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21.
Transitions of microstructure and photoluminescence properties of the Ge/ZnO multilayer films in certain annealing temperature region 总被引:1,自引:0,他引:1
Tianhang Zheng Ziquan Li Jiankang Chen Kai Shen Kefei Sun 《Applied Surface Science》2006,252(24):8482-8486
The Ge/ZnO multilayer films have been prepared by rf magnetron sputtering. The effects of annealing on the microstructure and photoluminescence properties of the multilayers have been investigated by X-ray diffraction (XRD), transmission electron microscopy (TEM), Fourier-transform infrared (FTIR) spectrometry and photoluminescence (PL) spectrometry. The investigation of structural properties indicates that Zn2GeO4 has been formed with (2 2 0) texture and Zn deficiency from Ge/ZnO multilayer films in the process of annealing. However, lower Zn/Ge ratio can be improved by annealing. The annealed multilayers show three main emission bands at 532, 700, and 761 nm, which originate from the transition between oxygen vacancy () and Zn vacancies (VZn), the radiative recombination of quantum-confined excitons (QCE) in Ge nanocrystals, and the optical transition in the GeO color centers, respectively. Finally, the fabrication of thin film Zn2GeO4 from Ge/ZnO multilayer films by annealing at low temperature provides another approach to prepare the green-emitting oxide phosphor film:Zn2GeO4:Mn. 相似文献
22.
提出了第三代同步辐射光源中的低温超导电流扭摆器和室温水冷电流扭摆器的物理设计方案。文中还讨论了电流扭摆器内腔中的磁场的分布特性,测量方法和电流扭摆器的制造技术的可行性。 相似文献
23.
Sulfur/graphene nanocomposite material has been prepared by incorporating sulfur into the graphene frameworks through a melting process. Field‐emission scanning electron microscope analysis shows a homogeneous distribution of sulfur in the graphene nanosheet matrix. The sulfur/graphene nanocomposite exhibits a super‐high lithium‐storage capacity of 1580 mAh g?1 and a satisfactory cycling performance in lithium–sulfur cells. The enhancement of the reversible capacity and cycle life could be attributed to the flexible graphene nanosheet matrix, which acts as a conducting medium and a physical buffer to cushion the volume change of sulfur during the lithiation and delithiation process. Graphene‐based nanocomposites can significantly improve the electrochemical performance of lithium–sulfur batteries. 相似文献
24.
毛克非 《新疆大学学报(理工版)》1988,(3)
使用Feynman路径积分方法,讨论了有质量Abel规范场中的Casimir效应。结果表明:(1)光子的质量对真空零点能量(Casimir能量)有贡献;(2)规范场的纵向分量会影响到Casimir能量;(3)体系不存在光子质量m→0的连续极限。 相似文献
25.
我们利用因式化方法找到了可解 Hamilton 量的又一新系列,其本征值谱相同而本征态有简单关系,从而为寻找新的可解势提供了又一途径.并给出了两个实例. 相似文献
26.
稀土变质钒白口铸铁的研究 总被引:7,自引:0,他引:7
采用稀土单元变质剂和稀土-硅复合变变质剂对钒白口铁(1.80-2.10%)V进行变质处理,分析了两种变质处理对钒白口铸铁组织和性能的影响。结果表明,稀土-硅复合变质处理显著改善了碳化物的分布形态,并使铸铁的冲击韧性大幅度提高。 相似文献
27.
Haijun Hu Xiping Chen Kefei Zhao Weiwei Zheng Changyou Gao 《Macromolecular bioscience》2023,23(5):2200577
Traumatic brain injury (TBI), a major public health problem accompanied with numerous complications, usually leads to serve disability and huge financial burden. The adverse and unfavorable pathological environment triggers a series of secondary injuries, resulting in serious loss of nerve function and huge obstacle of endogenous nerve regeneration. With the advances in adaptive tissue regeneration biomaterials, regulation of detrimental microenvironment to reduce the secondary injury and to promote the neurogenesis becomes possible. The adaptive biomaterials could respond and regulate biochemical, cellular, and physiological events in the secondary injury, including excitotoxicity, oxidative stress, and neuroinflammation, to rebuild circumstances suitable for regeneration. In this review, the development of pathology after TBI is discussed, followed by the introduction of adaptive biomaterials based on various pathological characteristics. The adaptive biomaterials carried with neurotrophic factors and stem cells for TBI treatment are then summarized. Finally, the current drawbacks and future perspective of biomaterials for TBI treatment are suggested. 相似文献
28.
借助量子化学计算,从分子层面模拟了γ-环糊精(γ-CD)主体与L-半胱氨酸(L-Cys)氧化产物客体之间的超分子相互作用,得到γ-CD与L-Cys氧化产物之间的弱相互作用能EL(-12. 6 e V),其与D-Cys氧化产物客体的弱相互作用能(ED=-2. 7 e V)相差3. 7倍,分子内氢键键价相差近1倍.据此,构建了基于手性源γ-环糊精的阻抗型传感器,并用于L-Cys的阻抗识别.结果表明,以铁氰化钾(Ⅱ/Ⅲ)作为氧化还原探针分子,电化学阻抗信号变量(Ret)与L-Cys浓度在0. 1~1. 0μmol/L(阶段一)和1. 0~6. 0μmol/L(阶段二) 2个范围内分别呈现良好的线性关系,检出限为74 nmol/L(S/N=3).与未修饰玻碳电极相比,L-Cys在该手性传感器上的阻抗响应灵敏度提高了约19倍,对含巯基结构相似物的选择性明显提高;将该传感器应用于人体血清、药品胶囊样品的分析,平均回收率在88. 9%~108%之间.建立了一种新颖、低成本、简便的针对弱电活性手性化合物的定量识别方法,为其电化学分析提供了新策略. 相似文献
29.
Ion chromatographic analysis of anions in ammonium hydroxide,hydrofluoric acid,and slurries,used in semiconductor processing 总被引:3,自引:0,他引:3
In this study, ion chromatography (IC) with suppressed conductivity detection was used for the determination of trace anions in 29% (w/w) ammonium hydroxide, 49% (w/w) hydrofluoric acid and slurries. For these samples, various sample pretreatment methods were applied to eliminate matrix interferences. For concentrated ammonium hydroxide, an on-line electrochemical neutralizer (SP10 AutoNeutralization module) was used to neutralize the base prior to the IC analysis. For concentrated hydrofluoric acid, a heart cutting technique with an ion-exclusion column was used to separate the anions of interest prior to an IC separation. A method was also developed to analyze chloride in silica slurries by IC. 相似文献
30.