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91.
To understand accurate protein dynamics, a highly reproducible proteomics analytical method is required. The acquired thus knowledge will lead to the diagnosis, treatment and protection against diseases. This review deals with proteomics analysis from a view of sample pre-treatment, sensitivity and reproducibility of the methods, including two-dimensional polyacrylamide gel electrophoresis (2D-PAGE), liquid chromatography-tandem mass spectrometry (LC-MS/MS). and fluorogenic derivatization (FD)-LC-MS/MS. 相似文献
92.
Kobayashi T Hasegawa F Hirose Y Tanaka K Mori H Katsumura S 《The Journal of organic chemistry》2012,77(4):1812-1832
The asymmetric one-pot 6π-azaelectrocyclization of alkenyl vinyl stannane, ethyl (Z)-2-iodo-4-oxobutenoate, and (-)-7-isopropyl-cis-aminoindanol in the presence of a Pd(0) catalyst stereoselectively produced the tetracyclic aminoacetal compounds, resulting from the four-bond formation accompanying by controlling the stereochemistry at the two asymmetric centers. The produced cyclic aminoacetals can be regarded as synthetic precursors of substituted chiral piperidines, and the syntheses of 2,4- and 2,4,6-substituted piperidines were realized from the obtained aminoacetals by the stereoselective hydrogenation of the double bond conjugated with the C-4 ester group and alkylation at the aminoacetal moiety. In addition, the stereoselective synthesis of an indolizidine alkaloid, (-)-dendroprimine, and its three stereoisomers, (+)-7-epidendroprimine, (+)-5-epidendroprimine, and (+)-5,7-epidendroprimine, were achieved. 相似文献
93.
Shun‐suke Asami Masafumi Okamoto Katsunori Suzuki Makoto Yamashita 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2016,128(41):13019-13023
A boryl‐substituted diphosphene was synthesized through the nucleophilic borylation of PCl3 with a borylzinc reagent, followed by a reduction with Mg. A combined analysis of the resulting diboryldiphosphene by single‐crystal X‐ray diffraction, DFT calculations, and UV/Vis spectroscopy revealed a σ‐electron‐donating effect for the boryl substituent that was slightly weaker than that of the 2,4,6‐tri‐tert‐butylphenyl (Mes*) ligand. The reaction of this diboryldiphosphene with nBuLi afforded a boryl‐substituted phosphinophosphide that was, in comparison with the thermally unstable Mes*‐substituted diaryldiphosphene, stabilized by a π‐electron‐accepting effect of the boryl substituent. 相似文献
94.
Regina Sibgatullina Katsumasa Fujiki Takefumi Murase Takahiro Yamamoto Taiji Shimoda Almira Kurbangalieva Katsunori Tanaka 《Tetrahedron letters》2017,58(20):1929-1933
One pot double click strategy containing strain-promoted click-reaction followed by 6π-azaelectrocyclization (RIKEN click reaction) has worked well in the synthesis of multivalent homogeneous and heterogeneous N-glycoalbumins. We have slightly changed the structure of linker unsaturated aldehyde used in this method. As a result it can be easily synthesized from commercially available material and furthermore, the enhancement of its reactivity towards both click-reactions was observed. The data described in this Communications facilitate the usage of the double click strategy as a general method for the synthesis of a variety of neo-N-glycoproteins. 相似文献
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98.
A method of reconstructing positive and negative images from Fourier holograms recorded without the dc components is demonstrated by use of a coaxial holographic storage system. Reconstructed images are obtained by adding a phase-modulated dc component of the signal beam on reading. Contrast reversal of the reconstructed images can be achieved by reversing the readout reference pattern. This method can realize not only optical noise reduction but also less consumption of the dynamic range of the recording medium, potentially contributing to increasing the number of multiplexed holograms. 相似文献
99.
A strong organic base, TBD, functioned as a unique catalyst for the intramolecular multi-step transformation of lactols using the Ferrier-type rearrangement as the key step to provide unsymmetrically substituted 2,2'-dihydroxy biaryl compounds having four ortho substituents about the biaryl axis without the need for a metal catalyst. 相似文献
100.
Katsunori Kawamura 《Linear algebra and its applications》2012,436(7):2638-2652
Let denote the -algebra defined as the direct sum of all matrix algebras . It is known that has a non-cocommutative comultiplication . From a certain set of transformations of integers, we construct a universal R-matrix R of the -bialgebra such that the quasi-cocommutative -bialgebra is triangular. Furthermore, it is shown that certain linear Diophantine equations are corresponded to the Yang–Baxter equations of R. 相似文献