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991.
992.
993.
994.
The theory of atomic diffraction from a classical standing wave light field in the presence of spontaneous emission in the Raman-Nath regime was developed by Tanguy et al. [6]. We describe the basis of computationally efficient methods for performing calculations in this regime and show their agreement with recent experimental results of Gould et al. [4]. 相似文献
995.
Ming Tan 《Journal of multivariate analysis》1991,38(2)
The problem of finding classes of estimators which improve upon the usual (e.g., ML, LS) estimator of the parameter matrix in the GMANOVA model under (matrix) quadratic loss is considered. Classes of improved estimators are obtained via combining integration-by-parts methods for normal and Wishart distributions. Also considered is the application of control variates to achieve better efficiency in multipopulation multivariate simulation studies. 相似文献
996.
B. P. Liu X. C. Lv Z. C. Tan Z. H. Zhang Q. Shi L. N. Yang J. Xing L. X. Sun T. Zhang 《Journal of Thermal Analysis and Calorimetry》2007,89(1):283-287
The molar heat capacity, C
p,m, of a complex of holmium chloride coordinated with L-aspartic acid, Ho(Asp)Cl2·6H2O, was measured from 80 to 397 K with an automated adiabatic calorimeter. The thermodynamic functions H
T-H
298.15 and S
T-S
298.15 were derived from 80 to 395 K with temperature interval of 5 K. The thermal stability of the complex was investigated by
differential scanning calorimeter (DSC) and thermogravimetric (TG) technique, and the mechanism of thermal decomposing of
the complex was determined based on the structure and the thermal analysis experiment. 相似文献
997.
Photochemical cycloaddition of cyclopentene with enone esters containing different chiral auxiliaries yielded anti and syn adducts and in good yield and with moderate to high (79%) enantiomeric excesses. 相似文献
998.
对三维空间某个多面体区域的四面体剖分,通过在每个四面体胞腔的棱和顶点设置适当的插值结点.本文给出了(1,1)型C0及C1光滑的非奇异有理样条存在的充分必要条件. 相似文献
999.
1000.
J. S. Tan 《Journal of Polymer Science.Polymer Physics》1974,12(1):175-185
Rotational isomeric-state theory has been applied to investigate chain configurations of a polyester prepared from 4′,5-(1,1,3-trimethyl-3-phenylindan) dicarboxylic acid and 2,2-bis(4′-hydroxyphenyl) propane (POLA polyester). Independent conformations for each repeat monomer unit of the chain have been assumed in the calculations of the unperturbed dimensions. Rotations about the oxygen-phenylene-carbon (O? ?? C) bonds are considered to be free with twofold symmetric potentials. The trans and cis conformations of the carbonyl-phenylene-carbon (O?C? ?? C) and the indan-carbonyl residues are assumed to have equal probability. Two rotational states, trans and cis, are assigned to the ester C? O bonds. Calculation of the reduced unperturbed dimensions (〈r02〉/M)∞ with conformations thus assigned for the bonds in the repeat unit, and comparison with experiment (0.72 ± 0.02 Å2/g) indicate that the conformation in the ester C? O bonds is predominantly trans. An equation for the conformational potential as a function of rotational angle about the ester C? O bond has been formulated using data on potential barriers for low molecular weight compounds. This equation, yielding a potential difference between the cis the trans isomers of 2.5–3.0 kcal/mole, is in good agreement with the prediction made from the calculation of the unperturbed dimensions where a cis/trans ratio of 0.01 for the ester C? O bonds was obtained. 相似文献