Elementary Properties of the Finite Ranks

This note investigates the class of finite initial segments of the cumulative hierarchy of pure sets. We show that this class is first-order definable over the class of finite directed graphs and that this class admits a first-order definable global linear order. We apply this last result to show that FO(<, BIT) = FO(BIT).     

Leaching Studies of Inorganic and Organic Compounds from Fly Ash

Fly ash is produced in massive quantities by fossil fuel based power plants and waste incinerators, and contains high levels of potentially toxic chemicals. Various leaching tests exist to determine the available fractions, but the outcome is strongly dependent on the experimental conditions, and these have not yet been harmonised at the international level. In order to test existing protocols for heavy metals, several intercomparisons were organised within the framework of an EU-INCO project "ANALEACH", in which seven institutes from five countries participated. Two existing reference materials were made available for the project and test batches of two new fly ash reference materials were produced. Availability tests, leaching tests and pH-stat tests were studied and critical steps in the procedures were identified. Fly ashes can also contain large amounts of inorganic sulphur and nitrogen compounds, and the determination and leaching behaviour of these compounds were also studied. In one intercomparison for metals, inorganic S and N-compounds were also included. A five-step leaching test was optimised for fly ash in order to link metal fractions to different types of binding. Column leaching experiments were carried out to investigate leaching from fly ash into soil, mimicking the effects of (acid) rain on fly ash deposited on topsoil after atmospheric transport. The major fraction of the leached metal ions was retained by the soil. Also large numbers of organic compounds (including many toxic ones) were identified in fly ash extracts, especially in city waste incinerator ash. Leaching procedures based on ultrasonic extraction were developed for organic compounds and an intercomparison exercise was organised. In a field study at the river Nitra(Slovakia) numerous organic pollutants were found at elevated levels downstream from a major fly ash dump site.     

Highly stable redox-active molecular layers by covalent grafting to conductive diamond

We demonstrate a modular "click"-based functionalization scheme that allows inexpensive conductive diamond samples to serve as an ultrastable platform for surface-tethered electrochemically active molecules stable out to ～1.3 V vs Ag/AgCl. We have cycled surface-tethered Ru(tpy)(2) to this potential more than 1 million times with little or no degradation in propylene carbonate and only slightly reduced stability in water and acetonitrile.     

An average case analysis of the minimum spanning tree heuristic for the power assignment problem

We present an average case analysis of the minimum spanning tree heuristic for the power assignment problem. The worst‐case approximation ratio of this heuristic is 2. We show that in Euclidean d‐dimensional space, when the vertex set consists of a set of i.i.d. uniform random independent, identically distributed random variables in [0,1]^d, and the distance power gradient equals the dimension d, the minimum spanning tree‐based power assignment converges completely to a constant depending only on d.     

Crystal Structure of Melaminium Orthophosphate from High‐Resolution Synchrotron Powder‐Diffraction Data

The crystal structure of melaminium orthophosphate (MP) has been determined from high‐resolution synchrotron powder‐diffraction data. The crystal packing consists of melaminium layers and pairs of orthophosphate chains connected by H‐bonds almost perpendicular to the layers. The distance between melaminium layers is 3.62 Å. Neighboring melaminium molecules do not lie in the same plane, but in two parallel planes at close distance (0.79 Å), and are shifted with respect to each other. The orthophosphate chains are connected by both intra‐chain and inter‐chain H‐bonds. The melamine is singly protonated at an endocyclic N‐atom. The powder‐diffraction data were corroborated by solid‐state NMR experiments.     

Corporate manpower planning

In this paper the necessity of corporate manpower planning is discussed and the growing interest in it within many organizations. In particular medium and long term forecasting in rather large and structured organizations are explained and the need for tools to get a survey of the evolution of their personnel strength. These tools should help management and staff-members of a planning or personnel department to design alternative policies concerning promotions, recruitments, etc.We will present a planning method which satisfies these requirements. The interactive manpower planning system FORMASY presents forecasts concerning the evolution of the personnel strength and makes it possible to assess the impacts of alternative policies. This planning system is based on a Markov model and is being used on a general purpose computer in several Dutch organizations, both industrial and governmental.FORMASY has proved its value for practical manpower planning which will be explained by means of a case-study with the Royal Dutch Airforce.