全文获取类型
收费全文 | 4689篇 |
免费 | 622篇 |
国内免费 | 452篇 |
专业分类
化学 | 3449篇 |
晶体学 | 52篇 |
力学 | 263篇 |
综合类 | 36篇 |
数学 | 521篇 |
物理学 | 1442篇 |
出版年
2024年 | 18篇 |
2023年 | 74篇 |
2022年 | 125篇 |
2021年 | 172篇 |
2020年 | 158篇 |
2019年 | 173篇 |
2018年 | 157篇 |
2017年 | 128篇 |
2016年 | 218篇 |
2015年 | 188篇 |
2014年 | 234篇 |
2013年 | 333篇 |
2012年 | 333篇 |
2011年 | 374篇 |
2010年 | 259篇 |
2009年 | 251篇 |
2008年 | 280篇 |
2007年 | 252篇 |
2006年 | 256篇 |
2005年 | 183篇 |
2004年 | 171篇 |
2003年 | 148篇 |
2002年 | 176篇 |
2001年 | 135篇 |
2000年 | 104篇 |
1999年 | 112篇 |
1998年 | 96篇 |
1997年 | 84篇 |
1996年 | 54篇 |
1995年 | 75篇 |
1994年 | 60篇 |
1993年 | 50篇 |
1992年 | 52篇 |
1991年 | 32篇 |
1990年 | 36篇 |
1989年 | 15篇 |
1988年 | 18篇 |
1987年 | 12篇 |
1986年 | 26篇 |
1985年 | 24篇 |
1984年 | 17篇 |
1983年 | 15篇 |
1982年 | 12篇 |
1981年 | 12篇 |
1980年 | 6篇 |
1979年 | 10篇 |
1977年 | 4篇 |
1974年 | 7篇 |
1973年 | 7篇 |
1969年 | 4篇 |
排序方式: 共有5763条查询结果,搜索用时 15 毫秒
21.
K. Kong Wan 《Foundations of Physics》1991,21(9):1107-1116
Traditionally spatial transformations such as translations and rotations are formulated in terms of transformations of the entire spatial space. In other words, transformations are taken automatically to be of a global nature. This paper investigates a local approach to spatial transformations; local transformations lead naturally to local observables in quantum mechanics. 相似文献
22.
本文考虑积分方程的ε复杂性问题.问题的ε复杂性是在误差不超过ε的前提下解决问题所需的最小成本.对某些具各向异性核与自由项的第二类Fredholm方程,求得了ε复杂性的精确阶.同时,找到了解决该问题具最小成本的算法. 相似文献
23.
24.
利用磁场诱导的微粒运动即磁泳对磁响应性粒子进行精细分离,是近年来发展起来的选择性分离细胞和高分子量核酸的有效技术。本文在阐明磁泳分离原理的基础上,介绍了磁泳分离的分流薄层分级技术、四极磁场流动分离技术和微芯片上的自由流磁泳分离技术的装置构造、工作原理及其在生物分离分析中的应用。 相似文献
25.
In situ scanning tunneling microscopy (STM) was used to examine the structure of thiocyanate adlayers specifically adsorbed
on Rh(111) in solutions of potassium hydroxide and perchloric acid, both containing potassium thiocyanate (KSCN). An atomically
flat terrace-step structure was consistently observed on Rh(111) surfaces prepared by the flame-annealing-quenching method.
The Rh(111)-(1 × 1) atomic structure was discerned on the atomically flat terrace even in the alkaline solution. High-resolution
STM images disclosed two different structures of the SCN− adlayers, () and (2 × 2), in the alkaline and the acidic media, respectively. In each structure, an individual adsorbed SCN− ion appeared as a single spot with a constant corrugation height in STM images, suggesting that SCN− ions adsorbed predominantly with their
S-ends at particular bonding sites on Rh(111). The difference in the adlayer structure in the two solutions can be attributed
to the interaction between adsorbed SCN− and coadsorbed K+ in the alkaline solution, and is different from that between adsorbed SCN− and H+ in the acidic solution.
Received: 26 February 1997 / Accepted: 3 March 1997 相似文献
26.
A method is proposed to calculate molar conductivity based on mode coupling theory in which the ion transference number is introduced into the theory. The molar conductivities of LiPF6, LiClO4, LiBF4, LiAsF6 in PC (propylene carbonate) are calculated based on this method. The results fit well to the literature data. This presents a potential way to calculate the conductivities of Li-ion battery electrolytes. 相似文献
27.
文章介绍了新材料的重要性及发展方向,分析化学在新材料研制中起着耳目的作用,另一方面新材料也为分析化学的进展提供了课题与条件。微量分析、微区分析、表面分析是此领域中的重点。在未来的发展中,分析化学在材料的发展中的地位不会改变,并期待着分析灵敏度与空间分辩率的进一步提高。 相似文献
28.
29.
Lin CS Zhang RQ Lee ST Elstner M Frauenheim T Wan LJ 《The journal of physical chemistry. B》2005,109(29):14183-14188
The assembly of small water clusters (H2O)n, n = 1-6, on a graphite surface is studied using a density functional tight-binding method complemented with an empirical van der Waals force correction, with confirmation using second-order M?ller-Plesset perturbation theory. It is shown that the optimized geometry of the water hexamer may change its original structure to an isoenergy one when interacting with a graphite surface in some specific orientation, while the smaller water cluster will maintain its cyclic or linear configurations (for the water dimer). The binding energy of water clusters interacting with graphite is dependent on the number of water molecules that form hydrogen bonds, but is independent of the water cluster size. These physically adsorbed water clusters show little change in their IR peak position and leave an almost perfect graphite surface. 相似文献
30.
Chaotic micromixers using two-layer crossing channels to exhibit fast mixing at low Reynolds numbers
We report two chaotic micromixers that exhibit fast mixing at low Reynolds numbers in this paper. Passive mixers usually use the channel geometry to stir the fluids, and many previously reported designs rely on inertial effects which are only available at moderate Re. In this paper, we propose two chaotic micromixers using two-layer crossing channels. Both numerical and experimental studies show that the mixers are very efficient for fluid manipulation at low Reynolds numbers, such as stretching and splitting, folding and recombination, through which chaotic advection can be generated and the mixing is significantly promoted. More importantly, the generation of chaotic advection does not rely on the fluid inertial forces, so the mixers work well at very low Re. The mixers are benchmarked against a three-dimensional serpentine mixer. Results show that the latter is inefficient at Re = 0.2, while the new design exhibits rapid mixing at Re = 0.2 and at Re of O(10(-2)). The new mixer design will benefit various microfluidic systems. 相似文献