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Keisuke Hatada Kuniko Hayakawa Fabrizio Palumbo Augusto Marcelli 《Journal of synchrotron radiation》2016,23(2):560-565
The occurrence of scissors modes in crystals that have deformed ions in their unit cells was predicted some time ago. The theoretical value of their energy is rather uncertain, however, ranging between ten and a few tens of eV, with the corresponding widths of 10?7 to 10?6 eV. Their observation by resonance fluorescence experiments therefore requires a photon spectrometer covering a wide energy range with a very high resolving power. Here, a new experiment is proposed and discussed in which such difficulties are overcome by measuring with a superconducting quantum interference device (SQUID) the variation of the magnetic field associated with the excitation of scissors modes. 相似文献
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Two polycatenar materials composed of a four-aromatic-ring core with a perfluorinated moiety attached in one terminal position through either butylene- or pentylene spacer groups, and three tetradecyloxy chains at the other end (abbreviated as 14PC4F and 14PC5F), were investigated to study the effect of pressure on the phase transition behaviour. A polarizing optical microscope equipped with a high pressure optical hot stage, was used for the purpose. The T vs. P phase diagrams of 14PC4F and 14PC5F were constructed in the pressure region up to 100 MPa. 14PC4F showed the stable crystal (Cr1)-columnar tetragonal (Coltet)-smectic A (SmA)-columnar hexagonal (Colh)-isoropic liquid (I) phase transition sequence under all pressures. 14PC5F exhibited the phase sequence metastable crystal (Cr2)-cubic (Cub)-Coltet-SmA-I in a melt-cooled sample on heating under pressure. But when the melt-cooled Cr2 sample was annealed at 52-54°C for 2-3 h, the stable crystal (Cr1) was formed slowly, giving a stable Cr1-Cub-Coltet-SmA-I phase sequence. The temperature region of the stable cubic phase broadened with increasing pressure. Furthermore a new mesophase of 14PC5F was pressure-induced between the I and SmA phases on cooling at pressures above about 16 MPa. Since the monotropic mesophase exhibited a texture very similar to that of the high temperature Colh phase of 14PC4F with planar orientation, the new phase was assigned at a high temperature columnar hexagonal phase of 14PC5F. 相似文献
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For the purpose of developing reflection pulse oximetry, we have analyzed the light propagation in tissue to calculate the photon-visit depth for reflected light and to estimate the measured intensities of transmitted and reflected light using the analytical solutions of the photon diffusion equation. The effects of the reflectance of the probe surface have been studied, and a low reflecting surface has been found to provide deeper photon-visit depth than a high reflecting surface for reflection pulse oximetry. Based on analytical estimation, we made reflection type probes, and conducted preliminary experiments to confirm the feasibility of this type of pulse oximetry. 相似文献