Development of isomerization and cycloisomerization with use of a ruthenium hydride with N-heterocyclic carbene and its application to the synthesis of heterocycles

A pure ruthenium hydride complex with N-heterocyclic carbene (NHC) ligand was efficiently generated from the reaction of a second-generation Grubbs ruthenium catalyst with vinyloxytrimethylsilane and unambiguously characterized. This ruthenium hydride complex showed high catalytic activity for the selective isomerization of terminal olefin and for the cycloisomerization of 1,6-dienes. These reactions of N-allyl-o-vinylaniline lead to novel synthetic methods for heterocycles such as indoles and 3-methylene-2,3-dihydroindoles, which are useful synthons for bioactive natural products. These procedures address an important issue in diversity-oriented synthesis.     

DEA congestion and returns to scale under an occurrence of multiple optimal projections

Economic implications of congestion have been recently discussed in many DEA (data envelopment analysis) studies. In addition, several previous research efforts have explored a theoretical linkage between returns to scale (RTS) and the concept of congestion, because the two economic concepts are closely connected to each other. Tone and Sahoo [Tone, K., Sahoo, B.K., 2004. Degree of scale economies and congestion: A unified DEA approach. European Journal of Operational Research 158, 755–772] have published the theoretical linkage in this journal. All of the previous studies, including their research (2004), assume a unique optimal solution in the investigation on DEA-based congestion. When multiple solutions occur in DEA-based congestion measurement, the economic implications of congestion obtained from the previous research are all problematic from both theoretical and practical perspectives. To deal with the issue, this study explores how to deal with the occurrence of multiple solutions in the DEA-based congestion measurement. This study proposes a new approach for the congestion measurement and theoretically compares the proposed approach with Tone and Sahoo (2004).     

An occurrence of multiple projections in DEA-based measurement of technical efficiency: Theoretical comparison among DEA models from desirable properties

This study discusses nine desirable properties that a measure of technical efficiency (TE) needs to satisfy from the perspective of production economics and optimization. Seven data envelopment analysis (DEA) models are theoretically compared from a viewpoint of nine TE criteria. All the seven DEA models suffer from a problem of multiple projections even though a unique projection for efficiency comparison is one of the nine desirable properties. Furthermore, all the DEA models violate the property on aggregation of inputs and outputs. Thus, the seven DEA models do not satisfy all desirable TE properties. In addition, the comparison provides us with the following guidelines: (a) The additive model violates all desirable TE properties. (b) Russell measure and SBM (=ERGM) perform as well as RAM as a non-radial measure. If we are interested in strict monotonicity, the two models outperform the other DEA models including RAM. In contrast, if we are interested in translation invariance, RAM is better than Russell measure and SBM (=ERGM). (c) The radial measures (CCR and BCC) have the property of linear homogeneity. (d) The CCR model is useful for measuring a frontier shift among different periods. (e) If a data set contains a negative value, RAM becomes a DEA model to handle the negative value because it has the property of translation invariance. After examining the desirable TE properties, this study proposes a new approach to deal with an occurrence of multiple projections. The proposed approach includes a test to examine an occurrence of multiple projections, a mathematical expression of a projection set, and a selection process of a unique reference set as the largest one covering all the possible reference sets.     

A Mesoporous Superlattice Consisting of Alternately Stacking Interstitial Nanospace within Binary Silica Colloidal Crystals

A novel class of nonclassical structures of mesoporous silica, namely a binary nanoparticle mesoporous superlattice (BNMS), is obtained by the assembly of silica nanospheres of different sizes into a binary colloidal crystal. The colloidal crystal has a CrB‐type structure and consists of alternate stacks of unary fcc and binary AlB₂‐type structures along the b axis and has four types of interstitial mesopores. The BNMS can be deposited on a substrate by dip coating to form an oriented thin film in which the direction of the superstructure (b axis) is perpendicular to the substrate.     

