全文获取类型
收费全文 | 1096篇 |
免费 | 57篇 |
国内免费 | 5篇 |
专业分类
化学 | 932篇 |
晶体学 | 13篇 |
力学 | 11篇 |
数学 | 40篇 |
物理学 | 162篇 |
出版年
2023年 | 5篇 |
2022年 | 10篇 |
2021年 | 6篇 |
2020年 | 15篇 |
2019年 | 19篇 |
2018年 | 8篇 |
2017年 | 13篇 |
2016年 | 21篇 |
2015年 | 32篇 |
2014年 | 32篇 |
2013年 | 48篇 |
2012年 | 58篇 |
2011年 | 75篇 |
2010年 | 34篇 |
2009年 | 35篇 |
2008年 | 73篇 |
2007年 | 72篇 |
2006年 | 74篇 |
2005年 | 50篇 |
2004年 | 48篇 |
2003年 | 37篇 |
2002年 | 33篇 |
2001年 | 12篇 |
2000年 | 20篇 |
1999年 | 8篇 |
1998年 | 13篇 |
1997年 | 10篇 |
1996年 | 11篇 |
1995年 | 6篇 |
1994年 | 9篇 |
1993年 | 7篇 |
1992年 | 17篇 |
1991年 | 16篇 |
1990年 | 9篇 |
1989年 | 8篇 |
1988年 | 12篇 |
1987年 | 9篇 |
1986年 | 12篇 |
1985年 | 27篇 |
1984年 | 16篇 |
1983年 | 17篇 |
1982年 | 11篇 |
1981年 | 11篇 |
1980年 | 11篇 |
1979年 | 16篇 |
1978年 | 11篇 |
1977年 | 12篇 |
1976年 | 13篇 |
1975年 | 10篇 |
1974年 | 8篇 |
排序方式: 共有1158条查询结果,搜索用时 9 毫秒
81.
Adachi I Aihara H Dijkstra HB Enomoto R Fujii H Fujii K Fujii T Fujimoto J Fujiwara N Hayashii H Higashi S Iida N Imanishi A Ikeda H Ishii T Itoh R Iwasaki H Iwata S Kajikawa R Kamae T Kato S Kawabata S Kichimi H Kishida T Kobayashi M Kuroda S Kusuki N Maruyama A Maruyama K Masuda H Matsuda T Miyamoto A Morimoto T Nakamura K Nitoh O Noguchi S Ochiai F Okuno H Okusawa T Ohshima T Ozaki H Sato T Sai F Shimonaka J Shimozawa K Shirahashi A Sugahara R Sugiyama A Suzuki S Suwada T Takahashi K 《Physical review letters》1988,60(2):97-100
82.
Bromide and iodide ions were determined simultaneously by capillary isotachophoresis using an aqueous electrolyte system; the separation principle was based on the ion-pairing equilibria between tetradecyldimethylbenzylammonium ion and these anions in the leading electrolyte. The interaction between iodide ion and tetradecyldimethylbenzylammonium ion was stronger than that for bromide ion. Thus complete separation of bromide and iodide ions could be obtained by using a leading electrolyte containing 1.5 mM tetradecyldimethylbenzylammonium ion. The pH of the leading electrolyte was adjusted to 5.0. The relative standard deviations of the zone length for bromide and iodide ions were 1.1 and 1.2%, respectively, when mixture of 3.0 mM of these ions was analysed. A 150-μl volume could be injected for the simultaneous determination of low concentrations of bromide and iodide ions. 相似文献
83.
Yoshio Iwakura Kohji Noguchi 《Journal of polymer science. Part A, Polymer chemistry》1969,7(3):801-812
A series of polyguanidines was prepared by the polyaddition reaction of biscarbodiimides with diamines. The polyaddition reaction was carried out in solution. The polymers thus obtained had intrinsic viscosities up to 0.84 and molecular weights up to 15000. The structure of the polymers was identified by comparison of their infrared spectra with those of model compounds, elementary analysis, and a study of the reaction conditions. Thermogravimetric study indicated that the polyguanidines decomposed over 170°C under nitrogen. The polyguanidines were highly resistant to hydrolytic degradation by strong acid or alkali. The polyguanidines had basic groups and formed stable hydrochloric salts when they were treated with hydrochloric acid. 相似文献
84.
2D computer simulation revealed that amino acids and weak electrolytes were cationized because of the migration of counter‐ion from a BGE zone to a sample zone, which encouraged electrokinetic injection (EKI) of these analytes (by the mobility‐boost (MB) effect). To investigate the effects of kinds and concentrations of counter‐ions on the MB effect and the analyte amount injected into the capillary, experiments, and 1D computer simulations were performed. When acetate was used as the counter‐ion, the LODs (S/N = 3) of l ‐histidine and creatinine, respectively, reached 0.10 and 0.25 nM because of the concentration effect by transient ITP (tITP). The concentrations of l ‐histidine and creatinine in human blood plasma obtained using the proposed method were agreed with those obtained using the conventional methods. The proposed method can be applied to the analysis of amino acids and weak bases that have similar pI and pKa to l ‐histidine and creatinine. 相似文献
85.
