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81.
82.
Tatsuya Kanno Takahide Oguchi Hirochika Sakuragi Katsumi Tokumaru 《Tetrahedron letters》1980,21(5):467-470
Irradiation of semiconductors (TiO2 and CdS) suspended in organic solvents containing 1,1-diphenylethylene and its derivatives under oxygen afforded the corresponding epoxides and benzophenone. A possible mechanism is discussed. 相似文献
83.
84.
Shinji Tomoda Yohji Achiba Katsunori Nomoto Kenji Sato Katsumi Kimura 《Chemical physics》1983,74(1):113-120
In this paper we describe several characteristics of our supersonic nozzle beam photoelectron spectrometer recently constructed for studying hydrogen-bonded dimers in the gas phase by HeI (58.4 nm) radiation. Using this photoelectron apparatus, we have reinvestigated the HeI photoelectron spectrum of the formic-acid dimer (HCOOH)2 which is well known as a fairly strong doubly hydrogen-bonded dimer. It was found that the (HCOOH)2 spectrum deduced here from the spectrum of the monomer—dimer mixture considerably differs from that reported by Carnovale et al. in the region beyond 16.5 eV. New spectral assignments are given for four ionization bands beyond 16.5 eV. It is also indicated that the lower bound of the dissociation energy of (HCOOH)2+ is estimated to be 1.0 ± 0.1 eV from the threshold of the dimer band (11.0 eV) obtained in this experiment. This value is considerably smaller than the value of 1.7 ± 0.2 eV recently reported for the water dimer cation (H2O)2+. 相似文献
85.
Shunji Katsumata Katsumi Kimura 《Journal of Electron Spectroscopy and Related Phenomena》1975,6(4):309-319
He(I) photoelectron spectra are reported for various series of chlorine-substituted compounds: (a) CH3CH3?mClm, (b) CH3?mClmCCl3, (c) CH3?mClmCHO and (d) CH3?mClmCOCl, where m = 1, 2 and 3. In each series it is shown that the total sum of vertical ionization energies over all p-type localized molecular orbitals (LO's) has an excellent linear relationship to the number of substituted chlorine atoms. The differences in the total orbital energy sum by successive chlorine substitutions are found to be 26.7 eV for series a and b and 27.2 eV for series c and d, yielding the corresponding experimental σCCl, energies useful for sum rule considerations. The photoelectron spectra of the chloro compounds studied are interpreted with the help of the sum rule as well as CNDO/2 calculations. Orbital correlation diagrams have been constructed for these compounds. 相似文献
86.
87.
88.
We show that there is a reduction of the magnetic transition strength at high momentum transfer due to core polarization. This accounts substantially for the observed reduction of 50% of the Jπ=12? and 14? transitions in 208Pb. The core polarization does not affect the shape of the high J form factors in the vicinity of their main peaks. However, a significant q-dependent effect is predicted for the ground state M1 moment of 207Pb. 相似文献
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90.