Decomposition of triacetone triperoxide is an entropic explosion

Both X-ray crystallography and electronic structure calculations using the cc-pVDZ basis set at the DFT B3LYP level were employed to study the explosive properties of triacetone triperoxide (TATP) and diacetone diperoxide (DADP). The thermal decomposition pathway of TATP was investigated by a series of calculations that identified transition states, intermediates, and the final products. Counterintuitively, these calculations predict that the explosion of TATP is not a thermochemically highly favored event. It rather involves entropy burst, which is the result of formation of one ozone and three acetone molecules from every molecule of TATP in the solid state.     

The Proalgebraic Completion of Rigid Groups

A finitely generated group is called representation rigid (briefly, rigid) if for every n, has only finitely many classes of simple representations in dimension n. Examples include higher rank S-arithmetic groups. By Margulis super rigidity, the latter have a stronger property: they are representation super rigid; i.e., their proalgebraic completion is finite dimensional. We construct examples of nonlinear rigid groups which are not super rigid, and which exhibit every possible type of infinite dimensionality. Whether linear representation rigid groups are super rigid remains an open question.     

Enolstannanes as electrofugal groups in allylic alkylation

Enolstannanes serve as nucleophiles towards allylic acetates under the influence of palladium(O) catalyst.     

Observation of a quantized hall resistivity in the presence of mesoscopic fluctuations

We present an experimental study of mesoscopic, two-dimensional electronic systems at high magnetic fields. Our samples, prepared from a low-mobility InGaAs/InAlAs wafer, exhibit reproducible, sample specific, resistance fluctuations. Focusing on the lowest Landau level, we find that, while the diagonal resistivity displays strong fluctuations, the Hall resistivity is free of fluctuations and remains quantized at its nu=1 value, h/e(2). This is true also in the insulating phase that terminates the quantum Hall series. These results extend the validity of the semicircle law of conductivity in the quantum Hall effect to the mesoscopic regime.     

Parallel magnetic field induced transition in transport in the dilute two-dimensional hole system in GaAs

A magnetic field applied parallel to the two-dimensional hole system in the GaAs/AlGaAs heterostructure, which is metallic in the absence of an external magnetic field, can drive the system into insulating at a finite field through a well-defined transition. The value of resistivity at the transition is found to depend strongly on density.     

Embedding with a Lipschitz function

We investigate a new notion of embedding of subsets of {?1,1}ⁿ in a given normed space, in a way which preserves the structure of the given set as a class of functions on {1, …, n}. This notion is an extension of the margin parameter often used in Nonparametric Statistics. Our main result is that even when considering “small” subsets of {?1, 1}ⁿ, the vast majority of such sets do not embed in a better way than the entire cube in any normed space that satisfies a minor structural assumption. © 2005 Wiley Periodicals, Inc. Random Struct. Alg., 2005     

Angular dependence of the magnetic-field driven superconductor-insulator transition in thin films of amorphous indium-oxide

A significant anisotropy of the magnetic-field driven superconductor-insulator transition is observed in thin films of amorphous indium-oxide. The anisotropy is largest for more disordered films which have a lower transition field. At higher magnetic fields the anisotropy reduces and even changes sign beyond a sample specific and temperature independent magnetic field value. The data are consistent with the existence of more than one mechanism affecting transport at high magnetic fields.