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排序方式: 共有186条查询结果,搜索用时 15 毫秒
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Herbert Struyf Luc Van Vaeck Katrien Poels René Van Grieken 《Journal of the American Society for Mass Spectrometry》1998,9(5):482-497
This study attempted to determine the molecular composition of inorganic analytes at the surface of solids by Fourier transform laser microprobe mass spectrometry (FT LMMS) with an external ion source. A database was established from the analysis of pure compounds. FT LMMS uses a similar ionization as the older LMMS instruments with time-of-flight (TOF) mass analyzer. However, apart from the mass resolution, the mass spectral patterns can be significantly different in FT LMMS compared to TOF LMMS. FT LMMS yields detailed information on the analyte by means of structural fragments, enabling us to specify the main building blocks, as well as adduct ions, consisting of the analyte molecule and a stable ion. Hence, deductive reasoning allows tentative characterization of the analogs without reference spectra, except for compounds with the same elements in different stoichiometries. In that case comparative data are needed. 相似文献
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Blanc F Copéret C Thivolle-Cazat J Basset JM Lesage A Emsley L Sinha A Schrock RR 《Inorganic chemistry》2006,45(23):9587-9592
Delayed-acquisition methods, namely, echo and constant-time-acquisition approaches, allow a significant improvement in resolution in the proton solid state NMR spectra of surface organometallic catalysts such as [syn-(SiO)Mo(=NAr)(=CH(t)Bu)(CH2(t)Bu)] and [(SiO)Re(C(t)Bu)(=CH(t)Bu)(CH2(t)Bu)] (syn/anti ratio = 1:1). This enables the observation of all of the proton resonances, which is not possible with the simple proton single-pulse technique under magic-angle spinning. For example, the methylene protons of the neopentyl ligands, buried in the large peak associated with all of the methyls in the 1H MAS spectrum, can easily be identified by recording a delayed-acquisition spectrum (resolution enhancement of a factor of 3 is obtained). Moreover, combining constant-time acquisition with heteronuclear carbon-proton correlation spectroscopy also improves the resolution of the 2D HETCOR spectra. 相似文献
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Zagdoun A Casano G Ouari O Lapadula G Rossini AJ Lelli M Baffert M Gajan D Veyre L Maas WE Rosay M Weber RT Thieuleux C Coperet C Lesage A Tordo P Emsley L 《Journal of the American Chemical Society》2012,134(4):2284-2291
A new nitroxide-based biradical having a long electron spin-lattice relaxation time (T(1e)) has been developed as an exogenous polarization source for DNP solid-state NMR experiments. The performance of this new biradical is demonstrated on hybrid silica-based mesostructured materials impregnated with 1,1,2,2-tetrachloroethane radical containing solutions, as well as in frozen bulk solutions, yielding DNP enhancement factors (ε) of over 100 at a magnetic field of 9.4 T and sample temperatures of ~100 K. The effects of radical concentration on the DNP enhancement factors and on the overall sensitivity enhancements (Σ(?)) are reported. The relatively high DNP efficiency of the biradical is attributed to an increased T(1e), which enables more effective saturation of the electron resonance. This new biradical is shown to outperform the polarizing agents used so far in DNP surface-enhanced NMR spectroscopy of materials, yielding a 113-fold increase in overall sensitivity for silicon-29 CPMAS spectra as compared to conventional NMR experiments at room temperature. This results in a reduction in experimental times by a factor >12,700, making the acquisition of (13)C and (15)N one- and two-dimensional NMR spectra at natural isotopic abundance rapid (hours). It has been used here to monitor a series of chemical reactions carried out on the surface functionalities of a hybrid organic-silica material. 相似文献
37.
Kerber RN Kermagoret A Callens E Florian P Massiot D Lesage A Copéret C Delbecq F Rozanska X Sautet P 《Journal of the American Chemical Society》2012,134(15):6767-6775
The determination of the nature and structure of surface sites after chemical modification of large surface area oxides such as silica is a key point for many applications and challenging from a spectroscopic point of view. This has been, for instance, a long-standing problem for silica reacted with alkylaluminum compounds, a system typically studied as a model for a supported methylaluminoxane and aluminum cocatalyst. While (27)Al solid-state NMR spectroscopy would be a method of choice, it has been difficult to apply this technique because of large quadrupolar broadenings. Here, from a combined use of the highest stable field NMR instruments (17.6, 20.0, and 23.5 T) and ultrafast magic angle spinning (>60 kHz), high-quality spectra were obtained, allowing isotropic chemical shifts, quadrupolar couplings, and asymmetric parameters to be extracted. Combined with first-principles calculations, these NMR signatures were then assigned to actual structures of surface aluminum sites. For silica (here SBA-15) reacted with triethylaluminum, the surface sites are in fact mainly dinuclear Al species, grafted on the silica surface via either two terminal or two bridging siloxy ligands. Tetrahedral sites, resulting from the incorporation of Al inside the silica matrix, are also seen as minor species. No evidence for putative tri-coordinated Al atoms has been found. 相似文献
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Katrien Ramaekers Gerrit K. Janssens Hendrik Van Landeghem 《4OR: A Quarterly Journal of Operations Research》2006,4(4):331-342
Logistics systems have to cope with uncertainties in demand, in lead times, in transport times, in availability of resources and in quality. Management decisions have to take these uncertainties into consideration. An evaluation of decisions may be done by means of simulation. However, not all stochastic phenomena are of equal importance. By design of simulation experiments and making use of response surfaces, the most important phenomena are detected and their influence on performance estimated. Once the influence of the phenomena is known, this knowledge may be used to determine the optimal values of some decision parameters. An illustration is given on how to use response surfaces in a real-world case. A model is built in a logistics modelling software. The decision parameters have to be optimised for a specific objective function. Experiments are run to estimate the response surface. The validity of the response surface with few observations is also tested. 相似文献
40.
We study response functions of integrable quantum impurity problems with an external field at T = 0 using non-perturbative techniques derived from the Bethe ansatz. We develop the first steps of the theory of excitations over the new, field-dependent ground state, leading to renormalized (or “dressed”) form factors. We obtain exactly the low-frequency behaviour of the dynamical susceptibility χ″ (ω) in the double-well problem of dissipative quantum mechanics (or equivalently the anisotropic Kondo problem), and the low-frequency behaviour of the AC noise St(ω) for tunnelling between edges in fractional quantum Hall devices. We also obtain exactly the structure of singularities in χ″ (ω) and St (ω). Our results differ significantly from previous perturbative approaches. 相似文献