The dynamics of complex polynomials and automorphisms of the shift

Oblatum 6-XII-1989 &; 13-IX-1990     

Neo-debromoaplysiatoxin C,with new structural rearrangement,derived from debromoaplysiatoxin

Abstract

Neo-debromoaplysiatoxin C (1), a new member of the aplysiatoxin family, was isolated from the marine cyanobacterium Lyngbya sp. The structure of 1 was elucidated based on spectroscopic data, and its stereochemistry was determined from NOESY spectrum and biosynthetic considerations. This new compound presents an intriguing 10-membered lactone ring skeleton derived from debromoaplysiatoxin by structural rearrangement, which is the first example in the aplysiatoxin family. Its biological properties were evaluated for cytotoxicity, PKCδ activation and inhibitory effects on potassium channel.     

Reversible pressure-induced amorphization of a zeolitic imidazolate framework (ZIF-4)

We report the reversible pressure-induced amorphization of a zeolitic imidazolate framework (ZIF-4, [Zn(Im)(2)]). This occurs irrespective of pore occupancy and takes place via a novel high pressure phase (ZIF-4-I) when solvent molecules are present in the pores. A significant reduction in bulk modulus upon framework evacuation is also observed for both ZIF-4 and ZIF-4-I.     

Materials Formed by Combining Inorganic Glasses and Metal-Organic Frameworks

Here, we propose the combination of glassy or crystalline metal-organic frameworks (MOFs) with inorganic glasses to create novel hybrid composites and blends.The motivation behind this new composite approach is to improve the processability issues and mechanical performance of MOFs, whilst maintaining their ubiquitous properties. Herein, the precepts of successful composite formation and pairing of MOF and glass MOFs with inorganic glasses are presented. Focus is also given to the synthetic routes to such materials and the challenges anticipated in both their production and characterisation. Depending on their chemical nature, materials are classified as crystalline MOF-glass composites and blends. Additionally, the potential properties and applications of these two classes of materials are considered, the key aim being the retention of beneficial properties of both components, whilst circumventing their respective drawbacks.     

由重构矩阵存储精度引起的波前重构误差的研究

 采用Southwell区域法波前重构模型对泽尼克多项式的前几项进行了波前重构的数值模拟, 研究了由重构矩阵存储精度原因而引起的波前重构误差。结果表明,对于前六项,以8Bit的数据精度来存储重构矩阵就能保证波前重构误差不超过1.0%,而对于具有更高阶的泽尼克多项式,比8Bit更高的数据精度不会使误差减小。对一个测量所得的波前进行了研究,所得结果和上述结论相符合。     

Raman microspectroscopic mapping: a tool for the characterisation of polymer surfaces

Raman mapping by point illumination of polymer surfaces is discussed with examples taken from the plasma treatment of polypropylene (PP) and subsequent grafting of polystyrene (PS). Maps can be constructed for surface properties such as crystallinity, blend components and distribution of grafted PS. The Raman sampling volume was estimated for confocal operation using a 50x objective lens.