全文获取类型
收费全文 | 891篇 |
免费 | 23篇 |
国内免费 | 6篇 |
专业分类
化学 | 692篇 |
晶体学 | 7篇 |
力学 | 10篇 |
数学 | 44篇 |
物理学 | 167篇 |
出版年
2023年 | 7篇 |
2021年 | 10篇 |
2020年 | 8篇 |
2019年 | 13篇 |
2018年 | 6篇 |
2017年 | 7篇 |
2016年 | 22篇 |
2015年 | 11篇 |
2014年 | 15篇 |
2013年 | 44篇 |
2012年 | 39篇 |
2011年 | 40篇 |
2010年 | 30篇 |
2009年 | 36篇 |
2008年 | 33篇 |
2007年 | 46篇 |
2006年 | 35篇 |
2005年 | 41篇 |
2004年 | 40篇 |
2003年 | 29篇 |
2002年 | 50篇 |
2001年 | 30篇 |
2000年 | 27篇 |
1999年 | 14篇 |
1998年 | 17篇 |
1997年 | 8篇 |
1996年 | 15篇 |
1995年 | 9篇 |
1994年 | 10篇 |
1993年 | 12篇 |
1992年 | 18篇 |
1991年 | 16篇 |
1990年 | 12篇 |
1989年 | 12篇 |
1988年 | 7篇 |
1987年 | 13篇 |
1986年 | 8篇 |
1985年 | 18篇 |
1984年 | 8篇 |
1983年 | 8篇 |
1982年 | 11篇 |
1981年 | 5篇 |
1980年 | 4篇 |
1979年 | 8篇 |
1978年 | 12篇 |
1977年 | 8篇 |
1976年 | 9篇 |
1975年 | 8篇 |
1974年 | 8篇 |
1973年 | 7篇 |
排序方式: 共有920条查询结果,搜索用时 46 毫秒
101.
Ruiyuan Liu Fumio Sanda Toshio Masuda 《Journal of polymer science. Part A, Polymer chemistry》2008,46(12):4175-4182
Copolymerization of ornithine‐ and lysine‐derived N‐propargylamides, N‐α‐tert‐butoxycarbonyl‐N‐δ‐fluorenylmethoxycarbonyl‐L ‐ornithine N′‐propargylamide ( 1 ), N‐α‐tert‐butoxycarbonyl‐N‐ε‐fluorenylmethoxycarbonyl‐L ‐lysine N′‐propargylamide ( 2 ), N‐α‐fluorenylmethoxycarbonyl‐N‐δ‐tert‐butoxycarbonyl‐L ‐ornithine N′‐propargylamide ( 3 ), and N‐α‐fluorenylmethoxycarbonyl‐N‐ε‐tert‐butoxycarbonyl‐L ‐lysine N′‐propargylamide (4) with dipropargyl adipate was carried out using (nbd)Rh+[η6‐C6H5B?(C6H5)3] as a catalyst in THF to obtain polymer gels in 80–93% yields. The gels adsorbed N‐benzyloxycarbonyl L ‐alanine, N‐benzyloxycarbonyl L ‐alanine methyl ester, and (S)‐(+)‐1‐phenyl‐1,2‐ethanediol preferably than the corresponding optical isomers. The order of chiral discrimination was poly( 1 ) > poly( 4 ) > poly( 2 ), poly( 3 ) gels. The fluorenylmethoxycarbonyl groups of the gels could be partly removed by piperidine treatment, leading to increase of adsorptivity but decrease of chiral recognition ability. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 4175–4182, 2008 相似文献
102.
We introduce the notions of approximate innerness and central triviality for endomorphisms on separable von Neumann factors, and we characterize them for hyperfinite factors by Connes-Takesaki modules of endomorphisms and modular endomorphisms which are introduced by Izumi. Our result is a generalization of the corresponding result obtained by Kawahigashi-Sutherland-Takesaki in automorphism case. 相似文献
103.
104.
Tomohiro Hirano Shuhei Masuda Shou Nasu Koichi Ute Tsuneyuki Sato 《Journal of polymer science. Part A, Polymer chemistry》2009,47(4):1192-1203
Radical polymerization of N,N‐dimethylacrylamide (DMAAm) was investigated in the presence of tartrates, such as diethyl L ‐tartrate, diisopropyl L ‐tartrate, and di‐n‐butyl L ‐tartrate, in toluene at low temperatures. Syndiotactic polymers were obtained in the presence of tartrates, whereas isotactic polymers were obtained in the absence of tartrates. The syndiotactic‐specificity increased with increasing amount of tartrates and with decreasing polymerization temperature. NMR analysis suggested that DMAAm and tartrates formed a 1:1 complex through double hydrogen bonding. A mechanism for the syndiotactic‐specific radical polymerization of DMAAm is proposed. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 1192–1203, 2009 相似文献
105.
