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341.
Several Techniques have been used successively or in combination to approach a better understanding of surfaces modified by silicotungstic heteropolyanion. Due to the strikingly high activity of these electrodes for the hydrogen evolution reaction, in particular, there exists a need to identify the chemical composition of the catalyst, to evaluate the amount of catalyst on the surface, and to study the electrochemical behaviour of the “catalyst” itself. Plasma emission spectrometry shows semi-quantitatively that the catalyst resembles the starting material closely, although it is not possible at present to give the exact chemical formula. Electron microprobe analysis (EMA) confirms the presence of tungsten, and especially silicon, on the surface, even though the concentration of this last element is very low. The absence of platinum in the starting HPA, as well as on the electrode surface, is also clearly demonstrated by EMA, which is of prime importance in showing that the “HPA catalyst” is active by itself. Combined coulometry and UV-visible spectroscopy have been used to evaluate the amount of HPA consumed during electrolysis. Cyclic voltammetry shows a surface redox couple corresponding to the catalyst, and well separated from the first redox couple of SiW12O4-4 in 0.5 M H2SO4 solution. A better understanding of the activation-deactivation processes of the catalytic electrode surface ensues.  相似文献   
342.
Arylation of both acyclic ketones and primary and secondary amines was achieved using a new, simple, stable, and easy-to-access nickel(II)-halide complex bearing mixed PPh3/N-heterocyclic carbene ligands as a catalyst precursor. Acyclic ketones were first arylated at the alpha-position with the nickel catalyst. On the other hand, less basic amines, such as diphenylamine and 4-aminobenzophenone, were more favorable in the catalytic amination of haloarenes than basic amines, contrary to previous reports. N-Arylation of 4-aminopropiophenone was found to proceed selectively without causing alpha-arylation of the ketone group.  相似文献   
343.
Three stable isotope ratios, D/H, (13)C/(12)C and (18)O/(16)O, are measurable in ethanol, an important organic compound that is used as a material for food and beverages, fuel and chemical feedstock, and as a substance related to metabolism. We developed a simple and rapid method of measurement of three isotope ratios of ethanol in aqueous solution at millimole levels using gas chromatography-high-temperature conversion or combustion-isotope ratio mass spectrometry (GC-TC/C-IRMS) combined with solid-phase microextraction (SPME). Using this method, the delta value for ethanol was determined in 30 min for deltaD and delta(13)C, and in 75 min for delta(18)O with precisions of +/-9 per thousand, +/-0.3 per thousand and +/-0.7 per thousand, respectively, for deltaD, delta(13)C, and delta(18)O. An advantage of this process is that it requires no distillation for ethanol purification. The method is useful for small quantities of analyte with low ethanol concentrations, which is expected for environmental and metabolic studies.  相似文献   
344.
Five Co(II) silicotungstate complexes are reported. The centrosymmetric heptanuclear compound K(20)[{(B-beta-SiW(9)O(33)(OH))(beta-SiW(8)O(29)(OH)(2))Co(3)(H(2)O)}(2)Co(H(2)O)(2)]47 H(2)O (1) consists of two {(B-beta-SiW(9)O(33)(OH))(beta-SiW(8)O(29)(OH)(2))Co(3)(H(2)O)} units connected by a {CoO(4)(H(2)O)(2)} group. In the chiral species K(7)[Co(1.5)(H(2)O)(7))][(gamma-SiW(10)O(36))(beta-SiW(8)O(30)(OH))Co(4)(OH)(H(2)O)(7)]36 H(2)O (2), a {gamma-SiW(10)O(36)} and a {beta-SiW(8)O(30)(OH)} unit enclose a mononuclear {CoO(4)(H(2)O)(2)} group and a {Co(3)O(7)(OH)(H(2)O)(5)} fragment. The two trinuclear Co(II) clusters present in 1 enclose a mu(4)-O atom, while in 2 a mu(3)-OH bridging group connects the three paramagnetic centers