首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   4393篇
  免费   773篇
  国内免费   707篇
化学   3024篇
晶体学   104篇
力学   224篇
综合类   66篇
数学   715篇
物理学   1740篇
  2024年   13篇
  2023年   77篇
  2022年   115篇
  2021年   150篇
  2020年   203篇
  2019年   177篇
  2018年   174篇
  2017年   179篇
  2016年   219篇
  2015年   203篇
  2014年   221篇
  2013年   323篇
  2012年   416篇
  2011年   412篇
  2010年   325篇
  2009年   327篇
  2008年   342篇
  2007年   291篇
  2006年   253篇
  2005年   210篇
  2004年   141篇
  2003年   145篇
  2002年   187篇
  2001年   152篇
  2000年   106篇
  1999年   85篇
  1998年   50篇
  1997年   42篇
  1996年   47篇
  1995年   30篇
  1994年   37篇
  1993年   31篇
  1992年   25篇
  1991年   27篇
  1990年   26篇
  1989年   9篇
  1988年   13篇
  1987年   9篇
  1986年   13篇
  1985年   8篇
  1984年   10篇
  1983年   9篇
  1982年   9篇
  1980年   2篇
  1977年   5篇
  1975年   2篇
  1974年   3篇
  1973年   5篇
  1972年   4篇
  1971年   4篇
排序方式: 共有5873条查询结果,搜索用时 15 毫秒
151.
152.
We develop here a simple wet chemistry to prepare covalent functionalized graphenes(FGs) through epoxide aminolysis especially under alkaline aqueous condition. Remarkably, a series of typical monoamines, such as industrial Huntsman Jeffamine~ M-2070 and M-2005 polymer with hydrophilic or hydrophobic polyetheramine chains, positively-charged 2-amino-N,N,Ntrimethylpropanaminium,negatively-charged sulfanilic acid, even oligopeptide sequence, can be effectively grafted on the platelets of graphene oxide precursor with covalent functionalization and partially reduced features. This strategy provides the researchers a facile and convenient approach to design and synthesize solution processable, biocompatible and functionalized graphenes for the potent applications in electronic inks, drug carriers and biomedicines. Expansion of the current study is actively ongoing in our laboratory.  相似文献   
153.
154.
155.
156.
157.
158.
CH3NH3PbBr3 perovskite quantum dots (PQDs) are synthesized by using four different linear alkyl phosphonic acids (PAs) in conjunction with (3-aminopropyl)triethoxysilane (APTES) as capping ligands. The resultant PQDs are characterized by means of XRD, TEM, Raman spectroscopy, FTIR spectroscopy, UV/Vis, photoluminescence (PL), time-resolved PL, and X-ray photoelectron spectroscopy (XPS). PA chain length is shown to control the PQD size (ca. 2.9–4.2 nm) and excitonic absorption band positions (λ=488–525 nm), with shorter chain lengths corresponding to smaller sizes and bluer absorptions. All samples show a high PL quantum yield (ca. 46–83 %) and high PL stability; this is indicative of a low density of band gap trap states and effective surface passivation. Stability is higher for smaller PQDs; this is attributed to better passivation due to better solubility and less steric hindrance of the shorter PA ligands. Based on the FTIR, Raman, and XPS results, it is proposed that Pb2+ and CH3NH3+ surface defects are passivated by R−PO32− or R−PO2(OH), whereas Br surface defects are passivated by R−NH3+ moieties. This study establishes the combination of PA and APTES ligands as a highly effective dual passivation system for the synergistic passivation of multiple surface defects of PQDs through primarily ionic bonding.  相似文献   
159.
The rapid development of additive manufacturing techniques, also known as three-dimensional (3D) printing, is driving innovations in polymer chemistry, materials science, and engineering. Among current 3D printing techniques, direct ink writing (DIW) employs viscoelastic materials as inks, which are capable of constructing sophisticated 3D architectures at ambient conditions. In this perspective, polymer designs that meet the rheological requirements for direct ink writing are outlined and successful examples are summarized, which include the development of polymer micelles, co-assembled hydrogels, supramolecularly cross-linked systems, polymer liquids with microcrystalline domains, and hydrogels with dynamic covalent cross-links. Furthermore, advanced polymer designs that reinforce the mechanical properties of these 3D printing materials, as well as the integration of functional moieties to these materials are discussed to inspire new polymer designs for direct ink writing and broadly 3D printing.  相似文献   
160.
Plasma Chemistry and Plasma Processing - Gas tungsten arc welding (GTAW), a widely used industrial process, is one of the most intense artificial sources of optical radiation. This paper presents a...  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号