全文获取类型
收费全文 | 9460篇 |
免费 | 1723篇 |
国内免费 | 1223篇 |
专业分类
化学 | 6435篇 |
晶体学 | 153篇 |
力学 | 422篇 |
综合类 | 135篇 |
数学 | 1116篇 |
物理学 | 4145篇 |
出版年
2024年 | 36篇 |
2023年 | 188篇 |
2022年 | 296篇 |
2021年 | 340篇 |
2020年 | 374篇 |
2019年 | 356篇 |
2018年 | 354篇 |
2017年 | 317篇 |
2016年 | 466篇 |
2015年 | 456篇 |
2014年 | 477篇 |
2013年 | 662篇 |
2012年 | 897篇 |
2011年 | 946篇 |
2010年 | 639篇 |
2009年 | 637篇 |
2008年 | 679篇 |
2007年 | 576篇 |
2006年 | 512篇 |
2005年 | 418篇 |
2004年 | 314篇 |
2003年 | 265篇 |
2002年 | 334篇 |
2001年 | 261篇 |
2000年 | 220篇 |
1999年 | 188篇 |
1998年 | 142篇 |
1997年 | 144篇 |
1996年 | 133篇 |
1995年 | 113篇 |
1994年 | 100篇 |
1993年 | 102篇 |
1992年 | 67篇 |
1991年 | 89篇 |
1990年 | 68篇 |
1989年 | 44篇 |
1988年 | 27篇 |
1987年 | 23篇 |
1986年 | 31篇 |
1985年 | 23篇 |
1984年 | 21篇 |
1983年 | 20篇 |
1982年 | 16篇 |
1981年 | 3篇 |
1977年 | 5篇 |
1975年 | 2篇 |
1974年 | 3篇 |
1973年 | 5篇 |
1972年 | 4篇 |
1971年 | 4篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
11.
The distortion theorem for biholomorphic convex mappings in bounded symmetric domains are considered. Especially the distortion theorem for biholomorphic convex mappings in classical domain of type IV and two exceptional domains are given. 相似文献
12.
采用固源Si分子束外延,在较高的生长温度于Si(100)衬底上制备出Si1-xGex/Si量子阱发光材料。发光样品的质量和特性通过卢瑟福背散射、X射线双晶衍射及光致发光评估。背散射实验中观察到应变超晶格的反常沟道效应;X射线分析表明材料的生长是共度的、无应力释放的,结晶完整性好。低温光致发光主要是外延合金量子阱中带边激子的无声发射和横光学声子参与的激子复合。并讨论了生长温度对量于阱发光的影响。 相似文献
13.
Q. Gong R. N tzel P.J. van Veldhoven T.J. Eijkemans J.H. Wolter 《Journal of Crystal Growth》2005,280(3-4):413-418
We report on the shape transition from InAs quantum dashes to quantum dots (QDs) on lattice-matched GaInAsP on InP(3 1 1)A substrates. InAs quantum dashes develop during chemical-beam epitaxy of 3.2 monolayers InAs, which transform into round InAs QDs by introducing a growth interruption without arsenic flux after InAs deposition. The shape transition is solely attributed to surface properties, i.e., increase of the surface energy and symmetry under arsenic deficient conditions. The round QD shape is maintained during subsequent GaInAsP overgrowth because the reversed shape transition from dot to dash is kinetically hindered by the decreased ad-atom diffusion under arsenic flux. 相似文献
14.
15.
A new constant-pressure molecular dynamics (MD) method is developed to simulate the dynamic behavior and structure transition of finite system under external pressure. In this method, no artificial parameter is introduced and the computation overheads are very small. As an application, a hard-soft transition of single wall carbon nanotube (SWCNT) under external pressure is found, which is in agreement with the experiments.
相似文献16.
The detailed characterization of multifunctional hybrid organosilazane/organosilylamine telechelic oligomers by IR and 1H, 13C and 29Si NMR spectroscopy in one and two dimenions has been undertaken. The specific multifunctional oligomers, comprising NH/NH2 or SiCl functionalities depending on the monomer feed-ratio, were prepared from mono- and di-functionally reacted dichlorodimethylsilane (DDS) and mono-, di-, tri- and tetra-functionally reacted ethylenediamine (EDA). Varying the feed-ratio afforded control of the microstructures of the oligomers and the preparation of oligomers with, in some cases, conterminously located silicon–chlorine (SiCl) groups. The combination of the NMR methods with the IR technique has enabled the detailed microstructural characterization of the oligomers and the identification of the functionalities therein. This approach and the knowledge gained from the DDS/EDA system has been applied to the microstructural characterization of other hybrid organosilazane/silylamine preceramic telechelic oligomers. 相似文献
17.