Tunnel spin injection into graphene using Al2O3 barrier grown by atomic layer deposition on functionalized graphene surface

We demonstrate electrical tunnel spin injection from a ferromagnet to graphene through a high-quality Al₂O₃ grown by atomic layer deposition (ALD). The graphene surface is functionalized with a self-assembled monolayer of 3,4,9,10-perylene tetracarboxylic acid (PTCA) to promote adhesion and growth of Al₂O₃ with a smooth surface. Using this composite tunnel barrier of ALD-Al₂O₃ and PTCA, a spin injection signal of ∼30 Ω has been observed from non-local magnetoresistance measurements at 45 K, revealing potentially high performance of ALD-Al₂O₃/PTCA tunnel barrier for spin injection into graphene.     

QUantitative Cross-Polarization at magic-angle spinning frequency of about 20 kHz

We study the QUantitative Cross-Polarization (QU-CP) method proposed by Hou et al. (Chem. Phys. Lett. 421 (2006) 356) under the moderate MAS speed of 23 kHz, re-examining its two building blocks, namely, the CP polarization transfer from (1)H to (13)C, and the thermal equalization of the (13)C magnetizations. We show that the nuclear-integrated cross-polarization (NI-CP) scheme is conveniently used for (1)H-(13)C polarization transfer, because of its simplicity, robustness to rf-mismatch, and compatibility with fast sample spinning. In the mixing part, in addition to dipolar-assisted rotational-resonance (DARR) recoupling, we examine the Phase-Alternated Recoupling Irradiation Schemes (PARIS and PARIS(xy)), and Second-order Hamiltonian among Analogous Nuclei Generated by Hetero-nuclear Assistance Irradiation (SHANGHAI) sequences, and show that SHANGHAI gives the best performances in equalizing the (13)C magnetizations.     

Gait-related Self-efficacy is Low in Older Adults with Knee Osteoarthritis: A Preliminary Study

Objective: To investigate the differences in self-efficacy (SE) for walking tasks between older patients with knee osteoarthritis (OA) and older adults without knee OA. Methods: A cross-sectional design was employed. Older patients with radiographic knee OA and community-dwelling older adults without knee OA as controls were enrolled in the study. SE for the walking task was assessed using the modified gait efficacy scale (mGES). A Wilcoxon rank-sum test was used to compare the mGES between the groups of participants. A Tobit regression model was used to estimate the difference in mGES. The presence of radiographic knee OA was used as an independent variable. Sex (women), age, and body mass index were used as potential confounding variables in the model. Results: After exclusion, 78 participants (n=40 with knee OA, n=38 controls) were included. The mGES was lower in patients with knee OA than in controls. In the Tobit regression model adjusted for confounding factors, mGES in patients with knee OA was estimated to be 26.8 (95% confidence interval [CI]: 15.8-37.8) points lower than in controls. Conclusion: This study demonstrated that mGES was lower in older patients with knee OA than in older adults without knee OA.     

Photochemical hole burning in macromolecular complexes

Photochemical hole burning (PHB) of free-base porphyrins in host polymers as a site-selective spectroscopy reveals the existence of vibronic structure in a porphyrin Q-band peak and low-energy excitation modes of host polymers. A new mechanism of photon-gated PHB by two-color sensitization of photoreactive polymers with a zinc porphyrin is also presented.     

Deuterium substitution and fluorescence studies on polymer hydrogels and complexes

Deuterium isotope effects on swelling kinetics and volume phase transition in typical polymer hydrogels (poly(N-isopropylacrylamide) and polyacrylamide gels) are discussed. Deuterium substitutions affect on the swelling kinetics and volume phase transition of the polymer hydrogels. The slower swelling kinetics of hydrogels in D₂O than in H₂O arises mainly from the high viscosity of the medium. The deuterium isotope effect on the swelling-shrinking curve of hydrogels would come from the different polymer-solvent interaction. The microenvironments of hydrogels studied by solvatochromic fluorescence probe are compared with the bulk state. The zipper-type hydrogen-bonding inter-polymer complexes (poly(acrylic acid)-polyacrylamide and poly(acrylic acid)-poly(N-acryloylglycineamide)) are also investigated and show the huge isotope effect on the phase separation temperature.     

Measurement of image sensor tilt based on amplitude and phase of image

Optical Review - In this study, we present a new method for measuring the tilt of an image sensor to the lens. The assembly accuracy of the lens and image sensor units has a significant influence...