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111.
Yasemin ?. ?iftci Kemal ?olako?lu Cansu ?oban Engin Delig?z 《Central European Journal of Physics》2012,10(1):197-205
The structural, elastic and thermodynamic characteristics of CeGa2 compound in the AlB2 (space group: P6/mmm) and the omega trigonal (space group: P-3m1) type structures are investigated using the methods of density
functional theory within the generalized gradient approximation (GGA). The thermodynamic properties of the considered structures
are obtained through the quasi-harmonic Debye model. The results on the basic physical parameters, such as the lattice constant,
the bulk modulus, the pressure derivative of bulk modulus, the phase-transition pressure (P
t
) from P6/mmm to P-3m1 structure, the second-order elastic constants, Zener anisotropy factor, Poisson’s ratio, Young’s modulus,
and the isotropic shear modulus are presented. In order to gain further information, the pressure and temperature-dependent
behavior of the volume, the bulk modulus, the thermal expansion coefficient, the heat capacity, the entropy, Debye temperature
and Grüneisen parameter are also evaluated over a pressure range of 0–6 GPa and a wide temperature range of 0–1800 K. The
obtained results are in agreement with the available experimental and the other theoretical values. 相似文献
112.
113.
Mustafa Kemal Berktaş Septimiu Crivei Fatma Kaynarca Derya Keskin Tütüncü 《Journal of Pure and Applied Algebra》2021,225(6):106621
Two uniqueness theorems on uniform decompositions due to Krause, Diracca and Facchini are extended from abelian categories to weakly idempotent complete exact categories. We give applications to (quasi-)abelian categories, finitely accessible additive categories and exactly definable additive categories. 相似文献
114.
The chemical compositions of the essential oils obtained by hydrodistillation from the aerial parts of Scutellaria diffusa, Scutellaria heterophylla and Scutellaria salviifolia were separately identified simultaneously by gas chromatography and gas chromatography-mass spectrometry. The main components were determined as hexadecanoic acid (30%) and caryophyllene oxide (9%) in the oil of S. diffusa. Germacrene D (21%), hexadecanoic acid (16%) and β-caryophyllene (13%) were found as major components in the oil of S. heterophylla. The main components of the oil of S. salviifolia were germacrene D (40%), bicyclogermacrene (14%) and β-caryophyllene (11%). Overall, individually 63, 68 and 43 constituents were identified in the aerial parts of S. diffusa, S. heterophylla and S. salviifolia essential oils representing 92.1%, 89.9% and 90% of the total, respectively. 相似文献
115.
In this study, a modular ligand structure was designed by altering the binding position of the phenyl group at backbone of hydrobenzoin. A series of regio isomeric substituted phthalonitriles derived from this modular C2-symmetric ligand was synthesized and characterized. Then, eight cobalt (II) phthalocyanines (CoPc) were obtained from the reaction of phthalonitrile derivatives with cobalt (II) chloride. The catalytic activities of synthesized cobalt (II) phthalocyanines were tested for benzyl alcohol oxidation in acetonitrile using tert-butylhydroperoxide as the oxygen source and in the presence of N-bromosuccinimide as an additive at 80 °C for 5 hr of the reaction. In this sense, the effect of substrate to catalyst ratio and oxidant to catalyst ratio have been studied in detail for getting the highest benzaldehyde selectivity (up to 83%). The effect of structural design of substituents at peripheral or non-peripheral positions of phthalocyanine skeleton on the catalytic activity performance of cobalt (II) phthalocyanines in benzyl alcohol oxidation was also clarified. All newly synthesized compounds are characterized by FT-IR, 1H NMR, IR, UV–Vis and MALDI-TOF MS spectral data. 相似文献
116.
Jean M. J. Tronchet Kemal Deen Pallie Françoise Barbalat-Rey 《Journal of carbohydrate chemistry》2013,32(1):29-52
The stereochemistry of the reaction of the conjugate base of nitromethane with aldehydosugars was shown to depend on the reaction conditions and the structure of the glycosyl group. Some reactions of a novel type of synthetic intermediates in carbohydrate chemistry, the gem-bromonitroenoses are described. 相似文献
117.
Pınar Esra Erden Abdullah Dirican Meryem Seferinoğlu Emin Yeltepe Namık Kemal Şahin 《Journal of Radioanalytical and Nuclear Chemistry》2014,301(1):159-166
Activity concentrations of 234U, 238U and 226Ra in mineral waters were determined on the basis of nine water bottling facilities using alpha particle spectrometry. The mineral water samples were collected from three geographic regions of Turkey. The radiochemical separation used in the uranium analysis is based on the isolation of uranium radioisotopes from other radionuclides such as Th, Am, Pu and Np using UTEVA resin. Alpha sources were prepared using electrodeposition method. The activity concentration of 226Ra was determined after deposition on a membrane using BaSO4 co-precipitation method. The activity concentrations (mBq L?1) of 226Ra, 238U and 234U ranged from <0.56 to 165, from <0.42 to 439 and from <0.42 to 464, respectively. The measured activity concentrations were used for the calculation of the average total annual effective ingestion doses for children and adults. The committed effective doses were calculated for three different scenarios according to mineral water consumption rate. In the most extreme scenario (for age group 12–17), all water samples except MW1 and MW2 cause annual committed effective doses below the reference level (0.1 mSv year?1) recommended by World Health Organization (WHO). 相似文献
118.
We describe a robust method for constructing a tubular surface surrounding a spacelike curve with a spacelike principal normal
in Minkowski 3-Space. Our method is designed to eliminate undesirable twists and wrinkles in the tubular surface’s skin at
points where the curve experiences high torsion. In our construction the tubular surface’s twist is bounded by the spacelike
curve’s curvature and is independent of the spacelike curve’s torsion.
相似文献
119.
Alper Şen Hande Yaman Kemal Güler Evren Körpeoğlu 《The Journal of the Operational Research Society》2014,65(11):1636-1648
We consider a problem faced by a procurement manager who needs to purchase a large volume of multiple items over multiple periods from multiple suppliers that provide base prices and discounts. Discounts are contingent on meeting various conditions on total volume or spend, and some are tied to future realizations of random events that can be mutually verified. We formulate a scenario-based multi-stage stochastic optimization model that allows us to consider random events such as a drop in price because of the most favoured customer clauses, a price change in the spot market or a new discount offer. We propose certainty-equivalent heuristics and evaluate the regret of using them. We use our model for three bidding events of a large manufacturing company. The results show that considering most favored customer clauses in supplier offers may create substantial savings that may surpass the savings from regular discount offers. 相似文献
120.