Reversed phase-HPLC for rapid determination of polyphenols in flowers of rose species

A rapid, simple, sensitive, robust, and improved HPLC method was developed and validated for determination of 10 polyphenols, namely gallic acid, catechin, epicatechin, rutin, m-coumaric acid, quercitrin, myricetin, quercetin, apigenin, and kaempferol in fresh flowers of Rosa bourboniana and R. brunonii and in both fresh flowers and marc (left after industrial distillation of rose oil) of R. damascena. Six polyphenols, gallic acid, rutin, quercitrin, myricetin, quercetin, and kaempferol, were detected and quantified in all extracts. The chromatographic separation of 10 polyphenols was achieved in less than 16 min by RP-HPLC (Phenomenex, Luna C18 (2) column, 5 microm, 250 mm x 4.6 mm) using linear gradient elution of water and acetonitrile (0.02% trifluroacetic acid) with a flow rate of 1 mL/min at lambda 280 nm. Standard calibration curves were linear in the range of 0.39-500 microg/mL. Good results were achieved with respect to repeatability (RSD <3%) and recovery (98.6-100.8%). The method was validated for linearity, accuracy, repeatability, LOD, and LOQ.     

Evolution of magnetooptical and transport properties of La<Subscript>1−<Emphasis Type="Italic">x</Emphasis></Subscript>Ag<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript>MnO<Subscript>3</Subscript> films depending on silver concentration

Evolution of optical, magnetooptical, and transport properties of La_1?x Ag _x MnO₃/SrTiO₃ epitaxial films depending on the silver concentration (x = 0.05, 0.10, 0.15, and 0.25) is studied. The highest values of the Curie temperature (T _C ≈ 317 K), magnetoresistance (～16%), magnetotransmission (～8%), and transverse Kerr effect (δ ～ 20 × 10^?3) are attained for a concentration x = 0.10 of Ag⁺ ions. Comparison of the temperature dependences of the transmission of IR radiation, resistivity, magnetotransmission, magnetoresistance, and Kerr effect indicates electronic and magnetic inhomogeneity of the films in spite of saturation of films with silver. This feature of the film state is explained using the concepts of epitaxial stresses and metastable point defects.     

Heat capacity of the La<Subscript>0.9</Subscript>Ag<Subscript>0.1</Subscript>MnO<Subscript>3</Subscript> manganite near the curie temperature

The heat capacity of the La_0.9Ag_0.1MnO₃ manganite is measured in the temperature range 77–350 K and studied in detail in the vicinity of the Curie temperature for the first time. The regularities of the variation in the universal critical parameters in the vicinity of the phase transition point are established. The critical exponent and the amplitude of the heat capacity are calculated to be α = ?0.127 and A ⁺/A ^? = 1.146 with due regard for the scaling corrections. These parameters correspond to the critical behavior within the three-dimensional Heisenberg model. The size of ferromagnetic droplets in the paramagnetic range at T > T _C is estimated as ξ ≈ 19 Å. The results obtained are analyzed thoroughly and compared with theoretical data for a number of model systems.     

Magnetocaloric properties of La0.7Ca0.3MnO3 manganites with 16O → 18O isotopic substitution

This paper reports on a study of the effect of isotopic ¹⁶O → ¹⁸O oxygen substitution on the heat capacity and magnetocaloric properties of the La_0.7Ca_0.3MnO₃ manganite. Direct measurements of the magnetocaloric effect have demonstrated that, in La_0.7Ca_0.3MnO₃, the effect reaches a fairly large magnitude, but its temperature width is rather small. The ¹⁶O ar ¹⁸O isotopic substitution shifts the temperature of the maximum of the effect toward lower temperatures while leaving its magnitude practically unchanged. The magnetocaloric effect in the La_0.7Ca_0.3Mn¹⁶O₃ + La_0.7Ca_0.3Mn¹⁸O₃ sandwich structure has been measured by the direct method. It has been shown that fabrication of a sandwich from materials with close temperatures of the maxima of the magnetocaloric effect permits increasing the relative cooling power (RCP) compared with that of the starting materials.     