of the trinuclear unit, inducing significantly larger Co-L-Co (L=mu(4)-O (1), mu(3)-OH (2)) bridging angles in 2 (theta(av(Co-L-Co))=99.1 degrees ) than in 1 (theta(av(Co-L-Co))=92.8 degrees ). Weaker ferromagnetic interactions were found in 2 than in 1, in agreement with larger Co-L-Co angles in 2. The electrochemistry of 1 was studied in detail. The two chemically reversible redox couples observed in the positive potential domain were attributed to the redox processes of Co(II) centers, and indicated that two types of Co(II) centers in the structure were oxidized in separate waves. Redox activity of the seventh Co(II) center was not detected. Preliminary experiments indicated that 1 catalyzes the reduction of nitrite and NO. Remarkably, a reversible interaction exists with NO or related species. The hybrid tetranuclear complexes K(5)Na(3)[(A-alpha-SiW(9)O(34))Co(4)(OH)(3)(CH(3)COO)(3)]18 H(2)O (3) and K(5)Na(3)[(A-alpha-SiW(9)O(34))Co(4)(OH)(N(3))(2)(CH(3)COO)(3)]18 H(2)O (4) were characterized: in both, a tetrahedral {Co(4)(L(1))(L(2))(2)(CH(3)COO)(3)} (3: L(1)=L(2)=OH; 4: L(1)=OH, L(2)=N(3)) unit capped the [A-alpha-SiW(9)O(34)](10-) trivacant polyanion. The octanuclear complex K(8)Na(8)[(A-alpha-SiW(9)O(34))(2)Co(8)(OH)(6)(H(2)O)(2)(CO(3))(3)]52 H(2)O (5), containing two {Co(4)O(9)(OH)(3)(H(2)O)} units, was also obtained. Compounds 2, 3, 4, and 5 were less stable than 1, but their partial electrochemical characterization was possible; the electronic effect expected for 3 and 4 was observed.  相似文献   
345.
The electrochemical behavior of the ball-shaped heteropolytungstates [[Sn(CH(3))(2)(H(2)O)](24)[Sn(CH(3))(2)](12)(A-XW(9)O(34))(12)](36-) (X=P, 1; As, 2) was examined in aqueous electrolytes by redissolution of their respective mixed cesium-sodium salts Cs(14)Na(22)[[Sn(CH(3))(2)(H(2)O)](24)[Sn(CH(3))(2)](12) (A-PW(9)O(34))(12)]149 H(2)O (Cs(14)-1) and Cs(14)Na(22)[[Sn(CH(3))(2)(H(2)O)](24)[Sn(CH(3))(2)](12)(A-AsW(9)O(34))(12)]149 H(2)O (Cs(14)-2). In the studied media, Cs(14)-2 is readily soluble in contrast to the significantly less soluble Cs(14)-1. The solubility of Cs(14)-1 is increased by the presence of Li(+) ions in solution. Gel filtration studies with 1 and 2 rule out a decay of the dodecameric spherical assemblies to Keggin-based monomers on the timescale of the experiment. By UV/Vis spectroscopy and cyclic voltammetry, 2 was found to be significantly less stable than 1 and both polyanions also show rather different decomposition pathways. Polyanion 1 collapses first into Keggin-type monomers which might contain the trilacunary [A-alpha-PW(9)O(34)](9-). The final monomeric species obtained from 1 appears to be very similar to [PW(11)O(39)](7-), which is the final transformation product of [A-alpha-PW(9)O(34)](9-) in the same media. In contrast, 2 does not seem to follow an analogous transformation pathway as that of the trilacunary [A-alpha-AsW(9)O(34)](9-). Importantly, stabilization of 1 is observed in chloride media. The fairly long-term stability of 1 in 1 M LiCl, pH 3, has allowed for its electrochemical study to be carried out. The solid-state cyclic voltammogram of 1 entrapped in a carbon paste electrode shows the same characteristics as 1 dissolved in chloride solutions, thus supporting the conclusion that the polyanion is stable in these environments. Controlled potential coulometry on 1 indicates that the number of electrons consumed in the first wave is larger than twenty. To our knowledge, 1 constitutes the first example of a molecule that can take up such a large number of electrons resulting in a chemically reversible W-wave. These properties show promise for future fundamental and applied studies. Polyanion 1 is also efficient in the electrocatalytic reduction of NO(x), including nitrate. Finally, a remarkable interaction was found between 1 and NO, a highly promising feature for biomimetic applications.  相似文献   
346.