Kayo Terada Toshio Masuda Fumio Sanda 《Journal of polymer science. Part A, Polymer chemistry》2009,47(19):4971-4981
Novel optically active ethynyl monomers were synthesized from L ‐valine and N‐methyl‐L ‐valine, and polymerized with a rhodium catalyst to provide the polymers with number‐average molecular weights over 200,000 in good yields. The CD and UV‐vis spectra of the polymers indicated that they took helical structures with predominantly one‐handed screw sense in solution. The polymers served as catalysts of asymmetric reduction of aromatic ketimines to afford optically active amines in moderate yields. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 4971–4981, 2009 相似文献
106.
Polytetrafluoroethylene (PTFE) films were successfully coated with tin oxide in aqueous solutions. Tin oxide was crystallized in the solution and formed nanocrystal coatings on the polymer films. The coatings consisted of SnO2 and SnO crystals. They were assemblies of tin oxide nanosheet of about 10 to 50 nm in size and about 5 nm in thickness. The nanocrystal films can be exfoliated from the PTFE substrates. Tin oxide nanocrystal films had a rough liquid surface and a dense substrate‐side surface. Transparency of PTFE films coated with tin oxide was same as that of bare PTFE films in the range from 400 to 800 nm. The PTFE films coated with tin oxide nanocrystals can be pasted on desired substrates. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
107.
Naohiro Kameta Dr. Hiroyuki Minamikawa Dr. Yuu Someya Dr. Hiroharu Yui Dr. Mitsutoshi Masuda Dr. Toshimi Shimizu Dr. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2010,16(14):4217-4223
Transportation, release behavior, and stability of a green fluorescent protein (GFP, 3×4 nm) in self‐assembled organic nanotubes with three different inner diameters (10, 20, and 80 nm) have been studied in terms of novel nanocontainers. Selective immobilization of a fluorescent acceptor dye on the inner surface enabled us to not only visualize the transportation of GFP in the nanochannels but to also detect release of the encapsulated GFP to the bulk solution in real time, based on fluorescence resonance energy transfer (FRET). Obtained diffusion constants and release rates of GFP markedly decreased as the inner diameter of the nanotubes was decreased. An endo‐sensing procedure also clarified the dependence of the thermal and chemical stabilities of the GFP on the inner diameters. The GFP encapsulated in the 10 nm nanochannel showed strong resistance to heat and to a denaturant. On the other hand, the 20 nm nanochannel accelerated the denaturation of the encapsulated GFP compared with the rate of denaturation of the free GFP in bulk and the encapsulated GFP in the 80 nm nanochannels. The confinement effect based on rational fitting of the inner diameter to the size of GFP allowed us to store it stably and without denaturation under high temperatures and high denaturant concentrations. 相似文献
108.
A photo-induced radical pair of FADH· and Y8· and in BLUF protein SyPixD was studied by pulsed electron paramagnetic resonance (EPR) spectroscopy. Blue light illumination
at 150 K for 30 min followed by cooling to 50 K during illumination induced the stable radical pair. The EPR signal has been
characterized by a Pake doublet signal with complete S = 1 spin state. The radical pair was utilized as a probe to analyze the oligomer of SyPixD. The relative arrangement of PixD
proteins in the complex was investigated by pulsed electron–electron double resonance (PELDOR) with the orientation selection.
Based on the decameric structure in the crystal, the possible structure for the PELDOR results was discussed. 相似文献
109.
A. Nakajima Y. Masuda E. Matsuda Y. Ueda H. Sameshima T. Ikenoue 《Applied magnetic resonance》2011,40(4):535-544
The reaction between 3-methoxycarbonyl-2,2,5,5-tetramethylpyrrolidine-1-oxyl (PCAM), which is a blood–brain-barrier (BBB)
permeable stable cyclic nitroxide, and ascorbic acid was examined in a low dissolved oxygen-phosphate buffer (low DO-PB, 0.1 mM
DO) under 8% oxygen in a glove bag or in an ordinal dissolved oxygen-phosphate buffer (ordinal DO-PB, 0.3 mM DO) under 21%
oxygen in an open atmosphere with and without diethylenetriaminepentaacetic acid (DTPA). In PB with DTPA, no difference was
observed between the results in the low DO-PB and those in the ordinal DO-PB. In the ordinal DO-PB without DTPA, the rate
constant of the PCAM decrease was half that in the low DO-PB without DTPA. The present results indicate that high DO and coexisting
transition metal ions caused the oxidation of ascorbic acid, which degraded the PCAM reduction. The stable nitroxide-ascorbic
acid system without DTPA was found to be applicable to an in vitro model for the acute hypoxia ischemia. 相似文献
110.
Mikiya Masuda Seonjeong Park 《Proceedings of the Steklov Institute of Mathematics》2014,286(1):308-323
The notion of a toric origami manifold, which weakens the notion of a symplectic toric manifold, was introduced by A. Cannas da Silva, V. Guillemin and A.R. Pires. They showed that toric origami manifolds bijectively correspond to origami templates via moment maps, where an origami template is a collection of Delzant polytopes with some folding data. Like a fan is associated to a Delzant polytope, a multi-fan introduced by A. Hattori and M. Masuda can be associated to an oriented origami template. In this paper, we discuss their relationship and show that any simply connected compact smooth 4-manifold with a smooth action of T 2 can be a toric origami manifold. We also characterize products of even dimensional spheres which can be toric origami manifolds. 相似文献