Highly enantioselective fluorescent recognition of mandelic acid derivatives by chiral salen macrocycles

Calixarene-like chiral salen macrocycles can be used for the enantioselective fluorescent recognition of mandelic acid derivatives. It was observed that one enantiomer of mandelic acid causes a 28-fold increase in the fluorescence intensity of a chiral salen macrocycle, whereas the other enantiomer causes only a 14-fold fluorescence enhancement. This highly enantioselective fluorescent response makes chiral salen macrocycles useful for the enantioselective fluorescent recognition of some mandelic acid derivatives.     

Arsole‐Containing π‐Conjugated Polymer by the Post‐Element‐Transformation Technique

A synthetic method to obtain an arsole‐containing π‐conjugated polymer by the post‐transformation of the organotitanium polymer titanacyclopentadiene‐2,5‐diyl unit with an arsenic‐containing building block is described. The UV/Vis absorption maximum and onset of the polymer were observed at 517 nm and 612 nm, respectively. The polymer exhibits orange photoluminescence with an emission maximum (E_max) of 600 nm and the quantum yield (Φ) of 0.05. The polymer proved to exhibit a quasi‐reversible redox behavior in its cyclic voltammetric (CV) analysis. The energy levels of the highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) were estimated to be ?5.43 and ?3.24 eV, respectively, from the onsets for oxidation and reduction signals in the CV analysis. Further chemical modification of the arsole unit in the π‐conjugated polymer by complexation of gold(I) chloride occurred smoothly resulting in the bathochromic shift of the UV/Vis absorption and lowering of the LUMO energy level.     

Numerical simulation of expansion/compression effect on shock induced turbulent flow

The interaction of homogeneous and isotropic turbulence with a shock wave is observed by solving the Reynolds-averaged Navier–Stokes equations with the k–? turbulence model. All turbulent fluctuations are measured at the period of expansion in the turbulent field and during compression by the reflected shock on turbulent field, and it is observed that the longitudinal turbulent velocity fluctuation is enhanced more at the period of expansion due to incident shock wave movement far from the turbulent field. The amplification of the turbulent kinetic energy (TKE) level in the shock/turbulence interaction depends on the shock wave strength and the longitudinal velocity difference across the shock wave. On decreasing the longitudinal velocity difference across the shock, the turbulent kinetic energy (TKE) level is less amplified. The TKE level is amplified by the factor of 1.5–1.8 in the shock/turbulence interaction where the dissipation rate of TKE decreases in all cases of shock/turbulence interaction. After the shock/turbulence interaction, the turbulent dissipative-length scale is amplified slightly and the amplification of the length scales decreases when increasing the shock strength. To cite this article: M.A. Jinnah, K. Takayama, C. R. Mecanique 333 (2005).     

Stereochemical assignments of rubiaquinones A–C,naphthoquinone derivatives from Rubia yunnanensis

Three new naphthoquinone derivatives, rubiaquinones A–C (1–3), were isolated from the roots of Rubia yunnanensis. Rubiaquinone A (1) was a racemic naphthoquinone dimer consisting of a 1,4-dihydroxynaphthalene and a 4-hydroxy-1,2-naphthoquinone moieties with a 2-oxo-propyl group. Rubiaquinones B (2) and C (3) were structurally unique trimeric naphthoquinones with a racemic nature possessing one chiral axis and one chiral carbon in common. The planar structures of 1–3 were assigned by detailed spectroscopic analyses, and enantiomers of 1–3 were obtained by optical resolutions. The absolute configurations of (+)-1 and (?)-1 were elucidated by interpretation of the ECD spectra with the aid of TDDFT ECD calculation, while those of enantiomers obtained from 2 and 3 were assigned by analyses of the composite ECD spectra generated by summing appropriate ECD spectra of enantiomers. Rubiaquinone A (1) exhibited antimicrobial activity against Bacillus subtilis.     

