CO_2 Reforming of CH_4 over Ni/CeO_2-ZrO_2-Al_2O_3 Prepared by Hydrothermal Synthesis Method

The Ni/CeO2-ZrO2-Al2O3 catalyst with different Al2O3 and NiO contents were prepared by hydrothermal synthesis method. The catalytic performance for CO2 reforming of CH4 reaction, the interaction among components and the relation between Ni content and catalyst surface basicity were investigated. Results show that the interaction between NiO and Al2O3 is stronger than that between NiO and CeO2-ZrO2.The addition of Al2O3 can prevent the formation of large metallic Ni ensembles, increase the dispersion of Ni, and improve catalytic activity, but excess Al2O3 causes the catalyst to deactivate easily. The interaction between NiO and CeO2 results in more facile reduction of surface CeO2. The existence of a small amount of metallic Ni can increase the number of basic sites. As metallic Ni may preferentially reside on the strong basic sites, increasing Ni content can weaken the catalyst basicity.     

Q-正则Loewner空间中的拟对称映射

本文在Q-正则Loewner空间中用环模不等式刻划了拟对称映射.另外,在 Q-维Ahlfors-David正则空间中建立了拟对称映射作用下的Grotzsch-Teichmuller型 模不等式,它是通过伸张系数的积分平均来表示.     

类锂铝复合机制产生X光激光的等离子体状态

本文从速率方程出发,讨论了类锂铝复合等离子体的激发态结构,衰减常数,反转率和小信号增益等表征介质增益特性的物理量以及它们随电子温度,电子密度和光子逃逸几率的变化。找到了进行类锂铝离子通过复合机制产生X光激光设计应创造的等离子体状态目标区域。还讨论了这些物理量随原子序数变化的定标律。     

红外折/衍混合离轴望远系统设计

本文针对空间光学系统轻型特点,设计了一个二元光学折/衍混合红外反射式望远系统。采用了离轴式格里高利(Gregorian)结构形式,消除了望远系统中的中心遮拦问题。用衍射光学元件校正系统象差,使反射面为球面,二元光学表面尺寸比施密特(Schmidt)校正板(位于入瞳处)缩小于3～4倍,光学设计运用OSLO软件,光学系统的通光孔径φ=120mm,焦距f=-1000mm,波长λ=4.3μm,视场2ω=2°×6°(子午×弧矢),分辨率Res=0.05mm,MTF≥0.4(空间频率fre≤10cl/mm).     

变参数波振器中小信号增益公式

利用微扰展开技术推导出变参数波振器的小信号增益两个近似求积表达式并将其计算结果与数值模拟结果进行了比较,二者吻合很好。利用近似解析式对小信号增益进行了初步探讨,得到了电子入射能量可低于初始谐振能,能散度允许范围受波振器设计影响以及降低锥度改变率可提高小信号增益等新结论。     

Synthesis and nuclear magnetic resonance analysis of starch‐g‐poly(1,4‐dioxan‐2‐one) copolymers

A new biodegradable starch graft copolymer, starch‐g‐poly(1,4‐dioxan‐2‐one), was synthesized through the ring‐opening graft polymerization of 1,4‐dioxan‐2‐one onto a starch backbone. The grafting reactions were conducted with various 1,4‐dioxan‐2‐one/starch feed ratios to obtain starch‐g‐poly(1,4‐dioxan‐2‐one) copolymers with various poly(1,4‐dioxan‐2‐one) graft structures. The microstructure of starch‐g‐poly(1,4‐dioxan‐2‐one) was characterized in detail with one‐ and two‐dimensional NMR spectroscopy. The effect of the feed composition on the resulting microstructure of starch‐g‐poly(1,4‐dioxan‐2‐one) was investigated. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 3417–3422, 2004     

Hydroxyapatite coating on porous silicon substrate obtained by precipitation process

Hydroxyapatite Ca₁₀(PO₄)₆(OH)₂ (HAP) is known as a bioactive and biocompatible material, HAP coatings were used to improve the biocompatible of substrate by many researcher, In this work, HAP thin films on porous silicon (PS) substrates have been prepared by aqueous precipitation method with rapid thermal annealing (RTA) processes. The HAP films had been prepared under the annealing temperature ranging from 300 to 1000 °C. By the measurement of X-ray diffraction (XRD), it was found that for the crystallinity optimization, the heat-treatment at 850–950 °C for 1 h would be favorable. Atomic force microscopy (AFM) and scanning electron microscope (SEM) measurements reveal a dense and smooth surface of the HAP film, and tightly adherence of the coating on porous silicon substrate after sintered. Thus, by this method, porous silicon could be increased its bioactivity and so that could be used in the biomedical area.     

三十烷醇在GA_3影响水稻幼苗生长和生理性状中的增效作用

微量三十烷醇（ＴＲＩＡ）与ＧＡ３配合使用，比ＧＡ３单独使用能明显地促进幼苗生长和增加幼苗干物质积累．同时还增强了ＧＡ３对幼叶中叶绿素含量、可溶性蛋白质含量、呼吸速率、细胞膜透性和过氧化物酶活性的影响．ＧＡ３＋ＴＲＩＡ与ＧＡ３处理相比，促进幼叶内源ＧＡ３水平提高，稳定保持内源ＺＴ于一定水平，ＴＲＩＡ在ＧＡ３低浓度时降低ＩＡＡ水平，在高浓度时则提高ＩＡＡ水平．作者认为ＴＲＩＡ可作为ＧＡ３处理时的增效剂．     

端面泵浦掺Yb3+双包层光纤激光器

从双包层光纤激光器的速率方程出发，得到了光纤中泵浦光与激光的功率分布、输出功率与泵浦功率的关系、腔镜反射率及光纤长度对输出功率的影响。研究结果表明：输出激光功率与光纤长度及后腔镜反射率有很强的依赖关系，存在一个输出功率最大的最佳光纤长度。后腔镜反射率越大，输出激光功率越小；当光纤长度较短时，在输出端放置反射镜使泵浦光高反射，可以提高输出功率和效率。通过对端面泵浦掺Yb3+双包层光纤激光器进行理论分析和实验研究，得到输出激光的中心波长为1088.3nm，斜率效率为33.7%，最大输出功率为1.75W。     

飞秒激光脉冲在三能级有机分子介质中传播时的频谱分析

通过采用预估校正的时域有限差分法求解麦克斯韦-布洛赫方程,我们研究了飞秒激光脉冲在三能级有机分子(4,4-二甲氨基二苯乙烯分子)介质中传播时脉冲的频谱演化情况.在单光子共振情况下,即入射脉冲频率等于1、2能级之间的共振频率,对大面积入射脉冲,由于强的二次激发的作用,电场频谱中出现了在ω32附近振荡的频率成分,ω32是2、3能级之间的共振频率,说明对大面积入射脉冲二能级模型已经失效,需要采用多能级模型来描述分子介质.在双光子共振情况下,即入射脉冲频率等于1、3能级之间的共振频率的一半,由于介质中放大的自发辐射和四波混频的作用,部分入射脉冲能量转化为高频和低频电场成分的能量,分子介质表现出了很强的光功率限幅特性.