Analysis of the Coaxial Ridge-Loaded Helical Groove Waveguide 总被引:1,自引:0,他引:1
Yonghai Lan Wenxiang Wang Yubin Gong 《International Journal of Infrared and Millimeter Waves》2002,23(3):425-434
The coaxial ridge-loaded helical groove waveguide is proposed in this paper. As an all-metal slow-wave circuit, it has advantages of good heat dissipation and great size, and thus is suitable for use of millimeter TWT. By means of field theory, the expressions of the dispersion equation and the coupling impedance of the coaxial ridge-loaded helical groove waveguide are obtained. The influence of various circuit dimensions on the dispersion relation and the coupling impedance is investigated by the results of numerical computation. 相似文献
18.
Ke Sha Dongshuang Li Yapeng Li Xiaotian Liu Shuwei Wang Jingqi Guan Jingyuan Wang 《Journal of polymer science. Part A, Polymer chemistry》2007,45(22):5037-5049
Amphiphilic diblock copolymer polycaprolactone‐block‐poly(glycidyl methacrylate) (PCL‐b‐PGMA) was synthesized via enzymatic ring‐opening polymerization (eROP) and atom transfer radical polymerization (ATRP). Methanol first initiated eROP of ?‐caprolactone (?‐CL) in the presence of biocatalyst Novozyme‐435 under anhydrous conditions. The resulting monohydroxyl‐terminated polycaprolactone (PCL–OH) was subsequently converted to a bromine‐ended macroinitiator (PCL–Br) for ATRP by esterification with α‐bromopropionyl bromide. PCL‐b‐PGMA diblock copolymers were synthesized in a subsequent ATRP of glycidyl methacrylate (GMA). A kinetic analysis of ATRP indicated a living/controlled radical process. The macromolecular structures were characterized for PCL–OH, PCL–Br, and the block copolymers by means of nuclear magnetic resonance, gel permeation chromatography, and infrared spectroscopy. Differential scanning calorimetry and wide‐angle X‐ray diffraction analyses indicated that the copolymer composition (?‐CL/GMA) had a great influence on the thermal properties. The well‐defined, amphiphilic diblock copolymer PCL‐b‐PGMA self‐assembled into nanoscale micelles in aqueous solutions, as investigated by dynamic light scattering and transmission electron microscopy. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 5037–5049, 2007 相似文献
19.
Meihua Lu H. Gong T. Song Jian-Ping Wang Hong-Wei Zhang T.J. Zhou 《Journal of magnetism and magnetic materials》2006
We present a simple way to synthesize FePt and ZnO (wide-band-gap semiconductor) nanoparticle composites. The FePt nanoparticles were fabricated using the method reported by Sun et al. By controlling the heating rate, 3 nm FePt nanoparticles were synthesized. Well-dispersed FePt and ZnO nanoparticle composites were prepared by further adding zinc acetate and oleyl amine into the 3 nm FePt nanoparticle dispersion. By controlling the molar ratio of the FePt and zinc acetate, FePt and ZnO nanoparticle composites with different FePt particle fractions were obtained. The intensity of photo luminescence spectra of the nanoparticle composites increases very much with decreasing FePt particle fraction, whereas the peak position shifts a little. After annealing at 550 °C for half an hour, the nanoparticle composites become magnetically hard or semi-hard with coercivity much dependent on the FePt particle volume fraction. The coercivity of the composites increases with annealing temperature. The composites hold the promise of applications in new generation recording and/or optical devices. 相似文献
20.
Modulation of Spin Distribution and Spin Transport by a Magnetic Field in a Quasi-One-Dimensional System with Spin--Orbit Coupling 下载免费PDF全文
The distributions of spin and currents modulated by magnetic field in a transverse parabolic confined two-dimensional electronic system with a Rashba spin--orbit coupling have been studied numerically. It is shown that the spin accumulation and the spin related current are generated by magnetic field if the spin--orbit coupling is presented. The distributions of charge and spin currents are antisymmetrical along the cross-section of confined system. A transversely applied electric field does not influence the characteristic behaviour of charge- and spin-dependent properties. 相似文献