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101.
102.
Kazutoshi Iwamoto Yukio Ohnuki Kiyoshi Sawada Manabu Senō 《Molecular Crystals and Liquid Crystals》2013,570(1-2):95-103
Transition properties of some compounds of the type, n-C n H2n+1N+(CH3)3X-, with n = 10, 12, 14, 18, 22, and X = Cl, Br, and I, were investigated. All these compounds show a solid-solid phase transition with a large enthalpy change in the range of temperature 350 ~ 400K. The transition behaviors were investigated by the aid of DSC, TG, X-ray, and optical microscope. The solid-solid phase transition is regarded to be caused by melting of the layer of hydrocarbon chains of the compounds, while the rigid ionic layer retains the regular arrangement. Some relationships between the physical properties and the structure of the compounds are discussed. 相似文献
103.
Takehiro Yoshida Yuichi Oshima Takeshi Eri Ken Ikeda Shunsuke Yamamoto Kazutoshi Watanabe Masatomo Shibata Tomoyoshi Mishima 《Journal of Crystal Growth》2008,310(1):5-7
By using the hydride vapor phase epitaxy and a void-assisted separation method, freestanding 3-in GaN substrates were successfully fabricated for the first time, and the process showed an excellent reproducibility. A thick GaN layer 3.2 in in diameter was easily separated from the base substrate. No cracks were generated during the separation process. The dislocation density was of the order of 106 cm–2. The carrier density was approximately 1×1018 cm–3 and the mobility was 3.4×102 cm2 V–1 s–1. The concentrations of impurities, estimated by secondary-ion mass spectrometry, were below the limit of detection, except for Si. The Si concentration was approximately 1×1018 cm–3, which is in good agreement with the carrier density. 相似文献
104.
Here, a simple new method is proposed to evaluate water for the presence of pesticides. Specifically, pesticides for golf link maintenance were used as the targets for this investigation. Water samples containing the pesticides were mixed with particulate adsorbent, after which the pesticides were extracted from the adsorbents using supercritical fluid carbon dioxide and then analyzed by gas chromatography-mass spectrometry. The recoveries of pesticides were examined with several types of adsorbents and found to be related to their octanol/water partition coefficients (Kow) for most of the adsorbents. Good recoveries were obtained when the water samples were mixed with octadecylsilane (ODS) and stylene-divinylbenzene copolymer (XAD) resins for 15 and 30 min, respectively. In the supercritical fluid extraction, extraction pressure affected the efficiency of extraction from XAD while a little effect on extraction from ODS, probably due to the internal structure of the adsorbents. The limit of detection ranged from 0.002 to 2.3 μg L−1 and the method is suitable for the measurement of golf link pesticides in μg L−1 order to 100 μg L−1. The procedure of the proposed method was simpler than the conventional solid-phase extraction method. Finally, the method presented here was used to identify pesticides present in actual wastewater from golf links. 相似文献
105.
de Meijere A Khlebnikov AF Kozhushkov SI Yufit DS Chetina OV Howard JA Kurahashi T Miyazawa K Frank D Schreiner PR Rinderspacher BC Fujisawa M Yamamoto C Okamoto Y 《Chemistry (Weinheim an der Bergstrasse, Germany)》2006,12(22):5697-5721
(P)-(+)-Hexaspiro[2.0.0.0. 0.0.2.1.1.1.1.1]pentadecane [(P)-17] as well as (M)-(-)- and (P)-(+)-octaspiro[2.0.0.0.0.0.0.0.2.1.1.1.1.1.1.1]nonadecanes [(M)- and (P)-25]-enantiomerically pure unbranched [7]- and [9]triangulanes-have been prepared starting from racemic THP-protected (methylenecyclopropyl)methanol 6. The relative configurations of all important intermediates as well as the absolute configurations of the key intermediates were established by X-ray crystal structure analyses. This new convergent approach to enantiomerically pure linear [n]triangulanes for n=7, 9 was also tested in two variants towards [15]triangulane. Some of the most prominent and unexpected features of the newly prepared compounds are the remarkable modes of self-assembly of the diols (P)-14, (E)-(3S,3'S,4S,4'S,5R,5'R)-21, (P)-(+)-22, and (E)-31 in the solid state through frameworks of intermolecular hydrogen bonds leading to, depending on the respective structure, nanotube- [(P)-14, (P)-(+)-22, and (E)-31], honeycomb-like structures [(E)-(3S,3'S,4S,4'S,5R,5'R)-21] or a supramolecular double helix [(P)-(+)- and (M)-(-)-22]. Liquid crystalline properties of the esters and ethers of the diols (P)-14, (P)-, and (M)-22 have also been tested. Although all of these [n]triangulanes have no chromophore which would lead to significant absorptions above 200 nm, they exhibit surprisingly high specific rotations even at 589 nm with [alpha](20)(D)=+672.9 (c=0.814 in CHCl(3)) for (P)-(+)-17, +909.9 (c=0.96 in CHCl(3)) for (P)-(+)-25, -890.5 (c=1.01 in CHCl(3)) for (M)-(-)-25, and -1302.5 (c=0.36 in CHCl(3)) for (M)-(-)-39, and the specific rotations increase drastically on going to shorter wavelengths. This outstanding rotatory power is in line with their rather rigid helical arrangement of sigma bonds, and accordingly these helically shaped unbranched [n]triangulanes may be termed "sigma-[n]helicenes", as they represent the sigma-bond analogues of the aromatic pi-[n]helicenes. Density functional theory (DFT) computations at the B3 LYP/6-31+G(d,p) level of theory for the geometry optimization and time-dependent DFT for determining optical rotations with a triplet-zeta basis set (B3 LYP/TZVP) reproduce the optical rotatory dispersions (ORD) very well for the lower members (n=4, 5) of the sigma-[n]helicenes. For the higher ones (n=7, 9, 15) the computed specific rotations turn out increasingly larger than the experimental values. The remarkable increase of the specific rotation with an increasing number of three-membered rings is proportional neither to the molecular weight nor to the number of cyclopropane rings in these sigma-[n]helicenes. 相似文献
106.
