全文获取类型
收费全文 | 4599篇 |
免费 | 141篇 |
国内免费 | 13篇 |
专业分类
化学 | 3536篇 |
晶体学 | 34篇 |
力学 | 68篇 |
数学 | 189篇 |
物理学 | 926篇 |
出版年
2022年 | 35篇 |
2021年 | 41篇 |
2020年 | 52篇 |
2019年 | 52篇 |
2018年 | 36篇 |
2017年 | 40篇 |
2016年 | 76篇 |
2015年 | 90篇 |
2014年 | 83篇 |
2013年 | 223篇 |
2012年 | 198篇 |
2011年 | 218篇 |
2010年 | 120篇 |
2009年 | 119篇 |
2008年 | 226篇 |
2007年 | 217篇 |
2006年 | 237篇 |
2005年 | 253篇 |
2004年 | 248篇 |
2003年 | 193篇 |
2002年 | 234篇 |
2001年 | 146篇 |
2000年 | 112篇 |
1999年 | 79篇 |
1998年 | 61篇 |
1997年 | 47篇 |
1996年 | 73篇 |
1995年 | 57篇 |
1994年 | 64篇 |
1993年 | 60篇 |
1992年 | 80篇 |
1991年 | 63篇 |
1990年 | 54篇 |
1989年 | 49篇 |
1988年 | 48篇 |
1987年 | 37篇 |
1986年 | 49篇 |
1985年 | 78篇 |
1984年 | 68篇 |
1983年 | 28篇 |
1982年 | 50篇 |
1981年 | 37篇 |
1980年 | 33篇 |
1979年 | 59篇 |
1978年 | 39篇 |
1977年 | 45篇 |
1976年 | 31篇 |
1975年 | 35篇 |
1974年 | 30篇 |
1973年 | 34篇 |
排序方式: 共有4753条查询结果,搜索用时 15 毫秒
121.
A direct preparative route to benzoyltrimethylsilane has been found by the reaction of benzoyl chloride with hexamethyldisilane in the presence of a specified palladium(II) complex as catalyst. 相似文献
122.
123.
124.
The synthetic procedures for spilanthol and trail-following pheromone for a southern subterranean termite were described. The syntheses heavily depend on the new diene synthesis using titanium reagent. 相似文献
125.
Synthesis and characterization of 6-O-acyl-2-O-alpha-D-glucopyranosyl-L-ascorbic acids with a branched-acyl chain 总被引:3,自引:0,他引:3
We previously reported the chemical synthesis of a series of novel monoacylated vitamin C derivatives, 6-O-acyl-2-O-alpha-D-glucopyranosyl-L-ascorbic acids (6-Acyl-AA-2G) possessing a straight-acyl chain of varying length from C(4) to C(18), as effective skin antioxidants. In this paper, we describe branched type of 6-Acyl-AA-2G derivatives (6-bAcyl-AA-2G) synthesized by use of a 2-branched-chain fatty acid anhydride as an acyl donor. The stability of 6-bAcyl-AA-2G in neutral solution was much higher than that of 6-Acyl-AA-2G, while they were susceptible to enzymatic hydrolysis for exerting vitamin C effect. These branched derivatives as well as 6-Acyl-AA-2G increased the radical scavenging activity against 1, 1-diphenyl-2-picrylhydrazyl and the lipophilicity in octanol/water-partitioning systems with increasing length of their acyl group. In addition, the 6-bAcyl-AA-2G derivative with an acyl chain of C(12), 6-bDode-AA-2G had the excellent solubility to various solvents, suggesting easy handling in cosmetic use. These characteristics of 6-bAcyl-AA-2G may be available for skin care application as an effective antioxidant. 相似文献
126.
Akiko Saito Mana Emoto Akira Tanaka Yuki Doi Kazuaki Shoji Yoshiyuki Mizushina Hiroshi Ikawa Hiromi Yoshida Nobuyasu Matsuura Noriyuki Nakajima 《Tetrahedron》2004,60(52):12043-12049
A simple method for the synthesis of procyanidin B3 substituted with a galloyl group at the 3 and 3″ position is described. Condensation of a benzylated catechin-3-O-gallate electrophile with a nucleophile, catechin and catechin-3-O-gallate, proceeded smoothly and stereoselectively to afford the corresponding dimer gallates, procyanidin B3-3-O-gallate and procyanidin B3-3,3″-di-O-gallate, in good yields. Further, their antioxidant activities on UV-induced lipid peroxide formation, DPPH radical scavenging activity and inhibitory activity of DNA polymerase were also investigated. Among three procyanidin B3 congeners (procyanidin B3, 3-O-gallate and 3,3″-di-O-gallate), the 3,3″-di-O-gallate derivative showed the strongest antioxidant and radical scavenging activity. Interestingly, the 3-O-gallate derivative was the strongest inhibitor of mammalian DNA polymerase with IC50 value of 0.26 μM, although it showed the weakest antioxidant and radical scavenging activity. It became apparent that the presence of a galloyl group at the C-3 position in the proanthocyanidin oligomer was very important for biological activity, however, the antioxidant activity of these compounds was not parallel to the DNA polymerase inhibitory activity. 相似文献
127.
The selective generation of three different silver-BINAP catalysts has been achieved via the proper combination of metal/ligand ratio and/or choice of silver salt. Indeed, the X-ray crystallographic study has been used to gain insight into the structure of the catalyst. After the evaluation of each species, 1:1 (AgX.(R)-BINAP) complex was found to be the real active species in the O-selective nitroso aldol reaction. On the other hand, a systematic survey of solvent has shown that the optimal 2:1 (AgX.(R)-BINAP) complex is the effective catalyst in the N-selective pathway. Thus, a new method of generation of the silver-BINAP catalyst and the synthetic transformations provide not only new insights into the developing area of catalytic enantioselective nitroso aldol synthesis but also clear guidance for the design of an effective catalyst. 相似文献
128.
Electrophoretic mobilities of red blood cells (RBCs) were measured in microgravity using a home-made capillary electrophoresis unit, which consisted of two small reservoirs of 0.6 mL and a fused-silica capillary tubing with 2 cm in length and 50 num in inner diameter. Migration of RBCs was observed by a microscope at 1000 times magnification and recorded on a videotape. The experiments were performed during stays in microgravity (about 0.01 G), which lasted 20 s and were attained by parabolic flights of an aircraft. On average, the electrophoretic mobilities of RBCs determined in microgravity were about 30% higher than those measured at 1-G condition irrespectively whether the cells were suspended in saline or serum during measurements. This difference might be explained as being mainly due to the cell floating in microgravity. Morphological changes of RBCs may contribute partly to the difference, while the variation in viscosity of the medium under microgravity could play only a minor role. 相似文献
129.
130.
The d. c. component of birefringence of aqueous carboxymethylcellulose (CMC) under an a. c. electric field was measured at frequencies ranging from 0.1 Hz to 100 kHz. Three samples of different molecular weights were studied with varying degree of neutralization, polymer concentration and added salt concentration. The dispersion curve of birefringence consists of three relaxation bands,A, B andC in order of decreasing frequency. RelaxationB with a negative relaxation strength is ascribed to end-over-end rotation of almost rodlike CMC molecules. RelaxationA with a positive strength is attributed to the relaxation of electrical polarizability along the minor axis of molecule. RelaxationC possesses also a positive strength and is induced by clusters of CMC molecules.Dedicated to Prof. Dr. F. H. Müller. 相似文献