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11.
Shiina I Kawakita Y Ibuka R Yokoyama K Yamai YS 《Chemical communications (Cambridge, England)》2005,(32):4062-4064
An efficient method for the synthesis of (+)-buergerinin F is established via the enantioselective aldol reaction of a tetra-substituted ketene silyl acetal with crotonaldehyde, followed by intramolecular Wacker-type ketalization. 相似文献
12.
The heat capacity of [Fe(2-pic)3]Cl2·C2H5OH Crystal (2-pic: 2-picolylamine) has been measured with an adiabatic calorimeter between 13 and 315 K. Two phase transitions centered at 114.04 and 122.21 K were observed. This finding accords with recent prediction of possible existence of two-step spin-conversion (H. Köppen et al., Chem. Phys. Lett., 91 (1982) 348). The total transition enthalpy and entropy amounted to ΔH = 6.14 kJ mol?1 and ΔS = 50.59 J K?1 mol?1. The transition entropy consists of the magnetic contribution (13.38 J K?1 mol?1), the orientational order-disorder phenomenon of the solvate ethanol molecule (8.97) and the change in the phonon system, in particular the change in stretching and deformation vibrations of the metal-ligand (28.24). 相似文献
13.
Amidation of exo/endo mixture of β-nitro bicyclic acids by dehydration with DCC, gives only the corresponding exo-amides. 相似文献
14.
Infrared absorption intensities of fundamental bands of propyl halides n-C3 H7 Cl, n-C3H7 Br and n-C3H7I were measured in the pure liquid state. In order to obtain L matrix data necessary for the intensity computation, normal frequencies of the rotational isomers were calculated, and LSFF force constants were determined by the least squares method so as to attain the best fit between the observed and calculated frequencies. By applying the absolute intensity method, energy differences between the rotational isomers were evaluated, which are in quite good agreement with values obtained by the temperature variation method. 相似文献
15.
16.
Kazutoshi Maegawa 《Proceedings of the American Mathematical Society》2008,136(8):2875-2879
For a dominant algebraically stable rational self-map of the complex projective plane of degree at least 2, we will consider three different definitions of the Fatou set and show the equivalence of them (Ascoli-Arzelà type theorem). As a corollary, it follows that all Fatou components are Stein. This is an improvement of an early result by Fornæss and Sibony.
17.
有机过氧化物安定性的差示扫描量热测定 总被引:1,自引:0,他引:1
1 引言有机过氧化物是一种自反应性物质.这类物质在制造、使用、贮存过程中或由于自分解发热、热积累导致燃烧、爆炸,或由于冲击、摩擦、电火花、明火等外部作用导致燃烧爆炸而造成人员伤亡.差示扫描量热法(DSC)、压力容器试验法(PVT)是评价这类物质安全性的基本方法.本文利用DSC法对7种有机过氧化物进行了加热分解试验研究,探讨其热安定性、发生热爆炸的难易程度及剧烈程度. 相似文献
18.
Kazutoshi Koike 《代数通讯》2013,41(9):4303-4319
In this note, we use a universal algebraic argument to show that modules with 0-limits need not be equationally compact, thus providing a counter-example to an open problem of Jensen and Lenzing. 相似文献
19.
Takashi Yoshida Rong Lu Shuqin Han Kazuyuki Hattori Takahiro Katsuta Kei‐Ichi Takeda Kazutoshi Sugimoto Masamitsu Funaoka 《Journal of polymer science. Part A, Polymer chemistry》2009,47(3):824-832
For the synthesis of a new biologically functional polymer from a natural resource by an environment‐friendly method, the laccase‐catalyzed polymerization of a lignin‐based macromonomer, lignocatechol, was carried out for the first time in ethanol–phosphate buffer solvent system to give crosslinked polymers in good yields. Lignocatechol was prepared by the phase separation system of lignin and catechol in aqueous sulfuric acid. The copolymerization was also performed with urushiol to afford the corresponding copolymers in high yields. The polymerization mechanism was estimated by the IR and pyrolysis GC‐MS measurements, suggesting that the polymerization proceeded mainly at the catechol ring through a quinone radical intermediate. The thermal properties were measured by the DSC, TG, and TMA analyses, indicating that the polymers had high thermal stabilities because of the crosslinked structures. In addition, it was found that the resulting polymers had the affinity of bovine serum albumin (BSA) and glucoamylase. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 824–832, 2009 相似文献
20.
Kazutoshi Ando 《Discrete Mathematics》2006,306(24):3181-3188
A pair (X,τ) of a finite set X and a closure operator τ:2X→2X is called a closure space. The class of closure spaces includes matroids as well as antimatroids. Associated with a closure space (X,τ), the extreme point operator ex:2X→2X is defined as ex(A)={p|p∈A,p∉τ(A-{p})}. We give characterizations of extreme point operators of closure spaces, matroids and antimatroids, respectively. 相似文献