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排序方式: 共有230条查询结果,搜索用时 232 毫秒
91.
Molecules confined in nanopores show unusual behavior not seen in bulk systems. The present paper reports on molecular dynamics simulations of unusual freezing behavior in confined Ar. Similar to bulk Ar, liquid Ar confined in pores with a diameter D>15sigma (5.1 nm), where sigma is the diameter of the Ar atom, crystallizes when the cooling rate is lower than a critical value (Qc). We also find that the spatial confinement does not have significant influence on Qc when D>15sigma (5.1 nm). In the pore of 10sigma (3.4 nm) in diameter, on the other hand, the behavior is dramatically changed. Crystalline Ar does not appear inside the pore even when the system is cooled at a rate lower than the Qc in the bulk system by over two orders of magnitude. Instead, amorphous Ar characterized by local icosahedral configurations is formed in the pore. We further find that, even when crystalline Ar is formed outside the pore, it does not grow deeply into the pore. This supports that the amorphous Ar is actually the most stable phase in the pore. It is well known that Ar is a poor glass former. Our finding that even such an amorphous Ar is the most stable in the pore suggests that, in any system, it is possible to prepare amorphous structure selectively by using nano-molds. 相似文献
92.
Mary K. Miller Haopei Wang Kengo Hanaya Olivia Zhang Alex Berlaga Zachary T. Ball 《Chemical science》2020,11(38):10501
Polypeptides present remarkable selectivity challenges for chemical methods. Amino groups are ubiquitous in polypeptide structure, yet few paradigms exist for reactivity and selectivity in arylation of amine groups. This communication describes the utilization of boronic acid reagents bearing certain o-electron withdrawing groups for copper-mediated amine arylation of the N-terminus under mild conditions and primarily aqueous solvent. The method adds to the toolkit of boronic acid reagents for polypeptide modification under mild conditions in water that shows complete selectivity for the N-terminus in the presence of lysine side chains.The discovery of unique Chan-Lam coupling reactivity of arylboronic acids containing an ortho-sulfonamide group allows site-specific tailoring of peptide structure. 相似文献
93.
Supported Gold Nanoparticles for Efficient α‐Oxygenation of Secondary and Tertiary Amines into Amides
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Dr. Xiongjie Jin Kengo Kataoka Takafumi Yatabe Dr. Kazuya Yamaguchi Prof. Dr. Noritaka Mizuno 《Angewandte Chemie (International ed. in English)》2016,55(25):7212-7217
Although the α‐oxygenation of amines is a highly attractive method for the synthesis of amides, efficient catalysts suited to a wide range of secondary and tertiary alkyl amines using O2 as the terminal oxidant have no precedent. This report describes a novel, green α‐oxygenation of a wide range of linear and cyclic secondary and tertiary amines mediated by gold nanoparticles supported on alumina (Au/Al2O3). The observed catalysis was truly heterogeneous, and the catalyst could be reused. The present α‐oxygenation utilizes O2 as the terminal oxidant and water as the oxygen atom source of amides. The method generates water as the only theoretical by‐product, which highlights the environmentally benign nature of the present reaction. Additionally, the present α‐oxygenation provides a convenient method for the synthesis of 18O‐labeled amides using H218O as the oxygen source. 相似文献
94.
Dr. Yunfeng Bao Dr. Shiwen Du Dr. Kengo Shibata Dr. Xiangyang Guo Yoshinobu Kamakura Prof. Dr. Zhaochi Feng Prof. Dr. Yanqiang Huang Prof. Dr. Osamu Ishitani Prof. Dr. Kazuhiko Maeda Prof. Dr. Fuxiang Zhang 《Angewandte Chemie (International ed. in English)》2023,62(4):e202214273
Developing mixed-anion semiconductors for solar fuel production has inspired extensive interest, but the nitrohalide-based photocatalyst is still in shortage. Here we report a layered nitro-halide β-ZrNBr with a narrow band gap of ca. 2.3 eV and low defect density to exhibit multifunctionalities for photocatalytic water reduction, water oxidation and CO2 reduction under visible-light irradiation. As confirmed by the results of electron paramagnetic resonance (EPR) and density functional theory (DFT) calculations, the formation of anion vacancies in the nitro-halide photocatalyst was inhibited due to its relatively high formation energy. Furthermore, performance of β-ZrNBr can be effectively promoted by a simple exfoliation into nanosheets to shorten the carrier transfer distance as well as to promote charge separation. Our work extends the territory of functional photocatalysts into the nitro-halide, which opens a new avenue for fabricating efficient artificial photosynthesis. 相似文献
95.
