全文获取类型
收费全文 | 3586篇 |
免费 | 531篇 |
国内免费 | 381篇 |
专业分类
化学 | 2653篇 |
晶体学 | 20篇 |
力学 | 177篇 |
综合类 | 34篇 |
数学 | 306篇 |
物理学 | 1308篇 |
出版年
2024年 | 13篇 |
2023年 | 85篇 |
2022年 | 117篇 |
2021年 | 96篇 |
2020年 | 132篇 |
2019年 | 137篇 |
2018年 | 106篇 |
2017年 | 105篇 |
2016年 | 151篇 |
2015年 | 150篇 |
2014年 | 194篇 |
2013年 | 272篇 |
2012年 | 339篇 |
2011年 | 356篇 |
2010年 | 235篇 |
2009年 | 199篇 |
2008年 | 260篇 |
2007年 | 223篇 |
2006年 | 191篇 |
2005年 | 149篇 |
2004年 | 113篇 |
2003年 | 89篇 |
2002年 | 87篇 |
2001年 | 84篇 |
2000年 | 59篇 |
1999年 | 63篇 |
1998年 | 60篇 |
1997年 | 59篇 |
1996年 | 66篇 |
1995年 | 73篇 |
1994年 | 39篇 |
1993年 | 26篇 |
1992年 | 36篇 |
1991年 | 30篇 |
1990年 | 17篇 |
1989年 | 17篇 |
1988年 | 15篇 |
1987年 | 6篇 |
1986年 | 9篇 |
1985年 | 10篇 |
1984年 | 5篇 |
1983年 | 3篇 |
1982年 | 6篇 |
1981年 | 7篇 |
1980年 | 1篇 |
1979年 | 4篇 |
1974年 | 1篇 |
1940年 | 1篇 |
1902年 | 1篇 |
1898年 | 1篇 |
排序方式: 共有4498条查询结果,搜索用时 15 毫秒
51.
Annals of Global Analysis and Geometry - In this paper, we study a problem of finding compact hypersurfaces of prescribed mean curvature with free boundary in a ball. We transform the problem to an... 相似文献
52.
53.
钼钨铌磷杂多化合物的研究(Ⅰ):杂多酸的合成和表征 总被引:4,自引:0,他引:4
提出了分步酸化一分步加料合成[PNb_2Mo_xW_(10-x)O_(40)]~(5-)(x=0,2,4,6)系列杂多酸的方法,给出了最佳配料比和生成反应的pH值,并进行了红外、紫外、极谱、电位滴定及热稳定性研究。 相似文献
54.
55.
In this work, the surface properties of novel sugar-containing polymers, α-allyl glucoside (AG)/acrylonitrile (AN)copolymers, were studied by contact angle, protein adsorption and cell adhesion measurements. It was found that the contactangle of the copolymer films decreased from 68° to 30° with the increase of AG content in the copolymer. The adsorptionamount of bovine serum albumin (BSA) and the adhesive macrophage onto the film surface also decreased significantly withincreasing α-allyl glucoside content from 0 to 42 wt% in the copolymer. These preliminary results reveal that both thehydrophilicity and the biocompatibility of polyacrylonitrile-based membranes could be improved by copolymerizing acrylonitrile with vinyl carbohydrates. 相似文献
56.
57.
The reaction of Cu(CH(3)CN)(4)ClO(4) with 2-pyridylacrylic acid (2-HPYA) affords an unusual mixed-valence Cu(I)-Cu(II) 3-D framework ([Cu(II)(2-PYA)(2)](3).[Cu(I)(2-PYA)](2).(H2O)(2))n (1) with a novel topology which features Cu(II) dimeric units (or paddle-wheel unit). The almost perpendicular coordinating direction between the N atom of pyridyl and the O atom of carboxylate groups may be responsible for the formation of such a novel network. 相似文献
58.
Xi Li Yi Liu Jun Wu Huigang Liang Songsheng Qu 《Journal of Thermal Analysis and Calorimetry》2002,67(3):589-595
The action of three kinds of the selenomorpholine compounds on a strain ofEscherichia coli was studied by microcalorimetry. Differences in their capacities to affect the metabolism of this bacterium were observed.
The extent and duration of the effect on the metabolism as judged from the rate constant (k) of Escherichia coli (in log phase) varied with the different drugs. The kinetics show that selenomorpholine compounds had an effect on the metabolism
process of Escherichia coli. The k of Escherichia coli in the presence of the drugs increased with the increasing concentrations of the drugs (C) at low concentration; but at high concentration, the rate constant decreased with the increasing concentrations of the drugs.
The experimental results reveal that the sequence of antibiotic activity of selenomorpholines is: N-selenomorpholinemethyl
succinimide and its hydrochloride>N-(α-selenomorpholinebenzyl) succinimide.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
59.
The triplet channel in the photodissociation of ozone in the Hartley band, O3 + hv-->O(3P) + O2(3sigma), is investigated by means of a classical trajectory surface hopping method using ab initio diabatic potential energy surfaces for the B and the R states. Because of the strong recoil in the R state along the breaking O-O bond, O2(3sigma) is produced with a high rotational energy. The nonadiabatic transition probability depends markedly on the coordinate along the crossing seam. As a consequence a unique correlation is found between the internuclear geometry at the crossing and the final vibrational state of O2(3sigma). The calculated distribution of the translational energy is in good accord with the measured distribution. 相似文献
60.
The calculations of clusters modeling the fluorine-doping and oxygen deficiency of YBa2Cu307 have been performed by the method of all-electronab initio Hartree-Fock with self-consistent crystal field. Results show that in CuO planes electric charge significantly increases,
the chemical valence of Cu decreases and the covalent bonding of Cu-O greatly weakens owing to oxygen deficiency, while the
effect of F restores the local electronic structure of YBa2Cu3O7. The reported opinion that F occupied the oxygen vacancy in Cu-O chains seems disputable according to the calculated bonding
characteristics
Project supported by the National Natural Science Foundation of China. 相似文献