Nonlinear scaling and its application to ferromagnetic systems

Making use of renormalization-group ideas, a scaling equation of state applicable to ferromagnetic systems and involving the nonlinear scaling variables =ε/t and =h/t, instead of the usual linear scaling variables ε=(T-T_c)/Tc = t-1 and h=H (ordering field), has been derived. The magnetic equation of state so obtained is then generalized to take into account the effect of nonlinear relevant and irrelevant scaling fields. To facilitate a comparison with experiments, the analytic (non-analytic) corrections to the dominant singular behaviour of spontaneous magnetization (order parameter) M(T, 0), ‘zero-field’ susceptibility χ(T, 0), and specific heat in zero field that the nonlinear relevant (irrelevant) scaling fields give rise to are explicitly calculated up to third order in Due consideration is also given to the modifications in the Arrott-Noakes form of the scaling equation of state and the Kouvel-Fisher definition of the effective susceptibility exponent brought about by these scaling fields. A detailed analysis of the M(T, 0) and χ(T, 0) data for crystalline and amorphous ferromagnets in terms of the theoretical expressions derived in this work reveals that i) in conformity with the theoretical predictions, the “;non-analytic”; corrections to the singular behaviour dominate over the “;analytic”; ones for temperatures in the immediate vicinity of the critical point Tc, whereas reverse is the case for temperatures far away from Tc and (ii) the expression for χ(T, 0), based on the nonlinear scaling arguments, which includes the leading “;analytic”; correction, reproduces closely the observed variation of χ with T over a wide range of temperatures T_c ≤ T ≤ 1.5T_c (in some cases, up to 3T_c) for both ordered as well as quench-disordered ferromagnets.     

Spin states of cobalt and the thermodynamics of Sm1 − x Ca x CoO3 − δ solid solutions

In the rare-earth SmCoO₃ perovskite, Co³⁺ ions at low temperatures appear to be in the low-spin state with S = 0, t _2g ² e _g ⁰ . If Ca²⁺ ions partially substitute Sm³⁺ ions, oxygen deficient Sm_{1 ? x} Ca _x CoO_{3 ? δ} solid solutions with δ = x/2 appear. The oxygen deficiency leads to the formation of pyramidally coordinated cobalt ions Co _pyr ³⁺ in addition to the existing cobalt ions Co _oct ³⁺ within the oxygen octahedra. Even at low temperatures, these ions have a magnetic state, either S = 1, t _2g ⁵ e _g ¹ or S = 2, t _2g ⁴ e _g ² . At low temperatures, the magnetization of Sm_{1 ? x} Ca _x CoO_{3 ? δ} is mainly determined by the response of Co _pyr ³⁺ ions. Owing to the characteristic features of the crystal structure of the oxygen deficient perovskite, these ions form a set of nearly isolated dimers. At high temperatures, the magnetization of Sm_{1 ? x} Ca _x CoO_{3 ? δ} is mainly determined by the response of Co _oct ³⁺ ions, which exhibit a tendency to undergo the transition from the S = 0, t _2g ⁶ e _g ⁰ state to the S = 1, t _2g ⁵ e _g ¹ or S = 2, tt _2g ⁴ e _g ² state. In addition, the magnetization and specific heat of the solid solutions under study include the contribution from the rare-earth subsystem, which undergoes a magnetic ordering at low temperatures.     

Lattice instability and martensitic transformation in LaAg predicted from first-principles theory

The electronic structure, elastic constants and lattice dynamics of the B(2) type intermetallic compound LaAg are studied by means of density functional theory calculations with the generalized gradient approximation for exchange and correlation. The calculated equilibrium properties and elastic constants agree well with available experimental data. From the ratio between the bulk and shear moduli, LaAg is found to be ductile, which is unusual for B(2) type intermetallics. The computed band structure shows a dominant contribution from La 5d states near the Fermi level. The phonon dispersion relations, calculated using density functional perturbation theory, are in good agreement with available inelastic neutron scattering data. Under pressure, the phonon dispersions develop imaginary frequencies, starting at around 2.3 GPa, in good accordance with the martensitic instability observed above 3.4 GPa. By structural optimization the high pressure phase is identified as orthorhombic B(19).     

Packing of graphic n‐tuples

An n‐tuple π (not necessarily monotone) is graphic if there is a simple graph G with vertex set {v₁, …, v_n} in which the degree of v_i is the ith entry of π. Graphic n‐tuples (d, …, d) and (d, …, d) pack if there are edge‐disjoint n‐vertex graphs G₁ and G₂ such that d(v_i) = d and d(v_i) = d for all i. We prove that graphic n‐tuples π₁ and π₂ pack if , where Δand δdenote the largest and smallest entries in π₁ + π₂ (strict inequality when δ = 1); also, the bound is sharp. Kundu and Lovász independently proved that a graphic n‐tuple π is realized by a graph with a k‐factor if the n‐tuple obtained by subtracting k from each entry of π is graphic; for even n we conjecture that in fact some realization has k edge‐disjoint 1‐factors. We prove the conjecture in the case where the largest entry of π is at most n/2 + 1 and also when k?3. © 2011 Wiley Periodicals, Inc. J Graph Theory