Minoru Yamaji Hajime Maeda Keita Minamida Tomohiro Maeda Kengo Asai Gen-Ichi Konishi Kazuhiko Mizuno 《Research on Chemical Intermediates》2013,39(1):321-345
Photophysical and photochemical properties of naphthalenes substituted with trimethylsilylethynyl, tert-butylethynyl, and trimethylsilylbutadiynyl groups were investigated by measurement of fluorescence yields, lifetimes, and triplet absorption. Introducing trimethylsilylethynyl and tert-butylethynyl groups to the 1-position of the naphthalene skeleton substantially enhanced fluorescence and intersystem crossing (ISC). The rates of fluorescence of 2-substituted naphthalenes were low. The effect of ethynyl groups on the 1-substituted naphthalenes was rationalized in terms of an increase of the transition moment along the short axis of the naphthalene skeleton. Substitution of the trimethylsilylbutadiynyl group at the 1 or 2-position of the naphthalene skeleton caused a considerable decrease in the fluorescence yield (approximately 0.01) and an increase in the ISC yield (0.99). 相似文献
96.
Kengo Matsumoto 《Israel Journal of Mathematics》2013,196(1):235-272
We will study a certain synchronizing property of subshifts called λ-synchronization. The λ-synchronizing subshifts form a large class of irreducible subshifts containing irreducible sofic shifts. We prove that the λ-synchronization is invariant under flow equivalence of subshifts. The λ-synchronizing K-groups and the λ-synchronizing Bowen-Franks groups are studied and proved to be invariant under flow equivalence of λ-synchronizing subshifts. They are new flow equivalence invariants for λ-synchronizing subshifts. 相似文献
97.
98.
99.
Prof. Dr. Hiromitsu Maeda Kengo Chigusa Dr. Tsuneaki Sakurai Prof. Dr. Kazuchika Ohta Dr. Shinobu Uemura Prof. Dr. Shu Seki 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(28):9224-9233
Modified 3,5‐dipyrrolylpyrazole (DPP) derivatives in their protonated form produce planar [2+2]‐type complexes with trifluoroacetate (TFA) ions. These complexes serve as constituent components of ion‐pair‐based assemblies. An essential strategy for the construction of dimension‐controlled organized structures based on these [2+2]‐type complexes is the introduction of aryl rings bearing long alkyl chains, which enables the formation of 2D patterns at interfaces, supramolecular gels, and mesophases. 相似文献
100.
Yusuke Uchida Kengo Fukuda Yoshihiko Murakami 《Journal of Polymer Science.Polymer Physics》2013,51(2):124-131
We have developed a novel hydrogel that is formed from a crosslinkable trilayered polymeric micelle and a polyamine for the sustained release of hydrophilic compounds. This hydrogel is quite unique because the vesicle‐like structure of the trilayered polymeric micelle acts as not only a crosslinker of the hydrogel but also a container of hydrophilic compounds. The hydrogel is rapidly formed by mixing both the trilayered polymeric micelle solution and the polyamine solution. The gelation property of the hydrogel, such as the storage modulus, can be changed by tuning the molecular weights, concentrations, and pH of the dissolving solvent of the hydrogel's constituent components. Furthermore, it is clarified that the structural difference among the micelles acting as crosslinkers affects the gelation property of the hydrogel. Amazingly, the hydrogel that is formed from the trilayered polymeric micelles possessing a vesicle‐like flexible structure exhibits a higher storage modulus than the hydrogel that is formed from the bilayered polymeric micelles possessing a highly packed, hard structure. Our results demonstrates that a microscopic structural difference of crosslinkers can induce a macroscopic (and, in some cases, an interesting and unexpected) change in the properties of the resulting hydrogels. For medical applications, the hydrogel proposed in the present article can encapsulate the hydrophilic compounds so that the hydrogel can be available as the material for their sustained release. © 2012 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys, 2013 相似文献