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991.
通过对共享保护算法的深入分析,使用K条最短路和迭代思想的方法,提出了两种共享风险链路组不相关的共享保护算法,并在仿真平台上对两种算法的性能进行了仿真.KWFF算法借鉴了传统的K条最短路策略,并且在每一个波长平面上,都对新到业务进行了K条工作路由的计算,极大挖掘了网络中潜在的波长资源.而IFF算法由于引入了迭代的思想,避免了共享风险链路组问题中,所特别有“陷阱”问题的出现,并且利用两套权重计算公式,在计算工作路由和保护路由的时候,充分考虑了网络资源的实时变化情况.通过仿真数据可以看到,与以往算法相比,KWFF和IFF算法大大降低了网络阻塞率,并且提高了网络资源的使用效率. 相似文献
992.
Transition metal-catalyzed carbene transfer reaction is one of the most notable advances for C-C bond formation reactionsduring the past decade,which has been widely employed in the preparation of C3-substituted indoles,Here,we described an efficient exa mple of catalyst-and metal-free aminobo ration of alkynes and C—C bond formation with diazo compounds to produce C3-substituted indoles,Diverse alkynyla nilines and diazo compounds ca n be utilized for this tandem transfo rmation under mild reaction conditions,re sulting in broad functional group co mpatibility.Additionally,this metal-free strategy can be extended to construct substituted benzofurans. 相似文献
993.
994.
Efficient and selective removal of 90Sr is an important process for the safe use of nuclear energy. Herein, we investigate and assess the Sr2+ adsorption properties of a metal-organic framework UiO-66-(COOH)2 functionalized by non-bonded carboxylic groups. This MOF is an exciting class of free carboxylic functionalized MOFs that combine chemical stability with gas sorption, dye elimination, and conductivity. Specifically, we show that uniformly distributed carboxyl and water stability make it accessible for loading Sr2+ without structural changes. The FTIR spectroscopy, PXRD analysis, XPS, and SEM-EDS studies show excellent stability as well as the strong affinity between -COOH active site and Sr2+. This strong coordination interaction guarantees a high adsorption capacity of 114 mg g−1 within 5 h (pH 5 and 298 K). Combined kinetic and thermodynamic studies show that the surface complexation is strong chemisorption and cost-effective spontaneous process (ΔG = −5.49 kJ mol−1~−2.16 kJ mol−1). The fact that UiO-66-(COOH)2 not only possesses a high adsorption capacity, but also enables selectivity to Sr2+ in the presence of similar radius ions Na+ and K+, prefigures its great potential for the practical treatment of radioactive Sr2+ in polluted water. 相似文献
995.
<正>有机发光材料由于分子结构多样、发光颜色可调、加工简便等优点受到广泛关注。经典有机发光分子往往含有大的π共轭结构,并由此产生充分的电子离域。然而,此类有机发光分子往往含有稠环或芳杂环结构,具有潜在的细胞毒性[1];且在调节发光颜色时往往需要增加分子共轭、改变取代基或引入不同的推拉电子结构,合成步骤较为繁琐。与之相比,不含大型共轭单元而仅含N、O、S、P等杂原子及C=O、C=N、C≡N、C=C等富电子单元的非典型发光化合物结构简单,可通过商购或简单反应获得。且许多非典型发光分子与生物体系密切相关,生物相容性良好,有利于后续应用[2]。 相似文献
996.
Developing an ideal and cheap adsorbent for adsorbing heavy metals from aqueous solution has been urgently need. In this study, a novel, effective and low-cost method was developed to prepare the biochar from lettuce waste with H3PO4 as an acidic activation agent at a low-temperature (circa 200 °C) hydrothermal carbonization process. A batch adsorption experiment demonstrated that the biochar reaches the adsorption equilibrium within 30 min, and the optimal adsorption capacity of Cd(II) is 195.8 mg∙g−1 at solution pH 6.0, which is significantly improved from circa 20.5 mg∙g−1 of the original biochar without activator. The fitting results of the prepared biochar adsorption data conform to the pseudo-second-order kinetic model (PSO) and the Sips isotherm model, and the Cd(II) adsorption is a spontaneous and exothermic process. The hypothetical adsorption mechanism is mainly composed of ion exchange, electrostatic attraction, and surface complexation. This work offers a novel and low-temperature strategy to produce cheap and promising carbon-based adsorbents from organic vegetation wastes for removing heavy metals in aquatic environment efficiently. 相似文献
997.
The most effective methodologies for the construction of polynuclear complexes usually take advantage of preorganized building blocks.Herein,we successfully developed a new versatile heterometallic{BiNb4}moiety,which can be applied for the assembly of less explored organic-inorganic hybrid polyoxoniobates.Through controlled condensation reactions,three{BiNb4}moieties can be assembled into a pair of isomeric Bi3Nb18clusters at different temperatures;whilst four{BiNb4}moieties can be combined into two unique Bi4Nb16and Bi4Nb18tetramers in different solvents.Interestingly,we have used mass spectrometry to probe the above condensation reactions,which clearly confirmed a stepwise bottom-up assembly process by capturing the presence of bismuth subsalicylate precursors,salicylate coordinated intermediates,Nb incorporated{BiNb4}moieties and the final BixNby-oxo clusters,respectively.Moreover,the packing modes of the{BiNb4}units induce different solution behaviors,and the{BiNb4}units in Bi4Nb16can be recombined by post-synthetic recrystallization in acetonitrile to produce a new tetramer Bi4Nb18-R.Therefore,this work provides not only a useful{BiNb4}building unit but also the mechanism for their condensation,both of which will promote the future development of metal-oxo clusters. 相似文献
998.
999.
交叉相位调制对非线性光纤环镜中光脉冲传输的影响 总被引:6,自引:6,他引:0
基于耦合非线性薛定谔方程,采用分步傅里叶方法分析了在单波长信道和WDM(波分复用)4波长信道中XPM(交叉相位调制)对高速NOLM(非线性光纤环镜)光开关中脉冲传输的影响.数值计算表明:XPM造成NOLM中信号脉冲串扰与畸变,并造成NOLM开关性能的下降.WDM系统NOLM光纤环中的同向传播的各波长之间的XPM串扰比相向脉冲之间的XPM效应的影响更大,并且波长越短输出功率越低,中间信道受XPM的影响所导致的脉座现象和走离效应比两侧波长信道严重. 相似文献
1000.
建立了考虑PMD在内的NOLM微波光子开关光波传输方程,给出了基于耦合非线性薛定谔方程的分步傅里叶法,三维庞加莱球理论和琼斯传输矩阵法的数值分析模型.仿真获得在光子开关中微波直接强度调制光载波的传输过程,以及在不同调制带宽下一阶和二阶PMD对光波信号和NOLM功率传输函数的影响.指出PMD造成NOLM开关性能钝化和消光比严重恶化,并引起信号信噪比下降和旁瓣泄漏.当调制带宽大于40GHz时,二阶PMD的影响比一阶PMD更加严重.最后讨论了NOLM中的PMD补偿问题. 相似文献