全文获取类型
收费全文 | 1075篇 |
免费 | 32篇 |
国内免费 | 7篇 |
专业分类
化学 | 895篇 |
晶体学 | 17篇 |
力学 | 10篇 |
数学 | 28篇 |
物理学 | 164篇 |
出版年
2023年 | 5篇 |
2021年 | 8篇 |
2020年 | 14篇 |
2019年 | 14篇 |
2018年 | 9篇 |
2017年 | 6篇 |
2016年 | 20篇 |
2015年 | 18篇 |
2014年 | 26篇 |
2013年 | 41篇 |
2012年 | 81篇 |
2011年 | 102篇 |
2010年 | 51篇 |
2009年 | 34篇 |
2008年 | 72篇 |
2007年 | 79篇 |
2006年 | 51篇 |
2005年 | 76篇 |
2004年 | 58篇 |
2003年 | 45篇 |
2002年 | 36篇 |
2001年 | 11篇 |
2000年 | 19篇 |
1999年 | 11篇 |
1998年 | 9篇 |
1997年 | 11篇 |
1996年 | 10篇 |
1995年 | 21篇 |
1994年 | 12篇 |
1993年 | 6篇 |
1992年 | 16篇 |
1991年 | 4篇 |
1990年 | 6篇 |
1989年 | 6篇 |
1988年 | 8篇 |
1986年 | 7篇 |
1985年 | 7篇 |
1984年 | 6篇 |
1983年 | 6篇 |
1982年 | 8篇 |
1981年 | 9篇 |
1980年 | 6篇 |
1979年 | 8篇 |
1978年 | 5篇 |
1974年 | 5篇 |
1971年 | 4篇 |
1969年 | 6篇 |
1968年 | 8篇 |
1967年 | 10篇 |
1966年 | 5篇 |
排序方式: 共有1114条查询结果,搜索用时 312 毫秒
101.
Tetsuro Shimo Mikio Yasutake Teruo Shinmyozu Kenichi Somekawa 《Analytical sciences》2003,19(3):471-472
A photochemical cycloaddition reaction of methyl 2-pyrone-5-carboxylate with methacrylonitrile mainly gave a [4 + 2] cycloadduct, assigned as methyl endo-8-cyano-exo-8-methyl-3-oxo-2-oxabicyclo[2.2.2]oct-5-ene-6-carboxylate, whose structure was determined by an X-ray diffraction study. The formation of the cycloadduct was reasonably explained by considering a biradical intermediate having a less steric hindrance between the methoxycarbonyl group and the cyano group. 相似文献
102.
We report on an interdisciplinary approach to the study of finds of unfired clay lumps and unfired broken vessels from two workshops in the Leche Valley, north coast of Peru. The material is used as a reference in the study of pottery making at both workshops. 相似文献
103.
Yusai Ito Naoki Sugimoto Takumi Akiyama Takeshi Yamazaki Kenichi Tanamoto 《Tetrahedron letters》2009,50(28):4084-11715
Cepaic acid was isolated as a novel xanthylium yellow pigment from the dried outer scales of the yellow onion Allium cepa Linne. Its structure was elucidated on the basis of ESI-MS and 2D NMR spectroscopy as a 9-carboxy-1,3,6,8-tetrahydroxyxanthylium, which suggests that cepaic acid and other yellow pigments in the dried outer skin of onion were formed by the nucleophilic reaction of phloroglucinol derived from quercetin, a flavonol in onion scales, by autoxidation to glyoxylic acid. To our knowledge, this is the first report of such a pigment in yellow onion. 相似文献
104.
Kenichi Oyaizu Kimihisa Yamamoto Toshio Asada Hiroyuki Nishide Eishun Tsuchida 《先进技术聚合物》1995,6(4):254-257
The effect of substituents on the electropolymerization of benzene derivatives and the redox properrties of the corresponding polymers were determined using Brown's substituent constants (σ+). Electron-donating groups lower the oxidation potential by which increase in the current efficiency was observed. However, stabilization of the produced cation radicals by the electron-donating groups resulted in a decrease in the polymerization efficiency. The appropriate values of σ+ for the efficient polymerization ranged near ?1.5. 相似文献
105.
Carbazole Dendrimers as Solution‐Processable Thermally Activated Delayed‐Fluorescence Materials 下载免费PDF全文
Assist. Prof. Ken Albrecht Assist. Prof. Kenichi Matsuoka Assoc. Prof. Katsuhiko Fujita Prof. Kimihisa Yamamoto 《Angewandte Chemie (International ed. in English)》2015,54(19):5677-5682
Recently, thermally activated delayed fluorescence (TADF) materials have received increasing attention as effective emitters for organic light‐emitting diodes (OLEDs). However, most of them are usually employed as dopants in a host material. In this report, carbazole dendrimers with a triphenyl‐s‐triazine core are reported, which are the first solution‐processable, non‐doped, high‐molecular‐weight TADF materials. The dendrimers were obtained by a new and facile synthetic route using the tert‐butyldimethylsilyl moiety as a protecting group. All dendrimers showed TADF in toluene. Measurements of the temperature‐dependent luminescence lifetime revealed that spin‐coated neat films also showed TADF with moderate quantum yields. OLED devices incorporating these dendrimers as spin‐coated emitting layers gave external quantum efficiencies of up to a 3.4 %, which suggests that this device is harvesting triplet excitons. This result indicates that carbazole dendrimers with attached acceptors are potential TADF materials owing to their polarized electronic structure (with HOMO–LUMO separation). 相似文献
106.
