Efficient strategies for boosting the performance of 2D graphitic carbon nitride nanomaterials during photoreduction of carbon dioxide to energy-rich chemicals

Nowadays, the alarming growing interest in providing a solution to increasing concentration of atmospheric carbon dioxide (CO₂) and the associated pollution has attracted global attention. The consequential effects of CO₂ are detrimental to the environment owing to the continuous depletion of carbon-emitting fossil fuels. Photocatalytic CO₂ reduction (CO₂R) to valuable chemicals and fuels is one the promising alternative option to mitigate the global menace instigated by CO₂ emissions. If the strategies for enhancing the CO₂R are unavailable, inefficient, or inappropriate, then efficiency conversion CO₂ to valuable products can become problematic. In that case, the emission of CO₂ results in synchronizing upsurge in the global-mean air surface temperature on the earth and sea levels from 1980 to 2100. This study presents different strategies for boosting the photocatalytic performance of 2D graphitic carbon nitride (g-C₃N₄) for CO₂R reaction. The first part consists of the fundamental principles of photocatalysis. The second part presents some answers to the question: what governs the mechanism of photocatalytic CO₂R? The existing literature lack comprehensive information about the strategical influence of available reactor designs on the photoactivity of 2D g-C₃N₄ for CO₂ conversion to energy-rich chemicals and ways to improve them as discussed in this study. This was then followed by strategies about the synthetic methods for enhancing photocatalytic CO₂R over 2D g-C₃N₄ materials before the discussion of the strategies for enhancing the CO₂ photoreduction on the 2D g-C₃N₄ nanomaterials. Some groups of g-C₃N₄ nanomaterials for photoreduction of CO₂R were also discussed. Unlike the previous reviews in the field, the present study presents some innovation to bridge the knowledge gaps of the previous reviews and corresponding insight thereof. For future breakthroughs, this study also explains some problems with the interpretation in the field. We also highlight insights into innovation on exclusion and inclusion criteria about the performance metrics and present some queries, concerns, and problems with the previous studies. The concluding part consists of research outlooks, including commonly overlooked challenges and future perspectives for ensuring highly efficient strategies, applications of 2D g-C₃N₄ photocatalysts, and CO₂ conversion to meet industrial scale expectations. The present study hypothesized that considering the current technological age, the experiment should go beyond presenting only illustration and analysis about the band energy, but the detailed explanation/information about the pathways of the various products formed using molecular dynamics system and artificial intelligence aspects should be combined in the future studies.     

Approximation of common solution of finite family of monotone inclusion and fixed point problems for demicontractive multivalued mappings in CAT(0) spaces

Ricerche di Matematica - In this paper, we use the gate condition on two multivalued k-demicontractive mappings to approximate a common solution of a finite family of monotone inclusion problem and...     

Structural studies of (prop‐2‐en‐1‐yl)bis[(pyridin‐2‐yl)methylidene]amine hetero‐scorpionate copper complexes

The structures of five compounds consisting of (prop‐2‐en‐1‐yl)bis[(pyridin‐2‐yl)methylidene]amine complexed with copper in both the Cu^I and Cu^II oxidation states are presented, namely chlorido{(prop‐2‐en‐1‐yl)bis[(pyridin‐2‐yl)methylidene]amine‐κ³N,N′,N′′}copper(I) 0.18‐hydrate, [CuCl(C₁₅H₁₇N₃)]·0.18H₂O, (1), catena‐poly[[copper(I)‐μ₂‐(prop‐2‐en‐1‐yl)bis[(pyridin‐2‐yl)methylidene]amine‐κ⁵N,N′,N′′:C²,C³] perchlorate acetonitrile monosolvate], {[Cu(C₁₅H₁₇N₃)]ClO₄·CH₃CN}_n, (2), dichlorido{(prop‐2‐en‐1‐yl)bis[(pyridin‐2‐yl)methylidene]amine‐κ³N,N′,N′′}copper(II) dichloromethane monosolvate, [CuCl₂(C₁₅H₁₇N₃)]·CH₂Cl₂, (3), chlorido{(prop‐2‐en‐1‐yl)bis[(pyridin‐2‐yl)methylidene]amine‐κ³N,N′,N′′}copper(II) perchlorate, [CuCl(C₁₅H₁₇N₃)]ClO₄, (4), and di‐μ‐chlorido‐bis({(prop‐2‐en‐1‐yl)bis[(pyridin‐2‐yl)methylidene]amine‐κ³N,N′,N′′}copper(II)) bis(tetraphenylborate), [Cu₂Cl₂(C₁₅H₁₇N₃)₂][(C₆H₅)₄B]₂, (5). Systematic variation of the anion from a coordinating chloride to a noncoordinating perchlorate for two Cu^I complexes results in either a discrete molecular species, as in (1), or a one‐dimensional chain structure, as in (2). In complex (1), there are two crystallographically independent molecules in the asymmetric unit. Complex (2) consists of the Cu^I atom coordinated by the amine and pyridyl N atoms of one ligand and by the vinyl moiety of another unit related by the crystallographic screw axis, yielding a one‐dimensional chain parallel to the crystallographic b axis. Three complexes with Cu^II show that varying the anion composition from two chlorides, to a chloride and a perchlorate to a chloride and a tetraphenylborate results in discrete molecular species, as in (3) and (4), or a bridged bis‐μ‐chlorido complex, as in (5). Complex (3) shows two strongly bound Cl atoms, while complex (4) has one strongly bound Cl atom and a weaker coordination by one perchlorate O atom. The large noncoordinating tetraphenylborate anion in complex (5) results in the core‐bridged Cu₂Cl₂ moiety.     

A DFT/TD-DFT study on the possible replacement of Ru(II) with Fe(II) in phthalocyanine-based dye-sensitized solar cells

Structural Chemistry - Density functional theory and time-dependent density functional theory (DFT/TD-DFT) methods have been used to study the photo-voltaic and photophysicochemical properties of...