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491.
Ni(II) coordination polymers with a 4,4'-azobis(pyridine) (azpy) ligand, {[Ni2(NCX)4(azpy)4].G}n (X = S, G (guest molecule) = MeOH (1.MeOH); X = S, G = EtOH (1.EtOH); X = S, G = H2O (1.H2O); X = S, G = no guest (1); X = Se, G = MeOH (2.MeOH); X = Se, G = H2O (2.H2O); X = Se, G = no guest (2)), have been synthesized and structurally characterized with their porosity. These compounds have one-dimensional periodic ultramicropores that contain the small guest molecules, H2O, MeOH, or EtOH, whose hydroxy groups interact with the S or Se atoms of isothiocyanate or isoselenocyanate, respectively, via -S(Se)...HO- hydrogen bonds. Although the molecular dimensions of the MeOH guest are considerably larger than the window size of the ultramicropore, 1.MeOH and 2.MeOH easily release their guest molecules without decomposition of the framework to form 1 and 2 without any guest molecules. This shows that 1 and 2 have dynamic ultramicropores constructed from the interpenetrating framework. The guest desorption experiments using 1.MeOH and 1.EtOH reveal that the difference in the desorption behavior is due to van der Waals interactions that depend on the molecular shape of the guest molecule in the ultramicropores and/or an entrance blocking effect that depends on the minimum dimensions of the guest molecule for the pore windows. A marked difference in the N2 and CH4 adsorption isotherms was observed and is associated with the strength of the host-guest interaction. 相似文献
492.
Monte Carlo (MC) simulations were performed for hard spheres (with diameter sigma and mass m) placed between well-separated upper and lower hard walls. A periodic boundary condition was imposed in the horizontal direction. The system was exposed to the gravitational field with the acceleration due to gravity g. After preparing a melt as the initial state, g was increased stepwise up to mgsigma/k(B)T(identical with g(*))=1.5 or 2.0 with an increment Deltag(*) = 0.1; k(B)T is the temperature multiplied by Boltzmann's constant. We maintained g(*) at each value for 2.0 x 10(5) MC cycles. The transition of the system into a metastable state such as a polycrystalline state due to trapping phenomena was successfully avoided. A monotonic increase and subsequent saturation were observed for the development of the crystalline region formed at the bottom of the system. The development of this region accompanied a shrinkage of the defective (or less ordered) crystalline region that was formed between the bottom region and the fluid phase. As the development of the bottom region almost saturated, the defective region grew upward again. 相似文献
493.
Electron transfer from the electron donor of p-phenylenediamine (PPD) to the electron acceptor of (H+)3[PMo12O40]3- forms a one-electron-reduced Keggin cluster of [PMo12O40]4-, bearing a S = 1/2 spin, while proton transfer from the proton donor of (H+)3[PMo12O40]3- to the proton acceptor of PPD yielded mono- and diprotonated cations of 4-aminoanilinium (HPPD+) and p-phenylenediammonium (H2PPD2+). By introduction of crown ether receptors during the crystallization process, supramolecular cations of (HPPD+)(crown ethers) and/or (H2PPD2+)(crown ethers) were successfully introduced into three new alpha-[PMo12O40]4- salts of (H2PPD2+)2([12]crown-4)4[PMo12O40]4- (1), (HPPD+)4([15]crown-5)4[PMo12O40]4- (2), and (HPPD+)2(H2PPD2+)([18]crown-6)4[PMo12O40]4- (3) as the countercation. The protonated states of PPD and molecular-assembly structures of the supramolecular cations depended on the size of the crown ethers. In salt 3, a novel mixed-protonated state of HPPD+ and H2PPD2+ was confirmed to be complexed in the cation structure. According to the changes in the cation structures, the anion arrangements were modulated from those of the two-dimensional layer for salt 1 to the isolated cluster for salts 2 and 3. The temperature-dependent magnetic susceptibilities of salts 1-3 were consistent with the isolated spin arrangements of [PMo12O40]4-. The electronic spectra of salts 1-3 indicated the intervalence optical transition from pentavalent Mo(V) to hexavalent Mo(VI) ions within the [PMo12O40]4- cluster. Temperature-dependent electron spin resonance spectra of salt 2 revealed the delocalization-localization transition of the S = 1/2 spin at 60 K. The spin on the [PMo12O40]4- cluster was localized on a specific Mo(V) site below 60 K, which was thermally activated with an activation energy of 0.015 eV. 相似文献
494.
Yuko Araki Sadanori Konishi Shuichi Kawano Hidetoshi Matsui 《Annals of the Institute of Statistical Mathematics》2009,61(4):811-833
We consider the problem of constructing functional regression models for scalar responses and functional predictors, using
Gaussian basis functions along with the technique of regularization. An advantage of our regularized Gaussian basis expansions
to functional data analysis is that it creates a much more flexible instrument for transforming each individual’s observations
into functional form. In constructing functional regression models there remains the problem of how to determine the number
of basis functions and an appropriate value of a regularization parameter. We present model selection criteria for evaluating
models estimated by the method of regularization in the context of functional regression models. The proposed functional regression
models are applied to Canadian temperature data. Monte Carlo simulations are conducted to examine the efficiency of our modeling
strategies. The simulation results show that the proposed procedure performs well especially in terms of flexibility and stable
estimates. 相似文献
495.
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497.
Various poly- and oligosaccharides having a well-defined structure have successfully been synthesized via enzymatic polymerization of glycosyl fluoride monomers. All of the reaction proceeded under perfect control of regio- and stereochemistry. The relative direction of the synthetic cellulose (parallel or antiparallel) could be controlled in vitro in the enzyme-promoted propagation system, and based on these findings, a new concept “allos-selectivity” has been proposed. 相似文献