A far-red emitting probe for unambiguous detection of mobile zinc in acidic vesicles and deep tissue
Pablo Rivera-Fuentes Alexandra T. Wrobel Melissa L. Zastrow Mustafa Khan John Georgiou Thomas T. Luyben John C. Roder Kenichi Okamoto Stephen J. Lippard 《Chemical science》2015,6(3):1944-1948
Imaging mobile zinc in acidic environments remains challenging because most small-molecule optical probes display pH-dependent fluorescence. Here we report a reaction-based sensor that detects mobile zinc unambiguously at low pH. The sensor responds reversibly and with a large dynamic range to exogenously applied Zn2+ in lysosomes of HeLa cells, endogenous Zn2+ in insulin granules of MIN6 cells, and zinc-rich mossy fiber boutons in hippocampal tissue from mice. This long-wavelength probe is compatible with the green-fluorescent protein, enabling multicolor imaging, and facilitates visualization of mossy fiber boutons at depths of >100 μm, as demonstrated by studies in live tissue employing two-photon microscopy. 相似文献
107.
High-speed holographic microscopy is applied to take three successive photographs of fast propagating cracks in Homalite 100 or in Araldite B at the moment of bifurcation. Crack speed at bifurcation is about 540 m/s on Homalite 100, and about 450 m/s on Araldite B. From the photographs, crack speeds immediately before and after bifurcation are obtained, and it is found that discontinuous change of crack speed does not exist at the moment of bifurcation in the case of Homalite 100, but exists in the case of Araldite B. From the photographs, crack opening displacement (COD) is also measured along the cracks as a function of distance r from the crack tips. The measurement results show that the CODs are proportional to √r before bifurcation. After bifurcation, the CODs of mother cracks are proportional to √r, though the CODs of branch cracks are not always proportional to √r. The energy release rate is obtained from the measured CODs, and it is found that energy release rate is continuous at bifurcation point in both cases of Homalite 100 and Araldite B. Energy flux that shows the energy flow toward a crack tip is also obtained. 相似文献
108.
Dr. Kensei Hayashida 《Rheologica Acta》1962,2(4):261-273
Zusammenfassung In der vorliegenden Arbeit wurde der Versuch unternommen, eine einheitliche Theorie aller Strömungsvorgänge im Extruder zu entwickeln, wobei von einer strukturviskosen bzw. pseudoplastischen Schmelze ausgegangen und daher die rheologischen Zustandsgleichungen vonRabinowitsch undOstwald-de Waele der Analyse der aus einer Schlepp- und einer Druckströmung überlagerten Strömungsform zugrunde gelegt wurden. Die Ergebnisse der Analyse wurden in zwei dimensionslosen Diagrammen zusammengefaßt. Die weitere Untersuchung ergab, daß nicht nur die Strömung in Richtung des Schneckenkanals, sondern auch die Leck- und die Querströmung mit den dimensionslosen Diagrammen erfaßt werden können. Als Anwendungsbeispiele der genannten Diagramme wurde der Druckgradientenverlauf, der Druckverlauf sowie die Schneckenkennlinie für eine beliebig variierbare Schneckenabmessung und einen beliebig gewählten Temperaturverlauf berechnet und mit den Versuchsergebnissen verglichen. Es wurde eine befriedigende Übereinstimmung gefunden.Es ist mir eine angenehme Pflicht, Herrn Prof. Dr.Mori für seinen wertvollen Rat bei der Durchführung dieser Untersuchungen meinen verbindlichen Dank auszusprechen. 相似文献
109.
Youhei Sohma Hitomi KitamuraHiroyuki Kawashima Hironobu HojoMasayuki Yamashita Kenichi AkajiYoshiaki Kiso 《Tetrahedron letters》2011,52(52):7146-7148
By using dimethylformamide to suppress the O-to-N acyl migration, we efficiently synthesized an O-acyl isopeptide by native chemical ligation of a peptide-thioester and a Cys-O-acyl isopeptide. The reaction mixture was then loaded onto an octadecylsilane reverse-phase HPLC column, and the isopeptide was purified by using a linear gradient of CH3CN in 0.1% aqueous trifluoroacetic acid. The recovery rate of the O-acyl isopeptide was considerably higher than that of the corresponding native polypeptide. Synthesis of O-acyl isopeptides via native chemical ligation, with O-to-N acyl migration as the final step to give the native form, has potential as an efficient method of constructing hydrophobic polypeptides. 相似文献