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141.
142.
Kazushi Yoshitomi 《Indagationes Mathematicae》2005,16(2):289-299
Let q ∈ {2, 3} and let 0 = s0 < s1 < … < sq = T be integers. For m, n ∈ Z, we put ¯m,n = {j ∈ Z| m? j ? n}. We set lj = sj − sj−1 for j ∈ 1, q. Given (p1,, pq) ∈ Rq, let b: Z → R be a periodic function of period T such that b(·) = pj on sj−1 + 1, sj for each j ∈ 1, q. We study the spectral gaps of the Jacobi operator (Ju)(n) = u(n + 1) + u(n − 1) + b(n)u(n) acting on l2(Z). By [λ2j , λ2j−1] we denote the jth band of the spectrum of J counted from above for j ∈ 1, T. Suppose that pm ≠ pn for m ≠ n. We prove that the statements (i) and (ii) below are equivalent for λ ∈ R and i ∈ 1, T − 1. 相似文献
143.
Statistical simulations in medical and biological research are usually conducted with normal random numbers. However, in many cases, the distributions of real data in medical fields are usually right skewed. The conclusions led by simulations with the misspecified model might be misleading because of a gap between real data’s distribution and theoretical one. In this paper, we provide the simulation procedure for right skewed data based on reparameterized, easily interpretable parameters of the Box–Cox transformation model which includes multivariate distributions and regression models. We also show that the provided procedure is widely applicable to real world based on laboratory data, and then we provide parameter vector sets obtained by reparameterized parameter estimates that would cover almost all situations in which the distributions of data were right skewed and unimodal. 相似文献
144.
Yoshihiro Minematsu Michinori Waki Kazushi Suwa Tetsuo Kato Nobuo Izumiya 《Tetrahedron letters》1980,21(22):2179-2180
Azide and N-hydroxysuccinimide ester of five pentapeptides related to gramicidin S (cyclic decapeptide) were cyclized to determine the ratio of dimer to monomer in the cyclization product, the pentapeptide derivative with D-Phe as C-terminus giving the dimer in good yield. 相似文献
145.
146.
147.
We prove homological mirror symmetry for Lefschetz fibrations obtained as Sebastiani–Thom sums of polynomials of types A or D. The proof is based on the behavior of the Fukaya category under Sebastiani–Thom summation of a polynomial of type D. 相似文献
148.
Jianjun Liu Kazushi Enomoto Kotaro Takeda Daishi Inoue Yong-Jin Pu 《Chemical science》2021,12(30):10354
The geometry in self-assembled superlattices of colloidal quantum dots (QDs) strongly affects their optoelectronic properties and is thus of critical importance for applications in optoelectronic devices. Here, we achieve the selective control of the geometry of colloidal quasi-spherical PbS QDs in highly-ordered two and three dimensional superlattices: Disordered, simple cubic (sc), and face-centered cubic (fcc). Gel permeation chromatography (GPC), not based on size-exclusion effects, is developed to quantitatively and continuously control the ligand coverage of PbS QDs. The obtained QDs can retain their high stability and photoluminescence on account of the chemically soft removal of the ligands by GPC. With increasing ligand coverage, the geometry of the self-assembled superlattices by solution-casting of the GPC-processed PbS QDs changed from disordered, sc to fcc because of the finely controlled ligand coverage and anisotropy on QD surfaces. Importantly, the highly-ordered sc supercrystal usually displays unique superfluorescence and is expected to show high charge transporting properties, but it has not yet been achieved for colloidal quasi-spherical QDs. It is firstly accessible by fine-tuning the QD ligand density using the GPC method here. This selective formation of different geometric superlattices based on GPC promises applications of such colloidal quasi-spherical QDs in high-performance optoelectronic devices.Gel permeation chromatography can finely control ligand coverage of PbS quantum dots. Self-assembly of these QDs with different ligand density leads to the formation of 2D square, hexagonal and 3D simple cubic and face-centered cubic superlattices. 相似文献
149.
A method for the catalytic hydrophosphinylation of internal ynamides with H-phosphinates has been developed for the first time. The protocol employing the catalyst generated from NiBr2 and PPh3 could be applied to several types of ynamides and H-phosphinates, affording (E)-β-aminovinylphosphinates in a highly regio- and stereoselective manner. 相似文献
150.
Kenta Nishino Kazushi Hashimoto Kazuo Tanaka Yasuhiro Morisaki Yoshiki Chujo 《中国科学:化学(英文版)》2018,61(8):940-946
This article describes comparison of the anchoring effect on electronic properties of the helicene-like bibenzothiophene between o-carborane and 5,6-dicarba-nido-decaborane. The o-carborane and nido-decaborane-fused bibenzothiophenes were simultaneously obtained in the same reaction and successfully isolated. Initially, the X-ray single crystal analysis revealed that the helicene-like distorted structure was realized in the nido-decaborane-fused bibenzothiophene. From optical measurements in the solution state, distinct different characteristics depending on the type of anchors were observed. It was summarized that the absorption and luminescent properties originated from weak π-conjugation at the bibenzothiophene moiety in the o-carborane-fused compound were obtained, whereas robust π-conjugation and significant emission from the intramolecular charge transfer state were detected from the nido-decaborane-fused compound. These data can be explained by the theoretical results that π-conjugation was restrictedly developed within the bibenzothiophene moiety in frontier orbitals of the o-carborane-fused compound. In contrast, π-conjugation can be constructed even through the distorted bibenzothiophene because of the nido-decaborane unit. Moreover, the intramolecular charge transfer state should be realized because of electronic interaction involving the nido-decaborane unit in the excited state. Furthermore, it was demonstrated that the nido-decaborane-fused compound possessed solid-state emission and mechanochromic luminescent properties. The π-conjugation on the distorted structure supported by the nido-decaborane anchor should play a significant role in suppressing aggregation-caused quenching followed by presenting solid-state emission with stimuli responsiveness. 相似文献