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321.
Photoliquefiable Ionic Crystals: A Phase Crossover Approach for Photon Energy Storage Materials with Functional Multiplicity
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Keita Ishiba Dr. Masa‐aki Morikawa Chie Chikara Dr. Teppei Yamada Katsunori Iwase Mika Kawakita Prof. Dr. Nobuo Kimizuka 《Angewandte Chemie (International ed. in English)》2015,54(5):1532-1536
Ionic crystals (ICs) of the azobenzene derivatives show photoinduced IC–ionic liquid (IL) phase transition (photoliquefaction) upon UV‐irradiation, and the resulting cis‐azobenzene ILs are reversibly photocrystallized by illumination with visible light. The photoliquefaction of ICs is accompanied by a significant increase in ionic conductivity at ambient temperature. The photoliquefaction also brings the azobenzene ICs further significance as photon energy storage materials. The cis‐IL shows thermally induced crystallization to the trans‐IC phase. This transition is accompanied by exothermic peaks with a total ΔH of 97.1 kJ mol?1, which is almost double the conformational energy stored in cis‐azobenzene chromophores. Thus, the integration of photoresponsive ILs and self‐assembly pushes the limit of solar thermal batteries. 相似文献
322.
Mohammad Shahabuddin Keita Ohgoshi Md. Sharif Hossain Takao Kimura Michinori Karikomi 《Tetrahedron letters》2017,58(38):3704-3707
A new class of helical shaped bi-phenol (1,1′-bibenzo[c]phenanthrene-2,2′-diol; HEBPOL) type derivatives 2a–g were synthesized from quinone derivatives using the conventional 5% Pd-C catalytic reduction process. We obtained excellent yields for all of the 2a–g derivatives. The HEBPOLs were characterized by different analytical techniques including FTIR, 1H NMR, 13C NMR, MS and X-ray crystallography. 相似文献
323.
An aqueous molecular tube composed of polyaromatic frameworks with peripheral hydrophilic groups was prepared. The new tube has a well-defined hydrophobic cavity with a diameter of ∼1 nm and quantitatively binds two molecules of fluorescent coumarin dyes in aqueous solutions. The bound coumarin dimers in a stacked fashion exhibit unusual excimer-like emissions in the confined space through efficient host–guest energy transfer. 相似文献
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Mitsunori Honda Tadashi NakajimaMaiko Okada Keita YamaguchiMitsuhiro Suda Ko-Ki KunimotoMasahito Segi 《Tetrahedron letters》2011,52(29):3740-3742
The reaction of acylsilanes with α-sulfinyl carbanions such as α-lithioalkyl sulfoxide is described. The reaction proceeds to give silyl enol ethers preferentially through the initial formation of the α-silyl alkoxide intermediates. In particular, the products derived from enolizable acylsilanes were the regio-defined silyl enol ethers that cannot be obtained by usual enolization of the corresponding unsymmetrical ketones with base. 相似文献
326.
Keita Fuchise Ryohei Kakuchi Sung‐Tso Lin Ryosuke Sakai Shin‐Ichiro Sato Toshifumi Satoh Wen‐Chang Chen Toyoji Kakuchi 《Journal of polymer science. Part A, Polymer chemistry》2009,47(22):6259-6268
The precise synthesis and variation in the thermoresponsive property based on the supramolecular assembly of a novel urea end‐functionalized poly(N‐isopropylacrylamide) (PNIPAM) were studied. A series of PNIPAMs with different diphenylurea groups at the chain end (X? Ph? NH? CO? NH? Ph? trz? PNIPAM: X = H, OCH3, CH3, NO2, Cl, and CF3) were synthesized by using a combination of the atom transfer radical polymerization and the copper(I)‐catalyzed azide‐alkyne cycloaddition. The cloud point of the obtained polymers depended on the hydrogen‐bonding ability of the introduced urea group. The 1H NMR measurement suggested that the obtained PNIPAM assembled in water via the intermolecular hydrogen bonding by the terminal urea group. From the dynamic light scattering and transmission electron microscopy measurements, the aggregated nanoparticles of the resulting polymer were directly observed in water at a temperature below its cloud point. The hydrogen‐bonding property of the chain end urea group was concluded to be involved in the aggregation of the PNIPAM in water, leading to the variation in its cloud point. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 6259–6268, 2009 相似文献
327.
Madhu Menon Ernst Richter Padma Raghavan Keita Teranishi 《Superlattices and Microstructures》2000,27(5-6):577-581
The stability of quasi-one-dimensional structures of carbon is investigated using a generalized tight-binding molecular-dynamics scheme. Large-scale simulations are made possible by the parallel implementation of the diagonalization routines. Our results show that these structures can be stable provided that their geometries consist of a core of four-fold coordinated atoms, surrounded by a three-fold coordinated outer surface accommodating one of the most stable reconstructions of bulk diamond structure. 相似文献
328.
We derive an expression for the effectivegravitational mass for any closed spacelike 2-surface.This effective gravitational energy is defined directlythrough the geometrical quantity of the freely falling 2-surface and thus is well adapted to intuitiveexpectation that the gravitational mass should bedetermined by the motion of a test body moving freely inthe gravitational field. We find that this effective gravitational mass has a reasonable positivevalue for a small sphere in the non-vacuum space-timesand can be negative for the vacuum case. Further, thiseffective gravitational energy is compared with the quasi-local energy based on the (2 + 2)formalism of General Relativity. Although some gaugefreedoms exist, analytic expressions of the quasi-localenergy for vacuum cases are the same as the effective gravitational mass. Especially, we see that thecontribution from the cosmological constant is the samein general cases. 相似文献
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330.
Kazushige Hori Mina Tamura Keita Tani Nagatoshi Nishiwaki Masahiro Ariga Yasuo Tohda 《Tetrahedron letters》2006,47(18):3115-3118
Asymmetric epoxidation of (E)-chalcone with alkaline hydrogen peroxide by novel chiral phase-transfer catalysts (chiral PTCs) with quaternary ammonium salts of azacrown ether proceeded in high yield and good enantioselectivity. Remarkably, this reaction depended on the length of the carbon chain on the nitrogen atom with the chiral PTCs and on the bulk of the base. 相似文献