The hydrological response of heavy clay grassland soils to rainfall in south‐west England using δ2H

Stable isotopes of water have been previously used in catchment studies to separate rain‐event water from pre‐event groundwater. However, there are a lack of studies at the smaller scale looking at the separation of event water from pre‐event water. This is particularly relevant for heavy clay soil systems through which the movement of water is uncertain but is thought to be rainwater‐dominated. The data presented here were collected at a rural site in the south‐west of England. The historic rainfall at the site was isotopically varied but similar to the global meteoric water line, with annual weighted means of ?37‰ for δ²H and ?5.7‰ for δ¹⁸O and with no seasonal variation. Drainage was sampled from the inter‐flow (surface runoff + lateral through‐flow) and drain‐flow (55 cm deep mole drains) pathways of two 1 ha lysimeters during two rainfall events, which had δ²H values of ?68‰ and ?92‰, respectively. The δ²H values of the lysimeter drainage water suggest that there was no contribution of event water during the first, small discharge (Q) event; however, the second larger event did show isotopic variation in δ²H values negatively related to Q indicating that rainwater was contributing to Q. A hydrograph separation indicated that only 49–58% of the inter‐flow and 18–25% of the drain‐flow consisted of event water. This was surprising given that these soil types are considered retentive of soil water. More work is needed on heavy clay soils to understand better the nature of water movement from these systems. Copyright © 2010 John Wiley & Sons, Ltd.     

Heat Kernel Empirical Laws on $${\mathbb {U}}_N$$ and $${\mathbb {GL}}_N$$GLN

This paper studies the empirical laws of eigenvalues and singular values for random matrices drawn from the heat kernel measures on the unitary groups \({\mathbb {U}}_N\) and the general linear groups \({\mathbb {GL}}_N\), for \(N\in {\mathbb {N}}\). It establishes the strongest known convergence results for the empirical eigenvalues in the \({\mathbb {U}}_N\) case, and the first known almost sure convergence results for the eigenvalues and singular values in the \({\mathbb {GL}}_N\) case. The limit noncommutative distribution associated with the heat kernel measure on \({\mathbb {GL}}_N\) is identified as the projection of a flow on an infinite-dimensional polynomial space. These results are then strengthened from variance estimates to \(L^p\) estimates for even integers p.     

A unique three-dimensional coordination cluster based on a silver carbene complex

In an attempt to perform a simple anion-exchange reaction on a pincer-carbene-ligated nickel complex using AgNO(3), we instead obtained an unexpected three-dimensional (3D) Ag(7) cluster containing a [Ag(6)] core in a twisted-bowtie geometry. The reverse-transmetalation reaction by which the carbene is transferred from nickel to silver is virtually unprecedented. The CNC pincer-carbene ligands exhibit unusual bridging modes of ligand bonding for all three donor atoms. Another unique feature is that the final structure exhibits a 3D structure brought about by the connection of two-dimensional layers of the [Ag(6)] core via a seventh Ag ion.     

Synthesis and structure of the medium-pore zeolite PST-35 with two interconnected cages of unusual orthorhombic shape

The search for new zeolite structures and compositions remains important in synthetic materials science due to the high impact on developing new chemical technologies, as well as on improving existing ones. Herein we present the synthesis and structure of PST-35, a novel medium-pore germanosilicate (Si/Ge = 2.1–6.6) zeolite, achieved by combining the excess fluoride approach and the unique structure directing ability of Ge in the presence of 1,2,3-triethylimidazolium ions as an organic structure-directing agent. PST-35 contains a zig-zag 10-ring (4.6 × 6.7 Å) channel system constructed of strictly alternating large 28-hedral ([4⁸·5⁸·6⁸·8²·10²]) and smaller 18-hedral ([4⁶·5⁴·6⁴·8²·10²]) cages of anomalous orthorhombic shape. The PST-35 structure is built from the connection of pst-35 layers consisting of small 8-hedral ([4³·5⁴·6]) cages, previously unobserved zeolite building layers, through single 4-rings.

A medium-pore zeolite containing 2 novel orthorhombic-shaped cages was synthesized by combining the tendency of Ge to form double 4-ring units with the structure-directing ability of 1,2,3-triethylimidazolium ions under excess fluoride conditions.     

Palladium-vacancy pairs in p-type and n-type germanium

Time differential perturbed angular correlation spectroscopy was performed for n-type and p-type germanium samples that had been recoil-implanted with the probe ¹⁰⁰Pd/¹⁰⁰Rh. Two different measurements with the detectors aligned along <100> and <110> crystallographic directions of germanium confirm that the palladium probe pairs with the nearest neighbour vacancy and not a dopant. The pairs interact with a coupling constant of υ _Q = 10.7(2) MHz and this agrees with what has been observed in undoped Ge. This further suggests that the palladium pairs with a vacancy in germanium, doped or un-doped. It was also observed that there are more Pd-V pairs in Ga-doped than there are in Sb-doped Ge. DFT calculations of the binding energies of the Pd-defect complexes support the experimental observations.     

Representation of partially ordered sets

It is well known [1] that any distributive poset (short for partially ordered set) has an isomorphic representation as a poset (Q, (–) such that the supremum and the infimum of any finite setF ofp correspond, respectively, to the union and intersection of the images of the elements ofF. Here necessary and sufficient conditions are given for similar isomorphic representation of a poset where however the supremum and infimum of also infinite subsetsI correspond to the union and intersection of images of elements ofI. Presented by R. Freese.     

Climbing ability of four-wheel-drive vehicles

The maximum angle of climb and the gear ratios needed for different angles of climb are calculated from vehicle specifications, terrain values and coefficients of rolling resistance. The torques demanded from the motor for different gear ratios are calculated for slopes climbed at constant speed and for short slopes climbed with loss of speed.     

An enthalpy balance approach to the study of metabolic activity in mammalian cells

After a formal explanation of Mayer's enthalpy balance method as applied to biological reaction rates, the history of its application is traced from Rubner's dog to accounting for the energy of muscle contraction. The introduction of microcalorimetry allowed the method generally to be used for cells in vitro and now particular emphasis can be paid to the growth of cells for the production of therapeutically-important heterologous proteins. In these systems, enthalpy balance studies contribute to defining catabolic processes, designing media, understanding the mechanisms of growth and controlling cultures using heat flux as an on-line sensor of metabolic activity.Plenary LectureThe authors are grateful to the BBSRC (UK) for a research grant, 2/3680.