lattices were observed the quantities of which vary with temperature. The implication of this phenomenon, that is interpreted as a structural phase transition associated with the high-to-low spin crossover, and the structural characteristics of the high-spin and low-spin models are discussed in relation to other compounds showing a similar type of spin-crossover behavior. 相似文献
106.
Takeshi Imagawa Nobuyiki Murai Tetsuo Akiyama Mituyosi Kawanisi 《Tetrahedron letters》1979,20(19):1691-1692
An iridoid monoterpene hop ether, 2,2-dimethyl-6-methylene-3-oxabicyclo[3.3.0]octane, was first synthesized in six steps starting from the protected lactol form of 3-formyl-2-methoxy-carbonylcyclopentanol. 相似文献
107.
Kenshu Fujiwara Masanori Kobayashi Fuyuki Yamamoto Yu-ichi Aki Mariko Kawamura Daisuke Awakura Seiji Amano Azusa Okano Akio Murai Hidetoshi Kawai Takanori Suzuki 《Tetrahedron letters》2005,46(30):5067-5069
The common left-half [C31-C33(OC1-C7)-C40] part of pectenotoxins has been synthesized convergently from the C31-C35, C36-C40, and C1-C7 parts. The C31-C35 part, prepared via a new route shorter than our previous route, was coupled with the C36-C40 part through reductive lithiation and addition reactions to give an adduct stereoselectively, which was converted to a cyclic acetal corresponding to the C31-C40 part. The left-half was synthesized by a three-step process including esterification of the C31-C40 part with the C1-C7 part. 相似文献
108.
109.
Reaction of FeCl3 with poly(N-methyl-2,5-pyrrolylene) (PNMPy), poly(2,5-thienylene) (PTh), and poly(3-methyl-2,5-thienylene) (P3MeTh) caused reduction of FeCl3 to afford Fe2+ species. Variable temperature Mössbauer spectra of the reaction systems indicated formation of FeCl2 and FeCl? 4. The latter is regarded as a counter-anion for the cation delocalized along the π-conjugated polymer chain. 相似文献
110.
Jian Dong Yukihiro Ozaki Kenichi Nakashima 《Journal of Polymer Science.Polymer Physics》1997,35(3):507-515
Fourier transform infrared (FTIR) spectroscopic measurements have been undertaken to estimate the conformational energies of poly(acrylic acid) (PAA) cast films in the temperature range of 40–130°C. The temperature dependence of the IR spectra in the C=O stretching region has been analyzed to yield the side-chain and backbone conformational energies. The estimated energies are close to those previously obtained by polarized Raman spectroscopic measurements for PAA solutions. Combining the FTIR value of conformational energy with the simplified rotational isomeric state (RIS) model proposed in the Raman analysis provides a persistence length in accordance with earlier SAXS experiments. The data also agree with the Gibbs-DiMarzio predictions, further substantiating the validity of the analysis. © 1997 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys, 35: 507–515, 1997 相似文献