Keio Toi Kazutoshi Takeuchi Taneki Tokuda 《Journal of Polymer Science.Polymer Physics》1980,18(2):189-198
Temperature dependences of diffusion and permeation coefficients of hydrogen and deuterium in glassy and rubbery polymer films have been measured. The size of the free volume element in rubbery polymers has been calculated according to the theory of Frisch and Rogers for the quantum isotope effect, but the free volume is too large for precise calculation below the glass-transition temperature. The cooperative movement of segments is also discussed using the ratio of preexponential factors for diffusion mechanisms above and below the glass-transition temperature. 相似文献
107.
Theoretical analysis of threshold gain and absorption efficiency is presented for a vertical-cavity surface-emitting organic
laser by using transfer matrix method. Pyrromethene 567 dye doped in a polymer film is examined for verification of the active
material with an InGaN cyan LED as a pump source. By alternately stacking high- and low-refractive-index active polymer films,
modeling results indicate that the threshold gain can be reduced and the absorption efficiency at the pump wavelength can
be improved compared with those of a vertical cavity with a dielectric mirror stack. The absorption efficiency of the distributed-feedback
resonator is not practically degraded even if the pump wavelength is located near the stopband. 相似文献
108.
Dvinskikh SV Yamamoto K Dürr UH Ramamoorthy A 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2007,184(2):228-235
Magnetically aligned bicelles are becoming attractive model membranes to investigate the structure, dynamics, geometry, and interaction of membrane-associated peptides and proteins using solution- and solid-state NMR experiments. Recent studies have shown that bicelles are more suitable than mechanically aligned bilayers for multidimensional solid-state NMR experiments. In this work, we describe experimental aspects of the natural abundance (13)C and (14)N NMR spectroscopy of DMPC/DHPC bicelles. In particular, approaches to enhance the sensitivity and resolution and to quantify radio-frequency heating effects are presented. Sensitivity of (13)C detection using single pulse excitation, conventional cross-polarization (CP), ramp-CP, and NOE techniques are compared. Our results suggest that the proton decoupling efficiency of the FLOPSY pulse sequence is better than that of continuous wave decoupling, TPPM, SPINAL, and WALTZ sequences. A simple method of monitoring the water proton chemical shift is demonstrated for the measurement of sample temperature and calibration of the radio-frequency-induced heating in the sample. The possibility of using (14)N experiments on bicelles is also discussed. 相似文献
109.
Matsubara T Iijima K Nakamura M Taki T Okahata Y Sato T 《Langmuir : the ACS journal of surfaces and colloids》2007,23(2):708-714
The ganglioside Galbeta1-3GalNAcbeta1-4(Neu5Acalpha2-3)Galbeta1-4Glcbeta1-1'Cer (GM1) is an important receptor. We have previously identified GM1-binding peptides based on affinity selection from a random peptide library. In the present study, we determined the amino acids essential for binding GM1 and investigated the specific interaction with GM1 in the lipid membrane. Arginines and aromatic amino acids in the consensus sequence (W/F)RxL(xP/Px)xFxx(Rx/xR)xP contributed to the ability of the peptides to bind GM1. The peptide p3, VWRLLAPPFSNRLLP, having the consensus sequence, showed high affinity for GM1 with a dissociation constant of 1.2 microM. Furthermore, the density-dependent binding of p3 was investigated using mixed monolayers of GM1 and Glcbeta1-1'Cer (GlcCer). p3 binds preferentially to high-density GM1, and its interaction with GM1 was found to be cooperative based on a Hill plot. These results indicated that a lateral assembly of GM1 molecules was required for the recognition of carbohydrates by p3. The GM1-binding peptide played a role as a unique anti-GM1 probe differing from the cholera toxin B subunit or antibodies. 相似文献
110.