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631.
T. G. Ermakova A. I. Gritsa N. M. Deriglazov L. A. Tatarova V. V. Keiko T. I. Vakul'skaya V. A. Lopyrev 《Chemistry of Heterocyclic Compounds》1980,16(3):313-315
The polarographic reduction of 1-substituted 1,2,4-triazoles in dimethylformamide (DMF) and acetonitrile was studied. 1-Methyl-,
1-ethyl-, and 1,2,4-triazoles are not reduced on a mercury electrode over the range of potentials accessible for polarography.
1-Phenyl-1,2,4-triazole and 1-vinyl-1,2,4-triazole are reduced in acetonitrile via a one-electron mechanism at high negative
potentials. The reduction of 1-vinyl-1,2,4-triazole is accompanied by polymerization of the electrolysis products. A possible
mechanism for the electrochemical reduction is discussed.
Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 3, pp. 408–410, March, 1980. 相似文献
632.
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634.
A method was developed for determining the activity of lysozyme using two pipettes as a viscometer. The proposed viscometric assay uses carboxymethylchitin as a substrate and measures the enzyme activity at 22°C. The method requires only simple manipulations with the use of readily available laboratory equipment and the determination of enzyme activity is rapid. 相似文献
635.
Masayuki Sato Yoshito Abe Kazuhisa Takayama Keiko Sekiguchi Chikara Kaneko Naoko Inoue Toshio Furuya Noriyoshi Inukai 《Journal of heterocyclic chemistry》1991,28(2):241-252
The use of rigid spirocyclic dioxinones having 1-menthone as the chiral auxiliary as the enones in the photo[2 + 2]cycloaddition reactions opened novel methods for obtaining enantiomerically pure compounds, such as iridoids. Convex side preference of the sofa-conformation of these dioxinones in the photoaddition to cyclopentene increases up to 100% by introducing either a bulky substituent or 5-hexenyl group at the 3-position to these dioxinones and, hence, highly asymmetric inter- and intramolecular de Mayo reactions have been disclosed. 相似文献
636.
H. Bøggild J. Boissevain M. Cherney J. Dodd S. Esumi C. W. Fabjan D. E. Fields A. Franz E. B. Holzer T. Humanic B. V. Jacak R. Jayanti H. Kalechofsky R. Kvatadze Y. Y. Lee M. Leltchouk B. Lorstad N. Maeda A. Medvedev A. Miyabayashi M. Murray S. Nishimura E. Noteboom S. U. Pandey F. Piuz V. Polychronakos M. Potekhin G. Poulard A. Sakaguchi M. Sarabura J. Schmidt-Sorenson J. Simon-Gillo W. Sondheim M. Spegel T. Sugitate J. P. Sullivan Y. Sumi H. van Hecke W. J. Willis K. Wolf N. Xu 《Zeitschrift fur Physik C Particles and Fields》1995,69(1):621-625
CERN experiment NA44 measures pion and kaon distributions atpT=0–320 MeV/c at midrapidity in p+A and A+A collisions at 450 and 200A GeV/c, respectively. Pion production from p+Pb and A+A is slightly enhanced at lowpT relative to p+Be, but less than observed at target rapidity. The lowpT behavior can be understood in the context of the RQMD model as arising from baryonic resonance decays. 相似文献
637.
N. A. Keiko A. Yu. Rulev I. D. Kalikhman M. G. Voronkov 《Russian Chemical Bulletin》1984,33(8):1715-1716
Conclusions The reaction of-ethoxyacrolein with alcohols produces the acetals of methylglyoxal in 55–65% yields.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1878–1879, August, 1984. 相似文献
638.
639.
Keiko Ikoma Akiko Okami Tatsuo Arai Hirochika Sakuragi Katsumi Tokumaru 《Tetrahedron letters》1984,25(45):5161-5164
The photostationary isomer ratios and quantum yields for triplet sensitized isomerization of the four isomers of a conjugated imine, l-methoxyimino-3-phenyl-2-propene, were determined to explore the reaction mechanism. 相似文献
640.