The grafting of the triangular 1,3,5-benzene tricarboxylate linkers (denoted trim) on tetrahedral ε-Keggin polyoxometalates (POMs) capped by Zn(II) ions, formed in situ under hydrothermal conditions, has generated three novel POM-based metal organic frameworks (POMOFs). (TBA)(3)[PMo(V)(8)Mo(VI)(4)O(36)(OH)(4)Zn(4)][C(6)H(3)(COO)(3)](4/3)·6H(2)O (ε(trim)(4/3)) is a 3D open-framework built of molecular Keggin units connected by trim linkers, with channels occupied by tetrabutylammonium (TBA) counterions. ε(trim)(4/3) is a novel (3,4)-connected net, named ofp for open-framework polyoxometalate, and computer simulations have been used to evaluate its relative stability in comparison with ctn- and bor-like polymorphs, showing the stability of this novel phase directly related to its greatest density. A computational study was also undertaken with the aim of locating TBA molecules, the positions of which could not be deduced from single crystal X-ray diffraction, and further rationalizes their structure directing role. In (TBA)(3)[PMo(V)(8)Mo(VI)(4)O(37)(OH)(3)Zn(4)][C(6)H(3)(COO)(3)] (ε(2)(trim)(2)), the building unit is not the molecular Keggin but a dimerized form of this POM. Their connection via trim linkers generates a 3D framework with channels filled by TBA cations. In (TBA)(3)[PMo(V)(8)Mo(VI)(4)O(37)(OH)(3)Zn(4)][C(6)H(3)(COO)(3)]·8H(2)O ([ε(trim)](∞)), zigzag chains are connected via the organic linkers, forming 2D grids. Modified electrodes were fabricated by direct adsorption of the POMOFs on glassy carbon or entrapment in carbon paste (CPE). A remarkable electrocatalytic hydrogen evolution reaction (HER) was detected with a yield greater than 95%, and a turnover number as high as 1.2 × 10(5) was obtained after 5 h. The reported POMOF-based electrodes are more active than platinum, with a roughly 260 mV anodic shift. Finally, the electrocatalytic activities of ε(trim)(4/3)/CPE electrodes in various XCl (X = Li, Na, K, Cs) media have been studied. This allowed us to detect a cation effect and propose an electrocatalytic mechanistic pathway for the HER.  相似文献   
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350.
Recent spectrophotometric and molecular dynamics simulation studies have shown that the physicochemical properties and structures of water in the vicinity of hydrophobic surfaces differ from those of the bulk water. However, the interfacial water acting as a separation medium on hydrophobic surfaces has never been detected and quantified experimentally. In this study, we show that small inorganic ions and organic molecules differentiate the interfacial water formed on the surfaces of octadecyl-bonded (C(18)) silica particles from the bulk water and the chemical separation of these solutes in aqueous media with hydrophobic materials can be interpreted with a consistent mechanism, partition between the bulk water phase and the interfacial water formed on the hydrophobic surface. Thermal transition behaviour of the interfacial water incorporated in the nanopores of the C(18) silica materials and the solubility parameter of the water calculated from the distribution coefficients of organic compounds have indicated that the interfacial water may have a structure of disrupted hydrogen bonding. The thickness of the interfacial water or the limit of distance from the hydrophobic surface at which molecules and ions can sense the surface was estimated to be 1.25 ± 0.13 nm from the volume of the interfacial water obtained by a liquid chromatographic method and the surface area, suggesting that the hydrophobic effect may extend beyond the first solvation shell of water molecules directly surrounding the surfaces.  相似文献   
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