Editorial

On behalf of the board of editors of the journal Shock Waves, I am pleased to give a brief overview of recent shock wave research activities. Shock waves are comprehensive representations of phenomena that appear in non-linear wave dynamics. Historically, shock wave phenomena started to be intensively investigated with the advent of high-speed gas-dynamics and these investigations are nowadays supported by the development of both super-computation and advanced experimental technology. Meanwhile, shock wave research has been expanding its scope to various interdisciplinary applications. A particular case is shock wave research in condensed matter which has a history as long as that of corresponding research in the field of gas-dynamics. However, although there are many dynamic similarities between shock wave motion in gases and condensed matter, the difference with respect to physical properties of both media was so dominating that for a long time research activities in these two fields have been regrettably rather isolated with only little communication between both scientific communities. Realizing that many methodologies are increasingly overlapping, it is now a good time for all of us - in the spirit of the advancement of science and technology - to try to look at shock wave phenomena in various media in order to understand their common features. The sheer variety of multi-faceted applications in shock wave research are reflected by an impressive number of international meetings such as the International Symposium on Shock Waves, the International Colloquium on the Dynamics of Explosions and Reactive Systems and the Conference on Shock Compression of Condensed Matter. In addition to these major international activities, many countries regularly organize national shock wave symposia. As a result of such activities the Asia-Pacific Shock Wave Research Society was established in 2003, whose wide membership includes researchers from the Asia-Pacific region and beyond. On the occasion of assuming the position as new Editor-in-Chief of the journal Shock Waves, I would like to thank my predecessor, Prof. Hans Grönig, for the many years of effort devoted to this task. I will continue to promote this journal as a major publishing platform that supports all international and interdisciplinary shock wave research activities and provides readers with an invaluable source of information.     

Corrosion-resistant amorphous FeC alloys containing chromium and/or molybdenum

An attempt was made to improve corrosion resistance of amorphous iron-base alloys, which contain only carbon as a metalloid element, by the addition of chromium and/or molybdenum. The addition of both metallic elements is effective in decreasing the corrosion rate. Especially, the addition of certain amounts of chromium leads to spontaneous passivation even in 1 N HCl. The corrosion resistance of amorphous FeCrC alloys is intermediate between those of amorphous FeCrPC and FeCrB alloys. The all-amorphous alloys examined are characterized by immunity to pitting corrosion, even by anodic polarization in 1 N HCl.     

Relationship between Hemolytic Toxicity and Signal Intensity of Various Organotin Compounds by a Spin-labeling Technique

Various organotin compounds caused strong hemolysis of erythrocytes. To investigate the mechanism of hemolysis, spin-labeling techniques with electron spin resonance (ESR) spectroscopy were used and the relationship between hemolytic toxicity and signal intensity was investigated. Two kinds of spin-labeled stearic acid in which the para- magnetic center was located at different sites on the alkyl chain (5- and 12-doxyl-stearic acids; 5- and 12-NS) were used. It became clear that the decrease of ESR signal intensity was related to the hemolytic toxicity of the organotin compounds. © 1997 by John Wiley & Sons, Ltd.     

Formation of dimer, trimer, and tetramer of C60 and C70 by γ-ray, charged-particle irradiation, and their HPLC separation

C₆₀ and C₇₀ fullerenes were irradiated by high-energy γ-rays and charged particles. Coalesced products of C₆₀ and C₇₀ have been isolated and detected in the liquid phase by a radiochromatographic technique. It was found that not only ¹¹C radioactive fullerene dimer, trimer, and possibly tetramer were produced by a recoil implantation process following nuclear reaction, but also such non-radioactive coalesced products were produced by the recombination process after ionization by γ-rays or charged particles.     

Direct synthesis of radioactive carbon labeled fullerences using nuclear reactions

The¹¹C and¹⁴C labeled fullerenes were produced by charged-particle and neutron irradiation, of C₆₀, C₇₀ and their mixture. It was found that a carbon atom of fullerence can be easily exchanged with a radioactive carbon atom produced by a nuclear reaction. The HPLC method was effective for identification and purification of various labeled fullerene families as chemically stable compounds. The radiochemically interesting aspect of the results is not only the production of¹¹C and¹⁴C labeled fullerenes but also the formation of radioactive higher fullerenes which can be simultaneously produced with high yield and in carrier-free form.     

Examination of Dislocation Mechanism on Grain Boundary Sliding in High Angle Grain Boundaries by Stress Change Test

In order to understand the factors dominating grain boundary sliding, stress change tests and stress reversal tests were conducted on aluminum bicrystal specimens with high angle grain boundaries. It is found that small change in stress results in the remarkable change in the rate of grain boundary sliding. Stress reversal tests showed that grain boundary slide hardening does not work for the sliding to the direction opposite to that before the stress reversal. Mean internal stresses for the dislocations contributing to grain boundary sliding are experimentally measured by a method consisting of stress change and annealing. It is found that the velocity of dislocations in the grain boundary is in proportion to the mean effective stress.