全文获取类型
收费全文 | 163篇 |
免费 | 15篇 |
专业分类
化学 | 140篇 |
晶体学 | 9篇 |
数学 | 6篇 |
物理学 | 23篇 |
出版年
2022年 | 2篇 |
2020年 | 4篇 |
2019年 | 6篇 |
2018年 | 2篇 |
2017年 | 1篇 |
2016年 | 5篇 |
2015年 | 11篇 |
2014年 | 9篇 |
2013年 | 9篇 |
2012年 | 16篇 |
2011年 | 15篇 |
2010年 | 7篇 |
2009年 | 5篇 |
2008年 | 14篇 |
2007年 | 16篇 |
2006年 | 4篇 |
2005年 | 9篇 |
2004年 | 5篇 |
2003年 | 10篇 |
2002年 | 4篇 |
2001年 | 4篇 |
2000年 | 2篇 |
1999年 | 1篇 |
1998年 | 2篇 |
1997年 | 1篇 |
1995年 | 1篇 |
1992年 | 4篇 |
1991年 | 2篇 |
1990年 | 1篇 |
1984年 | 1篇 |
1982年 | 3篇 |
1978年 | 1篇 |
1977年 | 1篇 |
排序方式: 共有178条查询结果,搜索用时 31 毫秒
91.
Takatsu H Kadowaki H Sato TJ Lynn JW Tabata Y Yamazaki T Matsuhira K 《J Phys Condens Matter》2012,24(5):052201
Neutron scattering experiments on a polycrystalline sample of the frustrated pyrochlore magnet Tb(2)Ti(2)O(7), which does not show any magnetic order down to 50 mK, have revealed that it shows condensation behavior below 0.4 K from a thermally fluctuating paramagnetic state to a spin-liquid ground state with quantum spin fluctuations. Energy spectra change from quasielastic scattering to a continuum with a double-peak structure at energies of 0 and 0.8 K in the spin-liquid state. Specific heat shows an anomaly at the crossover temperature. 相似文献
92.
The conditions necessary for the complete decomposition of six organic arsenic compounds, namely methylarsonic acid (MMAA), dimethylarsinic acid (DMAA), trimethylarsine oxide, tetramethylarsonium iodide, arsenocholine bromide (AsC) and arsenobetaine (AB), were investigated. The degree of decomposition of the arsenic compounds was monitored using a hydride generation (HYD) technique, because the response from this system depends strongly on the chemical species of arsenic, with inorganic arsenic (the expected product from these decomposition experiments) giving a much more intense HYD signal than the organic arsenic compounds. The arsenic compounds were decomposed by heating them with three types of acid mixture, namely HNO3? HClO4, HNO3? HClO4? HF, or HNO3? HClO4? H2SO4. Both MMAA and DMAA were decomposed completely using any of the mixed acids at a decomposition temperature of 200 °C or higher. The HNO3? HClO4? H2SO4 mixture was the most effective for decomposing AsC and AB, which are the most difficult compounds among all types of organic arsenic compound to decompose and render inorganic. The complete decomposition of AB was only achieved, however, when the temperature was 320 °C or higher, and the sample was evaporated to dryness. When the residue from this treatment was examined by high‐performance liquid chromatography combined with inductively coupled plasma atomic emission spectrometry, all of the arsenic was found to be present as arsenic(V). The optimized conditions (HNO3? HClO4? H2SO4 at 320 °C) for decomposing AB were then used to determine the total amount of arsenic in marine organisms known to contain AB. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献
93.
Yasuhiro Suzuki Masaaki Kasamatsu Shinichi Suzuki Toshio Nakanishi Masahisa Takatsu Seiji Muratsu Osamu Shimoda Seiya Watanabe Yoshinori Nishiwaki Naoki Miyamoto 《Analytical sciences》2005,21(7):855-859
Measurements of the refractive index (RI) and elemental analysis using synchrotron radiation X-ray fluorescence spectrometry (SR-XRF) were applied to the forensic discrimination of sheet-glass samples from different origins. The refractive index was calculated from the matching temperature at which the glass fragments became invisible in silicone oil. Fragments smaller than 1 mm in maximum diameter were taken from each of 11 sheet glasses and subjected to analysis by SR-XRF. The XRF spectrum of these samples indicated that a comparison of 6 elements (Ca, Fe, Sr, Zr, Ba and Ce) was useful for the discrimination of sheet glasses. Cluster analysis was performed using 33 sets of SR-XRF data obtained by triplicate measurements for the 11 glasses. Comparing 528 pairs among 33 samples, 515 pairs could be correctly discriminated. The number of indistinguishable pairs could be reduced from 36 to 4 by comparing the SR-XRF data. Elemental analysis by SR-XRF could provide small glass fragments with a more evidential value than the solely measurement of only RI, through a significant improvement of the discrimination capability. 相似文献
94.
