Mechanically tunable phononic band gaps in three-dimensional periodic elastomeric structures

Three-dimensional periodic structures have many applications in acoustics and their properties are strongly related to structural details. Here we demonstrate through simulations the ability to tune the phononic band gaps of 3D periodic elastomeric structures using deformation. The elastomeric nature of the material makes the transformation of the band gaps a reversible and repeatable process, providing avenues for the design of tunable 3D phononic crystals such as sonic switches.     

Effect of fluorination on the stability of carbon nanofibres in organic solvents

Beneficial effects of fluorination on the stability of carbon nanofibre (CNF) dispersion in organic solvents as a function of time are evidenced. Because of their excellent friction properties, fluorinated CNFs (CF_0.85) can be used as nanoparticles of tribo-active phase in lubrication; however, they have to be added into a matrix. We have shown that mixtures of CF_0.85 are more stable than CNF solutions. Investigations by ultraviolet–visible spectroscopy have been carried out 2 h after sonication and after an ageing of 4 months. Hansen solubility theory was used, and after ageing, tribological and Raman spectroscopy experiments showed no significant modification of physicochemical properties of the CF_0.85.     

Highly Productive CNN Pincer Ruthenium Catalysts for the Asymmetric Reduction of Alkyl Aryl Ketones

Chiral pincer ruthenium complexes of formula [RuCl(CNN)(Josiphos)] ( 2 – 7 ; Josiphos=1‐[1‐(dicyclohexylphosphano)ethyl]‐2‐(diarylphosphano)ferrocene) have been prepared by treating [RuCl₂(PPh₃)₃] with (S,R)‐Josiphos diphosphanes and 1‐substituted‐1‐(6‐arylpyridin‐2‐yl)methanamines (HCNN; substituent=H ( 1 a ), Me ( 1 b ), and tBu ( 1 c )) with NEt₃. By using 1 b and 1 c as a racemic mixture, complexes 4 – 7 were obtained through a diastereoselective synthesis promoted by acetic acid. These pincer complexes, which display correctly matched chiral PP and CNN ligands, are remarkably active catalysts for the asymmetric reduction of alkyl aryl ketones in basic alcohol media by both transfer hydrogenation (TH) and hydrogenation (HY), achieving enantioselectivities of up to 99 %. In 2‐propanol, the enantioselective TH of ketones was accomplished by using a catalyst loading as low as 0.002 mol % and afforded a turnover frequency (TOF) of 10⁵–10⁶ h^?1 (60 and 82 °C). In methanol/ethanol mixtures, the CNN pincer complexes catalyzed the asymmetric HY of ketones with H₂ (5 atm) at 0.01 mol % relative to the complex with a TOF of ≈10⁴ h^?1 at 40 °C.     

Deprotonative Metalation of Functionalized Aromatics Using Mixed Lithium–Cadmium,Lithium–Indium,and Lithium–Zinc Species

In situ mixtures of CdCl₂?TMEDA (0.5 equiv; TMEDA=N,N,N′,N′‐tetramethylethylenediamine) or InCl₃ (0.33 equiv) with [Li(tmp)] (tmp=2,2,6,6‐tetramethylpiperidino; 1.5 or 1.3 equiv, respectively) were compared with the previously described mixture of ZnCl₂?TMEDA (0.5 equiv) and [Li(tmp)] (1.5 equiv) for their ability to deprotonate anisole, benzothiazole, and pyrimidine. [(tmp)₃CdLi] proved to be the best base when used in tetrahydrofuran at room temperature, as demonstrated by subsequent trapping with iodine. The Cd–Li base then proved suitable for the metalation of a large range of aromatics including benzenes bearing reactive functional groups (CONEt₂, CO₂Me, CN, COPh) or heavy halogens (Br, I), and heterocycles (from the furan, thiophene, pyrrole, oxazole, thiazole, pyridine, and diazine series). Five‐membered heterocycles benefiting from doubly activated positions were similarly dideprotonated at room temperature. The aromatic lithium cadmates thus obtained were involved in palladium‐catalyzed cross‐coupling reactions or simply quenched with acid chlorides.     

Special symmetric periodic solutions of differential systems with distributed delay

We discuss the existence of periodic solutions to a system of differential equations with distributed delay which shows a certain type of symmetry. For this, such solutions are related to the solutions of a system of second-order ordinary differential equations.     

Elimination of the chirp of optical pulses through cascaded nonlinearities in periodically poled lithium niobate waveguides

We propose and demonstrate a novel method for the elimination of arbitrary frequency chirp from short optical pulses. The technique is based on the combination of two cascaded second-order nonlinearities in two individual periodically poled lithium niobate waveguides. The proposed scheme operates independently of the spectral phase characteristics of the input pulse, producing a near-transform-limited output.     

Thermal and DMA Characterization of PTFE-PMMA Nanocomposites from Core-Shell Nanoparticles

The thermal and dynamic-mechanical characteristics of three PTFE/PMMA nanoparticle samples are described. The shell forming PMMA, once isolated from the PTFE cores, exhibits a lower thermal stability than the PMMA component in the corresponding nanocomposite under both thermal and oxidative degradation conditions thus indicating a definite, though moderate, thermal reinforcement due to the morphology of the nanocomposites. An increase in the thermal stability under nitrogen atmosphere was observed as the PTFE amount increases. However under air, no difference is observed in the various systems. These observations suggest that only a physical shield can be exerted by the PTFE cores to the PMMA matrix possibly due to a weak interface between PTFE and the PMMA. This hypothesis is also substantiated by the DMA analysis.     

Implicit incentives for fund managers with partial information

Computational Management Science - We study the optimal asset allocation problem for a fund manager whose compensation depends on the performance of her portfolio with respect to a benchmark. The...     

Microwave‐Assisted Synthesis and Physicochemical Characterization of Tetrafuranylporphyrin‐Grafted Reduced‐Graphene Oxide

This work describes the design of a modified porphyrin that bears four furan rings linked by 1,2‐bis‐(2‐aminoethoxy)ethane spacers. This unit is a well‐suited scaffold for a Diels–Alder reaction with commercial reduced‐graphene oxide, which is also described in this paper. A new hybrid material is obtained, thanks to efficient grafting under microwave irradiation, and fully characterized in terms of structure (UV, TGA, Raman) and morphology (HR‐TEM and AFM). Potential applications in photo‐ and sonodynamic therapy are envisaged.