Keiichi Kimura Masayuki Kaneshige Hideo Tokuhisa Masaaki Yokoyama 《Journal of polymer science. Part A, Polymer chemistry》1993,31(11):2809-2813
Copolymers of bis[4-(N,N-dimethylamino)phenyl]-4-vinylphenylmethanenitrile (vinyl Malachite Green leuconitrile) with methyl methacrylate or ω-methoxyoligo(oxyethylene) methacrylate have been synthesized, aiming at designing one-component-type organic polymers for photoswitchable ion-conducting films. The triphenylmethanenitrile copolymers with ω-methoxyoligo(oxyethylene) methacrylate were found to undergo ionic-conductivity switching by turning on and off UV light at ambient temperature, owing to their low glass transition temperature. © 1993 John Wiley & Sons, Inc. 相似文献
86.
Masayuki Kuzuya Akihiro Noguchi Hideki Ito Shin-Ichi Kondo Nahoko Noda 《Journal of polymer science. Part A, Polymer chemistry》1991,29(1):1-7
Plasma-induced polystyrene radicals were first studied by electron spin resonance (ESR). The room temperature ESR spectrum was compared with those obtained by γ-irradiation, UV-irradiation, and mechanical fracture. It was found that even less than a few seconds of plasma-irradiation gave rise to a large amount of polystyrene radicals and the ESR spectrum consisted of two types of spectra, a triplet and a single broad line. The spectral feature of the triplet was nearly identical with that of γ-irradiated polystyrene. Thus, it was assigned to the structure of a cyclohexadienyl-type radical formed by a nearly random addition of a hydrogen atom to the aromatic ring. The single broad line, thought to be an outline of multicomponent spectrum, was assigned to an immobilized dangling-bond sites at the plasma-induced crosslinked portion of the polystyrene surface. 相似文献
87.
R. Minayoshi T. Ohyama N. Kinugawa J. Kamishima T. Ogi K. Ishikawa M. Noguchi H. Suganuma K. Takahashi S. Enomoto M. Yanaga 《Journal of Radioanalytical and Nuclear Chemistry》2007,272(2):429-431
The concentrations of essential trace elements and proteins in cytosolic fraction of hepatic cells of mice fed with Zn-deficient
diet (Zn-def, mice) and control were determined by ICP-MS and BCA protein assay method, respectively, after division into
forty fractions by gel filtration chromatography. The concentrations of zinc and proteins decreased in the 14–17th fractions
of Zn-def, mice, whereas cobalt concentrations increased in the 14, 17, and 18th fractions. However, no significant differences
were found on the gel after SDS-PAGE for the 12–21st fractions, although the BCA protein assay date showed the decrease of
protein amounts in 13–15th fractions of Zn-def. mice. 相似文献
88.
Tsuyoshi Miura Satoshi Tsujino Kohtaro Goto Midori Noguchi Manabu Node Nobuyuki Imai 《Tetrahedron》2005,61(27):6518-6526
The use of the bisfluorous chain-type propanoyl (Bfp) group as a fluorous protective group made it possible to rapidly synthesize the Gb2 and Gb3 oligosaccharide derivatives by a simple fluorous-organic extraction purification. Furthermore, the fluorescence-labeled Gb2 and Gb3 oligosaccharides were prepared as a potential Vero Toxins detecting reagent. 相似文献
89.
Keiichi Noguchi Hidekazu Kondo Yasushi Ichikawa Junichiro Washiyama Kenji Okuyama 《Acta Crystallographica. Section C, Structural Chemistry》2006,62(8):o528-o530
The 20‐membered ring of the title compound, C16H24O8, adopts an approximately flat rectangular structure with three‐ and seven‐bond sides and lies across a crystallographic center of inversion. The corners of the ring occur at both ends of one of the planar ester segments. All of the carbonyl O atoms are involved in intermolecular C—H⋯O hydrogen bonds. 相似文献
90.
K. Ohno Y. Noguchi S. Ueda J. Onoe 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2007,43(1-3):137-140
Optimized three-dimensional (3D) cell structures and energy bands
of fused (peanut-shaped) C60 polymers (p55 and p66) have been
investigated using the first-principles pseudopotential approach
within the local density approximation of the density functional theory.
We found that the resulting electronic structure is either metal or
semiconductor depending on the shape of the polymer chains and
the unit cell structure. 相似文献