A microwave-assisted extraction (MAE) technique for the determination of polychlorinated biphenyls (PCBs) and organochlorine pesticides (OCPs) in marine sediment samples has been investigated. The analytes were extracted under different treatment conditions, such as temperature, time and extraction solvent. They were quantified by an isotope-dilution method, and the observed concentrations and recovery yields obtained under different conditions were compared. The results of a comparison between this MAE and other extraction techniques, such as pressurized fluid extraction, saponification, sonication, and Soxhlet extraction, are also given in this report. The techniques gave comparable results with the values obtained by other extraction techniques and the certified values in the samples. However, the observed concentration values of mono- and dichlorinated biphenyls varied depending on the extraction temperature. 相似文献
95.
Keishi Sakamoto Atsushi Kasugai Masaki Tsuneoka Koji Takahashi Yukiharu Ikeda Tsuyoshi Imai Takashi Nagashima Mitsuru Ohta Tsuyoshi Kariya Kenichi Hayashi Yoshika Mitsunaka Yosuke Hirata Yasuyuki Itoh Yukio Okazaki 《International Journal of Infrared and Millimeter Waves》1997,18(9):1637-1654
A development of 170GHz/500kW level gyrotron was carried out as R&D work of ITER. The oscillation mode is TE31,8. In a short pulse experiment, the maximum power of 750kW was achieved at 85kV/40A. The efficiency was 22%. In the depressed
collector operation, 500kW/36%/50ms was obtained. The maximum efficiency of 40% was obtained at PRF=470kW whereas the power decrease by the electron trapping was observed. Pulse extension was done up to 10s at PRF=170kW with the depressed collector operation. The power was limited by the temperature increase of the output window. 相似文献
96.
97.
98.
99.
Masami Fukushima Ken FurubayashiNaotaka Fujisawa Mio TakeuchiTakeshi Komai Keishi OtsukaMitsuo Yamamoto Yasunari KawabeShigekazu Horiya 《Journal of Analytical and Applied Pyrolysis》2011,91(2):323-331
The structural features of humic acids (HAs) isolated from sediments on the bottom of dam reservoirs that can affect their binding capacities for Fe(II) were investigated by pyrolysis-gas chromatography/mass spectroscopy using tetramethylammonium hydroxide (TMAH-py-GC/MS). The binding capacities for Fe(II) increased with increasing O/C molar ratio, suggesting that the oxygen-containing functional group content plays a role in the binding of Fe(II). However, it was not possible to identify specific binding-sites for Fe(II) by TMAH-py-GC/MS analysis. Although C16:1ω7, iso-C15:0 and anteiso-C17:0 fatty acids, which serve as molecular markers of anaerobic microbial activity, were detected in all of the HA samples, the contents of these acids were not correlated with binding capacities for Fe(II). However, the ratio of C16:0 to C16:1ω7 fatty acids, which is used as an index of anaerobic bacterial activity, increased with increasing Fe(II) binding capacities of the HAs. It thus appears likely that the activities of anaerobic bacteria on the bottom of dam reservoirs contribute to alterations in the structural features for HAs, and that this process results in increased binding capacities for Fe(II). 相似文献
100.
Hirobumi Shibata Shin-ichi Ohshika Taku Ogura Satoshi Watanabe Keishi Nishio Hideki Sakai Masahiko Abe Kazuaki Hashimoto Mutsuyoshi Matsumoto 《Journal of photochemistry and photobiology. A, Chemistry》2011,217(1):136-140
Mesostructured titania particles modified with phthalocyanine (Pc) were prepared by using molecular self-assemblies of cetyltrimethylammonium bromide (CTAB) with solubilized Pc as a template. Low-angle X-ray diffraction pattern and transmission electron microscopy (TEM) image clearly show the formation of Pc/titania particles with hexagonal mesopore structures. Diffuse reflectance UV–vis spectrum and fluorescence spectrum of Pc/titania indicate that Pc molecules in the pores are in a monomeric state. In addition, Pc/titania particles have photocatalytic activity under visible light irradiation (>610 nm) due to the reduction reaction by the electrons transferred from Pc to titania. 相似文献